Catalyst composition and a process that uses the catalyst composition for the hydroconversion of a heavy hydrocarbon feedstock
View Patent ↗A catalyst composition that provides for a high percentage conversion of the pitch component of a heavy hydrocarbon feedstock and a process of using the catalyst composition. The catalyst composition comprises a nickel component, a molybdenum component in an amount less than 12 wt % of the catalyst composition, and it may also include an alumina support material having special properties. The weight ratio of the nickel component-to-molybdenum component exceeds 0.25, and the support material preferably has a median pore diameter of from 100-140 Å. The catalyst composition has a characteristically unique Raman spectrum that distinguishes it over other compositions.
1. A catalyst composition for use in the hydroconversion of a heavy hydrocarbon feedstock, wherein said catalyst composition comprising:
a support material having incorporated therein:
a molybdenum component in an amount such that it is present in said catalyst composition in an amount of from 5 wt. % to less than 12 wt. %, wherein the wt. % is based on the total weight of said catalyst composition and assuming said molybdenum component is in the oxide form regardless of its actual form; and
a nickel component in an amount such that it is present in said catalyst composition in an amount such that said catalyst composition has a weight ratio of said nickel component-to-said molybdenum component of at least 0.28, with said weight ratio computed assuming said nickel component and said molybdenum component are each in the oxide form regardless of their actual forms;
wherein said catalyst composition exhibits an absolute pitch conversion capability exceeding 0.16, and wherein said catalyst composition is characterized by a Raman spectrum that includes at least two Raman peaks having maxima in the Raman band range of from 275 cm −1 to 400 cm −1 .
2. A catalyst composition as recited in claim 1 , wherein said support material comprises alumina, wherein said support material has a median pore diameter in the range of from 100 Å to 140 Å and no more than 5% of its total pore volume in the pores having a pore diameter of greater than 210 Å.
3. A catalyst composition as recited in claim 2 , wherein said support material has a pore size distribution width of no more than 35 Angstroms and a total pore volume of at least 0.75 cc/gram.
4. A catalyst composition as recited in claim 3 , wherein said catalyst composition is further characterized by a Raman spectrum that includes a peak having its maximum in the Raman band range of from 1610 cm−1 to 1750 cm−1.
5. A catalyst composition as recited in claim 4 , wherein said weight ratio of said nickel component-to-said molybdenum component exceeds 0.3.
6. A catalyst composition as recited in claim 5 , wherein less than 10% of the total pore volume of said support material is contained in the pores of said support material having a pore diameter of less than 90 Å.
7. A catalyst composition as recited in claim 6 , wherein said support material has a substantial absence of silica.
8. A catalyst composition as recited in claim 7 , wherein said catalyst composition has a substantial absence of cobalt.
9. A process for the hydroconversion of a heavy hydrocarbon feedstock, wherein said process comprises: contacting under suitable hydroconversion conditions said heavy hydrocarbon feedstock with a catalyst composition as recited in any one of claims 1 through 3 and 4 through 8 .