IP Library Granted Patent US 7,989,547
Granted Patent B2
US 7,989,547 · App. 12/473,414 · Granted Aug 2, 2011

Fluoroelastomer composition containing process aid

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Quick Facts
Patent No.
US 7,989,547
App. No.
12/473,414
Granted
Aug 2, 2011
Kind
B2
Abstract

Polyhydroxy curable fluoroelastomer compositions contain at least one process aid that is an aminosilicone having only a single primary amine group per polysiloxane molecule.

Claims (14)

1. A polyhydroxy curable fluoroelastomer composition comprising:

A) fluoroelastomer;

B) 0.05 to 10 parts by weight, per 100 parts by weight fluoroelastomer, of an aminosilicone fluid having a single primary amine group per polysiloxane molecule;

C) 0.1 to 20 parts by weight, per 100 parts by weight fluoroelastomer, of a polyhydroxy curative;

D) 0.1 to 10 parts by weight, per 100 parts by weight fluoroelastomer, of a cure accelerator; and

E) 0.5 to 30 parts by weight, per 100 parts by weight fluoroelastomer, of an acid acceptor.

2. A polyhydroxy curable fluoroelastomer composition of claim 1 wherein said fluoroelastomer is selected from the group consisting of copolymers of i) vinylidene fluoride with hexafluoropropylene; ii) vinylidene fluoride with hexafluoropropylene and tetrafluoroethylene; iii) vinylidene fluoride with perfluoro(methyl vinyl ether) and 2-hydropentafluoroethylene; iv) vinylidene fluoride with perfluoro(methyl vinyl ether), 2-hydropentafluoroethylene and tetrafluoroethylene; v) tetrafluoroethylene with propylene and 3,3,3-trifluoropropene; and vi) ethylene with tetrafluoroethylene, perfluoro(methyl vinyl ether) and 3,3,3-trifluoropropylene.

3. A polyhydroxy curable fluoroelastomer composition of claim 1 wherein said amino silicone has a number average molecular weight between 500 and 50,000.

4. A polyhydroxy curable fluoroelastomer composition of claim 3 wherein said amino silicone has a number average molecular weight between 1000 and 10,000.

5. A polyhydroxy curable fluoroelastomer composition of claim 1 wherein said amino silicone is present at a level of 0.1 to 1 parts by weight, per 100 parts by weight fluoroelastomer.

6. A curable fluoroelastomer composition of claim 1 wherein said polyhydroxy curative is selected from the group consisting of i) dihydroxy-, trihydroxy-, and tetrahydroxy-benzenes, -naphthalenes, and -anthracenes;

ii) bisphenols of the formula

where A is a stable divalent radical; x is 0 or 1; and n is 1 or 2; iii) dialkali salts of said bisphenols, iv) quaternary ammonium salts of said bisphenols, v) quaternary phosphonium salts of said bisphenols, vi) tertiary sulfonium salts of said bisphenols, and vii) esters of said bisphenols.

7. A curable fluoroelastomer composition of claim 1 wherein said cure accelerator is chosen from the group consisting of quaternary ammonium salts, tertiary sulfonium salts and quaternary phosphonium salts.

Assignments (6)
SECURITY INTEREST Recorded Apr 4, 2018
From: THE CHEMOURS COMPANY FC, LLC
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 045846/0011 →
RELEASE OF SECURITY INTEREST Recorded Apr 4, 2018
From: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
To: THE CHEMOURS COMPANY FC, LLC
Reel/Frame 045845/0913 →
SECURITY AGREEMENT Recorded Jun 10, 2015
From: THE CHEMOURS COMPANY FC LLC; THE CHEMOURS COMPANY TT, LLC
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 035839/0675 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 15, 2015
From: E. I. DU PONT DE NEMOURS AND COMPANY
To: THE CHEMOURS COMPANY FC, LLC
Reel/Frame 035432/0023 →
CHANGE OF NAME Recorded Feb 13, 2012
From: DUPONT PERFORMANCE ELASTOMERS LLC
To: E. I. DU PONT DE NEMOURS AND COMPANY
Reel/Frame 027697/0185 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 9, 2009
From: ORIANI, STEVEN R.
To: DUPONT PERFORMANCE ELASTOMERS LLC
Reel/Frame 022932/0056 →