Process for tailoring water-borne coating compositions
The present invention relates to a process for tailoring theology of an aqueous or water-borne coating composition using a system comprising an amount of a first hydrophobically modified polymer comprising a polymer backbone modified with a first hydrophobe and an amount of a second hydrophobically modified polymer comprising the first hydrophobically modified polymer further modified with a second hydrophobe. By incorporating a system comprising at least two hydrophobically modified polymers into water-borne coatings where the amount of all of the hydrophobically modified polymers are able to be independently adjusted, the resultant coatings may be tailored to attain a desired combination of Stormer or Brookfield viscosity and ICI viscosity.
1 . A process for tailoring rheology of an aqueous or water-borne coating composition comprising the steps of:
a) obtaining an aqueous or water-borne coating composition;
b) obtaining a system comprising
i. an amount of a first hydrophobically modified polymer comprising a polymer backbone modified with a first hydrophobe and
ii. an amount of a second hydrophobically modified polymer comprising the first hydrophobically modified polymer further modified with a second hydrophobe
wherein the first hydrophobe and the second hydrophobe are different from each other;
c) selecting the amount of the first hydrophobically modified polymer relative to the amount of the second hydrophobically modified polymer to tailor the rheology of the aqueous or water-borne coating composition; and
d) combining the aqueous or water-borne coating composition with an amount of the system to obtain an aqueous or water-borne coating composition at 25° C. with a Brookfield viscosity of between about 1000-7000 cps at 5 sec −1 or Stormer viscosity of about 80-130 KU and high-shear viscosity (ICI viscosity) of about 0.1-3.8 poise at 10,000 sec −1 .
2 . The process of claim 1 wherein the first hydrophobically modified polymer is a water-soluble, water-dispersible or water-swellable polymer.
3 . The process of claim 1 wherein the second hydrophobically modified polymer is further characterized by the first and second hydrophobes having 1 to 40 carbon atoms and wherein the first hydrophobe has at least two carbon atoms more than the second hydrophobe.
4 . The process of claim 1 wherein the polymer backbone of the first hydrophobically modified polymer and the second hydrophobically modified polymer are selected from the group consisting of polyacrylates, polyacrylamides, polyurethanes, non-urethane polyether polymers, polysaccharides and derivatives thereof.
5 . The process of claim 4 wherein the non-urethane polyether polymers are selected from the group consisting of an aminoplast polyethers and polyacetal polyethers.
6 . The process of claim 1 wherein the second hydrophobically modified polymer comprises urethanes or non-urethane polyether polymers further comprising:
a) polyether segments connected by ether, acetal, ketal ester, aminoplast and amide linkages,
b) polyether polymer chain termini are connected to two different hydrophobe types through ether, acetal, ketal, ester or amide linkages and
c) two terminal hydrophobes which differ from one another by at least two carbon atoms.
7 . The process of claim 6 wherein the urethanes or non-urethane polyether polymers contains pendant hydrophobes with 1 to 40 carbon atoms in addition to terminal hydrophobes.
8 . The process of claim 6 wherein the lower limit of the weight average molecular weight of the urethanes or non-urethane polyether polymers is about 500 Daltons.
9 . The process of claim 8 wherein the lower limit of the weight average molecular weight of the urethanes or non-urethane polyether polymers is about 20,000 Daltons.
10 . The process of claim 4 wherein the lower limit of the weight average molecular weight of the polyacrylates, polyacrylamides, polysaccharides and derivatives thereof is about 35,000 Daltons.
11 . The process of claim 4 wherein the lower limit of the weight average molecular weight of the polyacrylates, polyacrylamides, polysaccharides and derivatives thereof is about 85,000 Daltons.
12 . The process of claim 1 further comprising adding to aqueous or water-borne coating composition with an amount of a viscosity suppressing agent selected from the group consisting of cyclodextrins and their derivatives, surfactants and water-miscible organic solvents.
13 . The process of claim 12 wherein the viscosity suppressing agent comprises a cyclodextrin.
14 . The process of claim 13 wherein the viscosity suppressing agent comprises a cyclodextrin selected from the group consisting of alpha, beta, and gamma cyclodextrin.
15 . The process of claim 13 wherein the cyclodextrin is selected from the group consisting of methylated, hydroxyethylated, hydroxypropylated, carboxymethylated, and diaminoethylated cyclodextrins and mixtures thereof.
16 . The process of claim 13 wherein the cyclodextrin is added to the aqueous or water-borne coating composition in the range of about 0.1-10% by weight of the aqueous or water-borne coating composition.
17 . The process of claim 16 wherein the cyclodextrin is added to the aqueous or water-borne coating composition in the range of about 0.5-7% by weight of the aqueous or water-borne coating composition.
18 . The process of claim 16 wherein the cyclodextrin is added to the aqueous or water-borne coating composition in the range of about 1-5% by weight of the aqueous or water-borne coating composition.
19 . The process of claim 12 wherein the viscosity suppressing agent comprises a surfactant selected from the group consisting of anionic, cationic, non-ionic zwitterionic and Gemini surfactants.
20 . The process of claim 19 wherein the surfactant comprises about 2-25% by weight of the aqueous or water-borne coating composition.
21 . The process of claim 20 wherein the surfactant comprises about 4-20% by weight of the aqueous or water-borne coating composition.
22 . The process of claim 20 wherein the surfactant comprises about 7-15% by weight of the aqueous or water-borne coating composition.
23 . An aqueous or water-borne coating composition comprising:
i.) a first hydrophobically modified polymer comprising a polymer backbone modified with a first hydrophobe and,
ii,) a second hydrophobically modified polymer comprising the first hydrophobically modified polymer further modified with a second hydrophobe;
a latex; and water,
wherein the aqueous or water-borne coating composition, at 25° C., has a Brookfield viscosity of between about 1000-7000 cps at 5 sec −1 or Stormer viscosity of about 80-130 KU and high-shear viscosity (ICI viscosity) of about 0.1-3.8 poise at 10,000 sec −1 and wherein the first hydrophobically modified polymer comprises from about 0.05 to 10 wt % of the aqueous or water-borne coating composition and the a second hydrophobically modified polymer comprises from about 0.01 to 8 wt % of the aqueous or water-borne coating composition.
24 . The aqueous or water-borne coating composition of claim 23 wherein the first hydrophobically modified polymer comprises from about 0.01 to 5 wt % of the aqueous or water-borne coating composition and the a second hydrophobically modified polymer comprises from about 0.01 to 4 wt % of the aqueous or water-borne coating composition.
25 . The aqueous or water-borne coating composition of claim 23 wherein the first hydrophobically modified polymer comprises from about 0.5 to 2 wt % of the aqueous or water-borne coating composition and the a second hydrophobically modified polymer comprises from about 0.05 to 1 wt % of the aqueous or water-borne coating composition.
26 . The aqueous or water-borne coating composition of claim 23 further comprising a pigment.
27 . The aqueous or water-borne coating composition of claim 26 wherein the pigment is selected from the group consisting of hydrated aluminum oxide, barium sulfate, calcium silicate, clay, silica, talc, titanium dioxide, zinc oxide, and mixtures thereof.
28 . The aqueous or water-borne coating composition of claim 23 , wherein the latex is selected from the group of 100% acrylics, vinyl-acrylics, and styrene-acrylics.
29 . The aqueous or water-borne coating composition of claim 23 wherein the polymer backbone of the first hydrophobically modified polymer and the second hydrophobically modified polymer are selected from the group consisting of polyacrylates, polyacrylamides, polyurethanes, non-urethane polyether polymers, polysaccharides and derivatives thereof.