Continuous washing of poly(vinyl butyral)
View Patent ↗The present invention provides a method for continuously washing poly(vinyl butyral) in which a poly(vinyl butyral) slurry is passed through multiple continuous stirred tank reactors, each of which is adjusted to specific processing parameters that allow for continuous input, washing, and removal of poly(vinyl butyral). The resulting poly(vinyl butyral) can then be dried to form a powder resin that can be used in place of conventional poly(vinyl butyral) resin. In an alternative embodiment, a counter current screw washing unit is provided that passes wash water over the poly(vinyl butyral) in a direction opposite to the flow of the poly(vinyl butyral), thereby allowing the continuous washing of the poly(vinyl butyral) resin.
1. A method of continuously washing a poly(vinyl butyral) resin, comprising the steps:
providing a first continuous stirred tank reactor;
providing a second continuous stirred tank reactor;
adding a continuous stream of poly(vinyl butyral) slurry to said first continuous stirred tank reactor;
washing said continuous stream of poly(vinyl butyral) slurry in said first continuous stirred tank reactor to form a once washed poly(vinyl butyral) slurry;
moving said once washed poly(vinyl butyral) slurry to said second continuous stirred tank reactor;
washing said once washed poly(vinyl butyral) slurry in said second continuous stirred tank reactor to form a twice washed poly(vinyl butyral) slurry; and,
removing said twice washed poly(vinyl butyral) slurry from said second continuous stirred tank reactor.
2. The method of claim 1 , further comprising moving said twice washed poly(vinyl butyral) through two to nine more continuous stirred tank reactors.
3. The method of claim 1 , further comprising moving said twice washed poly(vinyl butyral) through up to thirteen more continuous stirred tank reactors.
4. The method of claim 1 , wherein water is used for said washing.
5. The method of claim 1 , wherein said first continuous stirred tank reactor or said second continuous stirred tank reactor or both comprise a screen attached to the bottom or side walls, a screen barrels installed inside the tank, a top-inserted filter sock, or a filter installed in an external loop.
6. The method of claim 1 , wherein said first continuous stirred tank reactor is operated at a temperature between 20° C. and 95° C. and said second continuous stirred tank reactor is operated at a temperature of 20° C. and 95° C.
7. The method of claim 1 , wherein said first continuous stirred tank reactor is operated at a temperature of 20° C. and 95° C. and said second continuous stirred tank reactor is operated at a temperature of 20° C. and 95° C.
8. The method of claim 1 , wherein said continuous stream of poly(vinyl butyral) slurry is provided at a rate of 0.1 to 5 liters per second.
9. The method of claim 1 , wherein said poly(vinyl butyral) slurry has a total solids concentration of 15-25%.
10. The method of claim 1 , wherein the final washed polyvinyl butyral slurry has an acid catalyst content in the liquid portion of less than 100 ppm.
11. A method of continuously washing a poly(vinyl butyral) resin, comprising the steps:
providing a counter current, continuous screw wash unit, wherein said counter current, continuous screw wash unit comprises a trough with a screw located therein;
adding a continuous stream of poly(vinyl butyral) slurry to said counter current, continuous screw wash unit;
washing said continuous stream of poly(vinyl butyral) slurry in said counter current, continuous screw wash unit by passing a constant stream of wash fluid through said poly(vinyl butyral) slurry in a direction opposite to the flow of said poly(vinyl butyral) slurry to form a washed poly(vinyl butyral) slurry; and,
removing said washed poly(vinyl butyral) slurry from said counter current, continuous screw wash unit.
12. The method of claim 11 wherein said wash fluid is water.
13. The method of claim 11 , wherein said screw has screens.
14. The method of claim 11 , wherein said screw defines small holes that allow the passage of wash fluid.
15. The method of claim 11 , further comprising agitating said poly(vinyl butyral) slurry by injecting air into said trough.
16. The method of claim 15 , wherein said air is injected at 20 to 800 Nm 3 /h.
17. The method of claim 11 , further comprising agitating said poly(vinyl butyral) slurry by injecting steam into said trough.
18. The method of claim 11 , further comprising heating said poly(vinyl butyral) slurry by using heated air injection, jacketed heating, or electrical heating.
19. The method of claim 18 , wherein said poly(vinyl butyral) slurry is heated to 20° C. to 95° C.
20. The method of claim 11 , wherein said continuous stream of poly(vinyl butyral) slurry is provided at a rate of 0.1 to 5 liters per second.
21. The method of claim 11 , wherein said poly(vinyl butyral) slurry has a total solids concentration of 15-25%.
22. The method of claim 11 , wherein the final washed polyvinyl butyral slurry has an acid catalyst content in the liquid portion of less than 100 ppm.