Continuous process for converting natural gas to liquid hydrocarbons
View Patent ↗A method comprising: providing a first halogen stream; providing a first alkane stream; reacting at least a portion of the first halogen stream with at least a portion of the first alkane stream in a first reaction vessel to form a first halogenated stream; providing a second alkane stream comprising C 2 and higher hydrocarbons; providing a second halogen stream; and reacting at least a portion of the second halogen stream with at least a portion of the second alkane stream in a second reaction vessel to form a second halogenated stream.
1. A method comprising:
providing a halogen stream;
providing a first alkane stream;
reacting at least a portion of the halogen stream with at least a portion of the first alkane stream to form a halogenated stream, wherein the halogenated stream comprises alkyl monohalides, alkyl polyhalides, and hydrogen halide; and
contacting at least some of the alkyl monohalides with a coupling catalyst comprising a ZSM-5 zeolite having undergone a dealumination treatment to form a product stream that comprises higher hydrocarbons and hydrogen halide.
2. The method of claim 1 further comprising:
providing a second alkane stream;
reacting at least a portion of the second alkane stream with at least a portion of the alkyl polyhalides to create at least some additional alkyl monohalides; and
contacting at least some of the additional alkyl monohalides with the coupling catalyst to form at least some higher hydrocarbons and hydrogen halide.
3. The method of claim 1 further comprising:
separating the hydrogen halide from the product stream; and
reacting the hydrogen halide with a source of oxygen to regenerate the halogen stream.
4. The method of claim 1 wherein the coupling catalyst comprises a plurality of catalytic materials wherein each catalytic material is disposed in a different reaction vessel.
5. The method of claim 1 further comprising:
providing a Lewis base molecule; and
contacting the Lewis base molecule with the coupling catalyst contemporaneously with the contacting of at least some of the alkyl monohalides with the coupling catalyst to form the product stream.
6. The method of claim 5 wherein the Lewis base molecule is present in an amount less than about 15% by weight of the total feed to the coupling catalyst.
7. The method of claim 1 wherein the dealumination treatment comprises contacting the coupling catalyst with a dealumination agent.
8. The method of claim 7 wherein the dealumination agent comprises at least one material selected from the group consisting of: a mineral acid, hydrochloric acid, hydrofluoric acid, a chelating agent, ethylenediaminetetraacetic acid, oxalic acid, malonic acid; steam, an exchange reagent, SiCl 4 , NH 4 [SiF 6 ], NH 4 HF 2 , AlF 3 , a trialkyl phosphate, an organic phosphite, and a combination thereof.