Method of making tin-based alloys for negative electrode compositions
View Patent ↗Powder milling techniques, tin-based alloys formed thereby, and the use of such alloys as electrode compositions for lithium ion batteries are provided. The alloys include tin and at least one transition metal but contain no silicon. The powder milling is done using low energy roller milling (pebble milling).
1. A method of making nanostructured alloy particles containing substantially no silicon, the method comprising: milling a millbase in a pebble mill containing milling media to provide the nanostructured alloy particles, wherein the millbase comprises: tin, and at least one of carbon or a transition metal, and wherein the nanostructured alloy particles are substantially free of crystalline domains greater than 50 nanometers in size, wherein the pebble mill has an inside diameter of R in feet, and wherein the pebble mill has a rotational speed of greater than 100 percent of 54.2/R 1/2 .
2. A method according to claim 1 , wherein the pebble mill has an inside diameter of R in feet, and wherein the pebble mill has a rotational speed in a range of about 134 percent of 54.2/R 1/2 .
3. A method according to claim 1 , wherein the pebble mill has a theoretical critical speed, and wherein the pebble mill has a containment wall having a temperature, and wherein the temperature is maintained at or below 100° C.
4. A method according to claim 1 , wherein the milling time is less than about 300 hours.
5. A method according to claim 4 , wherein the milling time is less than about 100 hours.
6. A method according to claim 1 , wherein the milling media comprises stainless steel.
7. A method according to claim 6 , wherein the media has an average diameter of less than about 1.3 cm.
8. A method according to claim 6 , wherein the media has an average diameter of less than about 0.70 cm.
9. A method according to claim 1 , wherein the millbase comprises tin, carbon, and at least one transition metal.
10. A method according to claim 9 , wherein the millbase comprises at least one of iron or cobalt.
11. A method according to claim 1 , wherein the nanostructured alloy particles are used in a negative electrode composition in a lithium-ion electrochemical cell.
12. A method according to claim 1 , further comprising a milling aid.
13. A method according to claim 12 , wherein the milling aid comprises stearic acid.
14. A method of making a negative electrode for a lithium-ion electrochemical cell, the method comprising:
milling a millbase in a pebble mill wherein the millbase includes:
tin; and
at least one of carbon or a transition metal, wherein the nanostructured alloy particles are substantially free of crystalline domains greater than 50 nanometers in size; and
dispersing the nanostructured alloy particles in a slurry including a polymeric binder; and
coating the slurry onto a metal current collector,
wherein the pebble mill has an inside diameter of R in feet, and wherein the pebble mill has a rotational speed of greater than 100 percent of 54.2/R 1/2 .
15. A method according to claim 14 , wherein the nanostructured alloy particles comprise tin, carbon, and a transition metal.
16. A method according to claim 15 , wherein the transition metal is at least one of iron and cobalt.
17. A method according to claim 14 , wherein the pebble mill has a rotational speed of about 134 percent of 54.2/R 1/2 .