Method of making a lead-activated strontium hexaborate phosphor
View Patent ↗There is provided a method of making a SrB 6 O 10 :Pb phosphor that increases the manufactured quantity of the SrB 6 O 10 :Pb phosphor by approximately seven fold when using the same size reaction vessel, decreases the lead-containing waste stream, and eliminates the use of hazardous concentrated ammonium hydroxide. The UV emission brightness is equivalent to or better than the same phosphor when prepared using prior methods.
1. A method of making a SrB 6 O 10 :Pb phosphor comprising the steps of:
(a) forming a slurry of boric acid and water;
(b) adding a mixture of strontium carbonate and lead oxide to the slurry;
(c) heating and digesting the slurry for a period of time to obtain a precipitate;
(d) drying the precipitate; and
(e) firing the precipitate to form the phosphor.
2. The method of claim 1 wherein the precipitate is mixed with silica prior to firing and the phosphor after firing is washed and decanted with water to remove silica and then washed with a basic solution of strontium hydroxide to remove residual boric acid.
3. The method of claim 1 wherein the slurry is heated to about 90° C. and digested for about 2 hours.
4. The method of claim 1 wherein the mixture of strontium carbonate and lead oxide is added quickly to the slurry.
5. The method of claim 1 wherein the precipitate may be represented by a formula SrB 6 O 10 .5H 2 O.
6. The method of claim 5 wherein the precipitate contains 0.018 moles of Pb 2+ activator per formula unit.
7. A method of making a SrB 6 O 10 :Pb phosphor comprising the steps of:
(a) forming a slurry of boric acid and water;
(b) quickly adding a mixture of strontium carbonate and lead oxide to the slurry;
(c) heating and digesting the slurry for a period of time to obtain a SrB 6 O 10 .5H 2 O precipitate;
(d) drying the precipitate; and
(e) firing the precipitate in air to form the phosphor.