Polishing composition for planarizing metal layer
View Patent ↗A polishing composition of the present invention at least comprises about 750 ppm to less than 5000 ppm by weight of abrasive particles, hydrogen peroxide, an accelerator, a dual-corrosion inhibitor and water, wherein the dual-corrosion inhibitor contains a first and a second corrosion inhibitor. The dual-corrosion inhibitor is applied to the planarization of metal layers so as to maintain a high removal rate of metal layers as well as suppress etching of the metal, thus capable of reducing polishing defects such as dishing, erosion and the like.
1. A polishing composition for planarizing a metal layer consisting essentially of:
about 750 ppm to less than 5000 ppm by weight of abrasive particles;
hydrogen peroxide,
wherein the hydrogen peroxide is present in an amount of 0.8 wt % based on a total weight of the composition;
an accelerator;
a dual-corrosion inhibitor that reduces a static etching rate of the composition under a high removal rate and contains a first and a second corrosion inhibitor,
wherein the first corrosion inhibitor is selected from 1-H-benzotriazole, an N-acyl sarcosine, an alkyl sulfate or an alkyl sulfonate, and wherein the dual-corrosion inhibitor is present in an amount of 0.001 to 1 wt % based on the total weight of the composition;
and water,
wherein the metal layer comprises copper and wherein the composition has a pH of 7.3 to 7.4.
2. The polishing composition for planarizing a metal layer as claimed in claim 1 ,
wherein the abrasive particles are present in 1000 ppm to less than 3000 ppm by weight.
3. The polishing composition for planarizing a metal layer as claimed in claim 1 ,
wherein the diameter of the abrasive particles is less than 90 nm.
4. The polishing composition for planarizing a metal layer as claimed in claim 1 ,
wherein the diameter of the abrasive particles is less than 50 nm.
5. The polishing composition for planarizing a metal layer as claimed in claim 1 ,
wherein the abrasive particle is selected from the group consisting of fumed silica, colloidal silica formed by hydrolysis of sodium silicate or potassium silicate, or hydrolysis and condensation of silane, precipitated or fumed aluminum oxide, precipitated or fumed titanium dioxide, polymeric materials, and hybrids of metal oxides and polymeric materials.
6. The polishing composition for planarizing a metal layer as claimed in claim 1 ,
wherein the abrasive particle is a colloidal silica.
7. The polishing composition for planarizing a metal layer as claimed in claim 1 ,
wherein the accelerator is selected from the group consisting of citric acid, oxalic acid, tartaric acid, histidine, alanine, glycine and ammonium salts, sodium salts, potassium salts or lithium salts.
8. The polishing composition for planarizing a metal layer as claimed in claim 1 ,
wherein the accelerator is present in an amount of 0.01 to 5 wt % based on the total weight of the composition.
9. The polishing composition for planarizing a metal layer as claimed in claim 1 ,
wherein the second corrosion inhibitor is selected from the group consisting of 1,2,3-triazole, 1,2,4-triazole, tolytriazole, 5-amino tertraazole, 3-amino-1,2,4-triazole, 4-amino-4H-1,2,4-triazole, 3-nitro-1,2,4-triazole, 3-mercapto-1,2,4-triazole, 1H-1,2,3-triazole-1-ethanol, benzimidazole, imidazole, pyrrole, pyrroline, oxazole, isoxazole, indazole or indolizine.
10. The polishing composition for planarizing a metal layer as claimed in claim 1 ,
wherein the first and the second corrosion inhibitors are selected so that the polishing composition serves as a copper slurry for both a first rough polishing step and a second fine polishing step of a two-stage copper removal CMP process,
wherein a first copper removal rate in the first rough polishing rate step is higher than a second copper removal rate in the second fine polishing step.
11. A polishing composition for planarizing a metal layer consisting of:
750 ppm to less than 5000 ppm by weight of abrasive particles;
hydrogen peroxide;
wherein the hydrogen peroxide is present in an amount of 0.8 wt % based on a total weight of the composition;
an accelerator;
a dual-corrosion inhibitor that reduces a static etching rate of the composition under a high removal rate and contains a first and a second corrosion inhibitor;
wherein the first corrosion inhibitor is selected from 1-H-benzotriazole, an N-acyl sarcosine, an alkyl sulfate or an alkyl sulfonate, and
wherein the dual-corrosion inhibitor is present in an amount of 0.001 to 1 wt % based on the total weight of the composition;
and water and
wherein the composition has a pH of 7.3 to 7.4.
12. The polishing composition for planarizing a metal layer of claim 11 ,
wherein the accelerator is present in an amount of 0.01 to 5 wt % based on the total weight of the composition.
13. The polishing composition for planarizing a metal layer of claim 11 ,
wherein the first and the second corrosion inhibitors are selected so that the polishing composition forms a slurry configured for both a first rough polishing step and a second fine polishing step of a two-stage removal CMP process,
wherein a first removal rate in the first rough polishing rate step is higher than a second removal rate in the second fine polishing step.