Method for preparing B-Sialon phosphor
View Patent ↗There is provided a method for preparing a β-SiAlON phosphor capable of be controlled to show characteristics such as high brightness and desired particle size distribution. The method for preparing a β-SiAlON phosphor represented by Formula: Si (6−x) Al x O y N (6−y) :Ln z (wherein, Ln is a rare earth element, and the following requirements are satisfied: 0<x≦4.2, 0<y≦4.2, and 0<z≦1.0) includes: mixing starting materials to prepare a raw material mixture; and heating the raw material mixture in a nitrogen-containing atmospheric gas, wherein the starting materials includes a host raw material including a silicon raw material including metallic silicon, and at least one aluminum raw material selected from the group consisting of metallic aluminum and aluminum compound, and at least activator raw material selected from the rare earth elements for activating the host raw material.
1. A method for preparing a β-SiAlON phosphor, the method comprising:
weighing a silicon raw material, an aluminum raw material and an activator raw material in order to prepare a β-SiAlON phosphor represented by Formula: Si (6−x) Al x O y N (8−y) :Ln z (wherein Ln is a rare earth element, and the following requirements are satisfied: 0<x≦4.2, 0<y≦4.2, and 0<z≦1.0;
mixing the starting materials to prepare a raw material mixture; and heating the raw material mixture in a nitrogen-containing atmospheric gas,
wherein the starting material comprise:
at host raw material including a silicon raw material including metallic silicon and optionally a silicon compound, and at least one aluminum raw material selected from the group consisting of metallic aluminum and aluminum compound, wherein at least one of the silicon raw material and the aluminum raw material contains both the metal and compound;
at least one activator raw material selected from the rare earth elements for activating the host raw material,
wherein the method further comprises the step of adjusting at least one of a mixture ratio of metallic silicon and silicon compound and a mixing ratio of metallic aluminum and aluminum compound to control the particle size distribution of the β-SiAlON phosphor, and
wherein the metallic silicon is in the form of powder and has an average particle diameter of 300 μm or less.
2. The method of claim 1 , wherein the rare earth element comprises Eu or Ce.
3. The method of claim 1 , wherein the silicon compound comprises at least one selected from the group consisting of silicon nitride and silicon oxide.
4. The method of claim 1 , wherein the aluminum compound comprises at least one selected from the group consisting of aluminum nitride, aluminum oxide and aluminum hydroxide.
5. The method of claim 1 , wherein the β-SiAlON phosphor has a peak wavelength of 500 to 570 nm.
6. The method of claim 1 , wherein the nitrogen-containing atmospheric gas has an N 2 concentration of 90% or more.
7. The method of claim 1 , wherein the nitrogen-containing atmospheric gas has a gas pressure of 0.1 to 20 MPa.
8. The method of claim 1 , wherein the operation of heating the raw material mixture is performed at a temperature of 1850 to 2200° C.