Process for preparing radiation-curable prepolymers containing urethane groups
View Patent ↗The invention relates to a continuous process for preparing radiation-curable prepolymers containing urethane groups, more particularly urethane acrylates.
1. Process for the continuous preparation of radiation-curable prepolymers containing urethane groups, comprising mixing at least two components and then passing the mixed components through a delay section, one of the at least two components comprising one or more compounds having at least one isocyanate group per molecule, and the other of the at least two components comprising one or more compounds having at least one isocyanate reactive group and at least one ethylenically unsaturated double bond per molecule, wherein the delay section has a heat transfer rate of 20-750 kW/(K·m 3 ), and the process is performed in a microreactor allowing for said heat transfer rate.
2. Process according to claim 1 , carried out under pressure of 0-30 bar and at temperatures of +20 to +200° C.
3. Process according to claim 1 , having a delay time in the delay section of from 20 sec to 120 min.
4. Process according to claim 1 , wherein the delay section has a maximum pressure loss of 0 to 30 bar.
5. Process according to claim 1 , wherein the delay section comprises mixing elements and the components are further mixed by said mixing elements as they pass through the delay section.
6. Process according to claim 1 , optionally including the addition of one or more further components along the delay section said one or more further components optionally comprising one or more compounds selected from the group consisting of compounds bearing isocyanate groups, isocyanate-reactive compounds, solvents, catalysts, reactive diluents and auxiliaries.
7. Process according to claim 1 , wherein the delay section is subdivided into two or more zones having different temperatures.