Method of fabricating a thermostructural composite material part, and a part obtained thereby
View Patent ↗The method comprises: using chemical vapor infiltration to form a first continuous interphase on the fibers of a fiber structure made of refractory fibers, the interphase having a thickness of no more than 100 nanometers; impregnating the fiber structure with a consolidation composition comprising a carbon or ceramic precursor resin; forming a fiber preform that is consolidated by shaping the impregnated fiber structure and using pyrolysis to transform the resin into a discontinuous solid residue of carbon or ceramic; using chemical vapor infiltration to form a second continuous interphase layer; and densifying the preform with a refractory matrix. This preserves the capacity of the fiber structure to deform so as to enable a fiber preform to be obtained that is of complex shape, while nevertheless guaranteeing the presence of a continuous interphase between the fibers and the matrix.
1. A method of fabricating a thermostructural composite material part, the method comprising the following successive steps:
using chemical vapor infiltration to form a first continuous interphase layer of a single material on the fibers of a fiber structure made of refractory fibers, the first interphase layer having a thickness of no more than 100 nanometers;
forming a consolidated fiber preform by shaping the fiber structure, with the first interphase layer and impregnated with a consolidation composition that includes a carbon or ceramic precursor resin, into a desired shape;
transforming the resin by pyrolysis into a discontinuous solid residue formed by grains of carbon or ceramic;
then using chemical vapor infiltration to form a second continuous interphase layer covering the first interphase layer and the solid pyrolysis residue grains; and
then densifying the preform with a refractory matrix.
2. A method according to claim 1 , wherein the first interphase layer is made of a single material selected from pyrolytic carbon, boron nitride, and boron-doped carbon.
3. A method according to claim 1 , wherein the material of the second interphase layer is selected from pyrolytic carbon, boron nitride, boron-doped carbon, and a material made up of layers of pyrolytic carbon, boron nitride, or boron-doped carbon alternating with layers of silicon carbide.
4. A method according to claim 1 , wherein the first interphase layer has thickness of no more than 50 nanometers.
5. A method according to claim 1 , wherein the first interphase layer has thickness of at least 10 nanometers.
6. A method according to claim 1 , wherein the second interphase layer has a thickness of at least 100 nanometers.
7. A method according to claim 1 , wherein the operations of transformation into a solid residue of carbon or ceramic by pyrolysis, and of forming the second interphase layer are performed sequentially in a same oven.
8. The method according to claim 1 , wherein said shaping of the fiber structure into the desired shape is carried out by using a tooling to maintain the fiber structure in the desired shape.
9. The method according to claim 8 , wherein the second continuous interphase layer is formed after the consolidated preform has been removed from said tooling.
10. The method according to claim 1 , wherein said first and second contiguous interphase layers together form an embrittlement relief interphase between the fibers and the refractory matrix.