Phosphonium ionic liquids, compositions, methods of making and batteries formed there from
The invention generally encompasses phosphonium ionic liquids and compositions and their use in many applications, including but not limited to: as electrolytes in electronic devices such as memory devices including static, permanent and dynamic random access memory, as battery electrolytes, as a heat transfer medium, fuel cells and electrochromatic devices, among other applications. In particular, the invention generally relates to phosphonium ionic liquids, compositions and molecules possessing structural features, wherein the molecules exhibit superior combination of thermodynamic stability, low volatility, wide liquidus range and ionic conductivity. The invention further encompasses methods of making such phosphonium ionic liquids, compositions and molecules, and operational devices and systems comprising the same.
1. A battery, comprising:
a positive electrode;
a negative electrode;
a separator between said positive and negative electrode; and
an electrolyte comprising an ionic liquid composition, the ionic liquid composition comprising: a phosphonium based cation of the formula:
and;
one or more anions comprised of any one or more of the following: − O 3 SCF 3 , − O 2 CCF 3 , − O 2 CCF 2 CF 2 CF 3 , CF 3 BF 3 − , C(CN) 3 − , PF 6 − , − O 3 SCH 3 , − O 3 SCF 2 CF 2 CF 3 , − O 2 CH, − O 2 CC 6 H 5 , − OCN, CO 3 2− , or − N(CN) 2 .
2. The battery of claim 1 wherein the electrolyte is a solution and further contains a solvent.
3. The battery of claim 1 wherein one or more of the hydrogen atoms in one or more of the alkyl groups are substituted by fluorine atoms.
4. A battery, comprising:
a positive electrode;
a negative electrode;
a separator between said positive and negative electrode; and
an electrolyte comprising an ionic liquid composition, the ionic liquid composition comprising: one or more phosphonium based cations of the general formula:
R 1 R 2 R 3 R 4 P
wherein: R 1 , R 2 , R 3 and R 4 are each independently an alkyl group comprised of 1 to 4 carbons, and one or more anions, wherein the ionic liquid composition exhibits thermodynamic stability up to a temperature of approximately 375° C., and ionic conductivity up to 10 mS/cm.
5. A battery comprising:
a positive electrode;
a negative electrode;
a separator between said positive and negative electrode; and
an electrolyte comprising an ionic liquid composition, the ionic liquid composition comprising one or more phosphonium based cations of the following formulas:
Cation
R1
R2
R3
R4
P +
Methyl
Methyl
Methyl
Ethyl
P +
Methyl
Methyl
Methyl
Propyl
P +
Methyl
Methyl
Methyl
i-Propyl
P +
Methyl
Methyl
Ethyl
Propyl
P +
Methyl
Methyl
Ethyl
i-Propyl
P +
Methyl
Ethyl
Ethyl
Propyl
P +
Methyl
Ethyl
Ethyl
i-Propyl
P +
Methyl
Ethyl
i-Propyl
i-Propyl
P +
Ethyl
Ethyl
Propyl
i-Propyl
P +
Ethyl
Ethyl
Ethyl
Propyl
P +
Ethyl
Ethyl
Ethyl
i-Propyl
P +
Propyl
Propyl
Propyl
Methyl
P +
Propyl
Propyl
Propyl
Ethyl
P +
Propyl
Propyl
Propyl
i-Propyl
P +
i-Propyl
i-Propyl
i-Propyl
Methyl
P +
i-Propyl
i-Propyl
i-Propyl
Ethyl
P +
i-Propyl
i-Propyl
i-Propyl
Propyl
and;
one or more anions, wherein the one or more anions are comprised of any one or more of the following: − O 3 SCF 3 , − O 2 CCF 3 , − O 2 CCF 2 CF 2 CF 3 , CF 3 BF 3 − , C(CN) 3 − , PF 6 − , − O 3 SCH 3 , − O 3 SCF 2 CF 2 CF 3 , − O 2 CH, − O 2 CC 6 H 5 , − OCN, CO 3 2− , or − N(CN) 2 .
6. The battery of claim 5 wherein one or more of the hydrogen atoms in one or more of the alkyl groups are substituted by fluorine atoms.
7. A battery, comprising:
a positive electrode;
a negative electrode;
a separator between said positive and negative electrode; and
an electrolyte comprising an ionic liquid composition, the ionic liquid composition comprising: a phosphonium based cation of the formula:
and;
one or more anions comprised of any one of more of the following anion mixtures: 1NO 3 − /1O 3 SCF 3 − , 3NO 3 − /1O 3 SCF 3 − , 1NO 3 − /3O 3 SCF 3 − , 1NO 3 − /1N(SO 2 CF 3 ) 2 − , 1NO 3 − /1PF 6 − , 1O 3 SCF 3 − /1N(SO 2 CF 3 ) 2 − , 1O 3 SCF 3 − /1O 3 SC 6 H 4 CH 3 − , 3O 3 SCF 3 − /1O 3 SC 6 H 4 CH 3 − , 1O 3 SCF 3 − /1O 3 SCF 2 CF 2 CF 3 − , 1O 3 SC 6 H 4 CH 3 − /3O 3 SCH 3 − , 1O 3 SC 6 H 4 CH 3 − /1O 3 SCF 2 CF 2 CF 3 − , 3O 3 SC 6 H 4 CH 3 − /1O 3 SCF 2 CF 2 CF 3 − , or 1O 3 SC 6 H 4 CH 3 − /3O 3 SCF 2 CF 2 CF 3 − .