Method of separating rhodium from platinum and/or palladium
View Patent ↗A method of separating rhodium from platinum and/or palladium includes; chloridizing a raw material including rhodium and at least platinum and/or palladium in chlorine atmosphere and obtaining a soluble salt of platinum and/or palladium; water-leaching chloridized material and dissolving platinum and/or palladium into a solution; filtering the solution; and leaving rhodium in a filtered residue of the solution.
1. A method of separating rhodium from platinum and/or palladium comprising:
chloridizing a raw material including rhodium and at least platinum and/or palladium in chlorine atmosphere without sodium chloride and obtaining a soluble salt of platinum and/or palladium;
water-leaching chloridized material and dissolving platinum and/or palladium into a solution;
filtering the solution; and
leaving rhodium in a filtered residue of the solution.
2. The method as claimed in claim 1 further comprising:
crushing the raw material including rhodium and at least platinum and/or palladium into particles having grain diameter of 500 μm or smaller; and
mixing carbon particle with the crushed raw material.
3. The method as claimed in claim 1 , wherein the raw material is chloridized at 750 to 880 degrees C.
4. The method as claimed in claim 1 wherein the raw material includes ruthenium and iridium, further comprising:
mixing sodium chloride with the residue;
chloridizing the residue in chlorine atmosphere and obtaining a soluble salt of rhodium, ruthenium, and iridium;
water-leaching the rhodium, ruthenium, and iridium and dissolving the rhodium, ruthenium, and iridium into a solution;
filtering the solution;
adding sodium bromate to the solution and separating ruthenium from the solution by oxidizing and distilling; and
separating palladium, platinum, and iridium in order with solvent extraction method.