Liquid crystal composition and liquid crystal display device
View Patent ↗A liquid crystal composition is provided that satisfies at least one characteristic among the characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of a nematic phase, a small viscosity, a large optical anisotropy, a large dielectric anisotropy, a large specific resistance, a high stability to ultraviolet light and a high stability to heat, or is properly balanced regarding at least two characteristics. An AM device is provided that has a short response time, a large voltage holding ratio, a large contrast ratio, a long service life and so forth. The liquid crystal composition having a nematic phase contains a specific five-ring compound having a large maximum temperature as the first component, a specific compound having a small viscosity as the second component, and a specific four-ring compound having a high maximum temperature as the third component. The liquid crystal display device contains the liquid crystal composition.
1. A liquid crystal composition having a nematic phase comprising three components, wherein the first component is at least one compound selected from the group of compounds represented by formula (1-1) and (1-2), and the second component is at least one compound selected from the group of compounds represented by formula (2), and the third component is at least one compound selected from the group of compounds represented by formula (3):
wherein R 1 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons; R 2 and R 3 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; ring A, ring B and ring C are each independently 1,4-cyclohexylene, 1,4-phenylene, 1,3-dioxan-2,5-diyl, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene or 3,5-difluoro-1,4 phenylene; ring D, ring E, ring F and ring G are each independently 1,4-cyclohexylene, 1,4-phenylene 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene or 2,5-difluoro-1,4-phenylene; Z 1 , Z 2 and Z 3 are each independently a single bond, ethylene or carbonyloxy; X 1 and X 2 are each independently hydrogen or fluorine; Y 1 is fluorine, chlorine or trifluoromethoxy; and m is 0 or 1.
2. The liquid crystal composition according to claim 1 , wherein the first component is at least one compound selected from the group of compounds represented by formulas (1-1-1) to (1-1-4) and (1-2-1):
wherein R 1 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, or alkenyl having 2 to 12 carbons; and X 1 , X 2 , X 3 , X 4 , X 5 , X 6 , X 7 and X 8 are each independently hydrogen or fluorine; Y 1 is fluorine, chlorine or trifluoromethoxy.
3. The liquid crystal composition according to claim 2 , wherein the first component is at least one compound selected from the group of compounds represented by formula (1-1-1) to (1-1-3).
4. The liquid crystal composition according to claim 1 , wherein the second component is at least one compound selected from the group of compounds represented by formula (2-1) to (2-6):
wherein R 2 and R 3 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
5. The liquid crystal composition according to claim 4 , wherein the second component is at least one compound selected from the group of compounds represented by formula (2-1).
6. The liquid crystal composition according to claim 4 , wherein the second component is at least one compound selected from the group of compounds represented by formulas (2-1) to (2-4).
7. The liquid crystal composition according to claim 4 , wherein the second component is a mixture of at least one compound selected from the group of compounds represented by formula (2-1), at least one compound selected from the group of compounds represented by formula (2-4), and at least one compound selected from the group of compounds represented by formula (2-6).
8. The liquid crystal composition according to claim 1 , wherein the third component is at least one compound selected from the group of compounds represented by formula (3-1) to (3-4):
wherein R 2 and R 3 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
9. The liquid crystal composition according to claim 8 , wherein the third component is at least one compound selected from the group of compounds represented by formula (3-4).
10. The liquid crystal composition according to claim 1 , wherein a ratio of the first component is from approximately 5% by weight to approximately 25% by weight based on the total weight of the liquid crystal composition, a ratio of the second component is from approximately 30% by weight to approximately 80% by weight based on the total weight of the liquid crystal composition, and a ratio of the third component is from approximately 5% by weight to approximately 25% by weight based on the total weight of the liquid crystal composition.
11. The liquid crystal composition according to claim 1 , wherein the composition further comprises at least one compound selected from the group of compounds represented by formula (4) as a fourth component:
wherein R 1 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons or alkenyl having 2 to 12 carbons; ring H is independently 1,4-cyclohexylene, 1,3-dioxan-2,5-diyl, 1,4-phenylene,2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene,3,5-difluoro-1,4-phenylene, or 2,5-pirymidine; Z 4 is independently a single bond, ethylene, carbonyloxy or difluoromethyleneoxy; X 1 and X 2 are each independently hydrogen or fluorine; Y 1 is fluorine, chlorine or trifluoromethoxy; and n is 1, 2 or 3.
12. The liquid crystal composition according to claim 11 , wherein the fourth component is at least one compound selected from the group of compounds represented by formulas (4-1) to (4-17):
wherein R 4 is alkyl having 1 to 12 carbons, or alkenyl having 2 to 12 carbons.
13. The liquid crystal composition according to claim 12 , wherein the fourth component is at least one compound selected from the group of compounds represented by formula (4-9).
14. The liquid crystal composition according to claim 12 , wherein the fourth component is at least one compound selected from the group of compounds represented by formula (4-11).
15. The liquid crystal composition according to claim 12 , wherein the fourth component is at least one compound selected from the group of compounds represented by formula (4-14).
16. The liquid crystal composition according to claim 12 , wherein the fourth component is at least one compound selected from the group of compounds represented by formula (4-17).
17. The liquid crystal composition according to claim 12 , wherein the fourth component is a mixture of at least one compound selected from the group of compounds represented by formula (4-6) and at least one compound selected from the group of compounds represented by formula (4-11).
18. The liquid crystal composition according to claim 12 , wherein the fourth component is a mixture of at least one compound selected from the group of compounds represented by formula (4-9) and at least one compound selected from the group of compounds represented by formula (4-11).
19. The liquid crystal composition according to claim 12 , wherein the fourth component is a mixture of at least one compound selected from the group of compounds represented by formula (4-11) and at least one compound selected from the group of compounds represented by formula (4-17).
20. The liquid crystal composition according to claim 11 , wherein a ratio of the fourth component is from approximately 10% by weight to approximately to 50% by weight based on the total weight of the liquid crystal composition.
21. The liquid crystal composition according to claim 1 , wherein the composition has a maximum temperature of a nematic phase of approximately 70° C. or more, an optical anisotropy (25° C.) at a wavelength of 589 nm of approximately 0.08 or more, and a dielectric anisotropy (25° C.) at a frequency of 1 kHz of approximately 2 or more.
22. A liquid display device that includes the liquid crystal composition according to claim 1 .
23. The liquid crystal display device according to claim 22 , wherein the liquid crystal display device has an operation mode of a TN mode, an OCB mode, an IPS mode or a PSA mode, and has a driving mode of an active matrix mode.