Impact modifier, method for preparing the same and scratch resistant methacrylate resin composition using the same
Disclosed herein is an impact modifier formed by graft polymerizing about 45 to about 70% by weight of a rubber polymer with about 30 to about 55% by weight of a methacrylate-based monomer, wherein said rubber polymer is prepared by polymerizing about 0.1 to about 1 part by weight of an antioxidant with about 100 parts by weight of a monomer mixture comprising about 30 to about 45% by weight of a diene-based monomer and about 55 to about 70% by weight of alkyl acrylate. The methacrylate-based resin composition of the present invention using the aforementioned impact modifier may have improved transparency, impact resistance and a good appearance.
1. An impact modifier formed by graft polymerizing 55 to 70% by weight of a rubber polymer with 30 to 45% by weight of a methacrylate-based monomer, wherein said rubber polymer is prepared by polymerizing 100 parts by weight of a monomer mixture comprising 30 to 45% by weight of a diene-based monomer and 55 to 70% by weight of alkyl acrylate in the presence of 0.1 to 1 part by weight of an antioxidant using a cross-linking agent in an amount of 0.5 to 1 part by weight per 100 parts by weight of the monomer mixture, wherein said rubber polymer has a particle diameter of about 170 nm to about 230 nm, and wherein the impact modifier added to a methacrylate-based resin composition in an amount of 5 to 45% by weight provides a molded article having an Izod notched impact strength of about 4.5 to about 9 kgf·cm/cm at a thickness of ¼″ according to ASTM D256, a yellow index of about 1.7 or less according to ASTM D1925, a pencil hardness of 1H or more at a load of 500 g and a temperature of 23° C. according to JIS K5401, a total light transmittance of about 92% or more and a haze of about 0.9% or less respectively measured by a color computer manufactured by Suga Instrument Corporation.
2. The impact modifier of claim 1 , wherein said methacrylate-based monomer comprises a C1 to C10 alkyl methacrylate.
3. The impact modifier of claim 1 , wherein said alkyl acrylate comprises a C1 to C10 alkyl acrylate.
4. The impact modifier of claim 1 , wherein said antioxidant is octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, triethylene glycol-bis-3(3-tert-butyl-4-hydroxy-5-methylphenyl)propionate, 2,6-di-tert-butyl-4-methylphenol, 2,2′-methylene-bis-(4-methyl-6-tert-butylphenol), tri(2,4-di-tert-butylphenyl)phosphate, n-octadecyl-3(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, 1,3,5-tri(3,5-di-tert-butyl-4-hydroxyphenyl)isocyanate, distearyl-thio-dipropionate, laurylthio propionate methane, di-phenyl-isooctyl phosphite, or a combination thereof.
5. A methacrylate-based resin composition comprising the impact modifier as defined in claim 1 .
6. A molded article produced from the resin composition of claim 5 .
7. A method for preparing an impact modifier comprising: polymerizing a monomer mixture comprising 30 to 45% by weight of a diene-based monomer and 55 to 70% by weight of alkyl acrylate in the presence of 0.1 to 1 part by weight of an antioxidant and using 0.5 to 1 part by weight of a cross-linking agent per 100 parts by weight of the monomer mixture to prepare a rubber polymer with a particle diameter of 170 nm to about 230 nm; and
adding 30 to 45% by weight of a methacrylate-based monomer into 55 to 70% by weight of the rubber polymer to graft polymerize the methacrylate-based monomer with the rubber polymer to form an impact modifier, wherein the impact modifier added to a methacrylate-based resin composition in an amount of 5 to 45% by weight provides a molded article having an Izod notched impact strength of about 4.5 to about 9 kqf·cm/cm at a thickness of ¼″ according to ASTM D256, a yellow index of about 1.7 or less according to ASTM D1925, a pencil hardness of 1 H or more at a load of 500 g and a temperature of 23° C. according to JIS K5401, a total light transmittance of about 92% or more and a haze of about 0.9% or less respectively measured by a color computer manufactured by Suga Instrument Corporation.
8. The method of claim 7 , wherein said alkyl acrylate comprises an C1 to C10 alkyl acrylate.
9. The method of claim 7 , wherein said methacrylate-based monomer comprises a C1 to C10 alkyl methacrylate.
10. The method of claim 7 , wherein said monomer mixture is polymerized using a molecular weight controlling agent.
11. The method of claim 7 , wherein said cross-linking agent is triallyl isocyanurate, allyl methacrylate, or a combination thereof.
12. The method of claim 7 , wherein said antioxidant is octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, triethylene glycol-bis-3(3-tert-butyl-4-hydroxy-5-methylphenyl)propionate, 2,6-di-tert-butyl-4-methylphenol, 2,2′-methylene-bis-(4-methyl-6-tert-butylphenol), tri(2,4-di-tert-butylphenyl)phosphate, n-octadecyl-3(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, 1,3,5-tri(3,5-di-tert-butyl-4-hydroxyphenyl)isocyanate, distearyl-thio-dipropionate, laurylthio propionate methane, di-phenyl-isooctyl phosphite, or a combination thereof.
13. The method of claim 7 , wherein said methacrylate-based monomer is introduced when a conversion ratio of the rubber polymer is about 70 to about 98%.