Ambient cure solvent-based coatings for writable-erasable surfaces
View Patent ↗Solvent-based coatings having writable-erasable surfaces are provided. The coatings have many desirable attributes. For example, the coatings cure rapidly under ambient conditions, have low VOC emissions upon curing, and have reduced tendency to form ghost images, even after prolonged normal use.
1. A method of forming a coating having a write-erasable surface on a substrate comprising:
combining an isocyanate resin component and an acrylic polyol resin component in relative amounts with respect to each other to produce a composition, wherein the composition is in an organic solvent-based carrier, and further wherein
a) the isocyanate resin component comprises 20-40% by weight of the composition, and
b) the acrylic polyol resin component comprises 10-20% by weight of the composition;
applying the composition to a substrate, to cure under ambient conditions so that a coating having a write-erasable surface is produced on the substrate, the coating being characterized by:
a gloss finish greater than 65 when measured at 60°;
an average surface roughness of less than 7,500 nm and a maximum surface roughness of less than 10,000 nm;
a Sward hardness of greater than about 10;
a Taber abrasion of less than 150 mg/thousand cycles;
an elongation at break is between about 5 percent and about 400 percent;
a sag resistance is between about 4 mils to about 24 mils; and
a contact angle measured using deionized water of less than about 150 degree,
and so that after the coating is marked with a marking material comprising a colorant and a solvent, the marking material can be erased from the write-erasable surface to be effectively invisible.
2. The method of claim 1 , wherein the step of combining comprises:
obtaining a first material comprising the isocyanate resin component;
obtaining a second material, physically separate from the first material, that comprises the acrylic polyol resin component; and
combining the first and second materials with one another.
3. The method of claim 2 , wherein the first and second materials are maintained physically separate from one another in first and second containers.
4. The method of claim 1 , wherein the second material further comprises a cross-linking agent.
5. The method of claim 1 , wherein the isocyanate resin component is selected from the group consisting of hexamethylene diisocyanate (HDI), tetramethylene diisocyanate, octamethylene diisocyanate, decamethylene diisocyanate, 2-methylpentane-1,5-diisocyanate, toluene diisocyanate (TDI), diphenylmethane diisocyanate (MDI), m- and p-phenylene diisocyanates, bitolylene diisocyanate, cyclohexane diisocyanate (CHDI), bis-(isocyanatomethyl) cyclohexane (H 6 XDI), dicyclohexylmethane diisocyanate (H 12 MDI), dimer acid diisocyanate (DDI), trimethyl hexamethylene diisocyanate, lysine diisocyanate and its methyl ester, methyl cyclohexane diisocyanate, 1,5-napthalene diisocyanate, xylene diisocyanate, polyphenylene diisocyanates, isophorone diisocyanate (IPDI), hydrogenated methylene diphenyl isocyanate (HMDI), tetramethyl xylene diisocyanate (TMXDI), oligomers and homopolymers of any of the foregoing, and mixtures thereof.
6. The method of claim 1 , wherein the isocyanate resin component is selected from the group consisting of an aliphatic diisocyanate, its oligomer, its homopolymer, and mixtures thereof.
7. The method of claim 1 , wherein the isocyanate resin component is a hexamethylene-1,6-diisocyanate homopolymer.
8. The method of claim 1 , wherein the solvent-based carrier is selected from the group consisting of hydrocarbons, alcohols, ketones, esters, mineral spirits, bio-based solvents, and mixtures thereof.
9. The method of claim 1 , wherein the solvent-based carrier is selected from the group consisting of ethyl benzene, xylene, n-butyl acetate, methyl iso-amyl ketone, Stoddard solvent, t-butyl acetate, acetone, isopropyl alcohol, 2-butoxyethanol, toluene, methanol, propanol, 2-butanol, iso-amyl alcohol, methyl amyl alcohol, pentane, heptane, odorless mineral spirits, methyl ethyl ketone, diacetone alcohol, methyl amyl ketone, ethyl amyl ketone, diisobutyl ketone, methyl heptyl ketone, ethyl acetate, isopropyl acetate, propyl acetate, isobutyl acetate, n-butyl acetate, glycol ether EM acetate, amyl acetate, isobutyl isobutyrate, glycol ether EE acetate, Glycol ether EB acetate, 2-ethylhexyl acetate, glycol ether DE acetate, Glycol DB acetate, methyl isobutyl ketone, dipropylene glycol butoxy ether, vegetable oil, corn oil, sunflower oil, and mixtures thereof.
10. The method of claim 1 , wherein the step of combining further comprises combining an accelerator with the isocyanate resin component and the acrylic polyol resin component.
11. The method of claim 10 , wherein the accelerator comprises dibutyltin dilaurate.
12. The method of claim 1 , wherein the step of combining further comprises combining an acid promoter with the isocyanate resin component and the acrylic polyol resin component.
13. The method of claim 12 , wherein the acid promoter comprises propionic acid.
14. The method of claim 1 , wherein the step of combining further comprises combining titanium dioxide, a surface additive, a wetting agent, or a defoaming agent with the isocyanate resin component and the acrylic polyol resin component.
15. The method of claim 1 , wherein the step of combining further comprises combining a pigment or a colorant with the isocyanate resin component and the acrylic polyol resin component.
16. The method of claim 1 , wherein the coating is characterized in that, the marking material can be erased from the write-erasable surface to be substantially invisible after writing and erasing at the same position for more than about 100 cycles.
17. The method of claim 1 , wherein the coating is characterized in that, the marking material can be erased from the write-erasable surface to be substantially invisible after writing and erasing at the same position for more than about 5,000 cycles.
18. The method of claim 1 , wherein the substrate is selected from the group consisting of cellulosic material, glass, wall, fiber board, particle board, gypsum board, wood, plastic, densified ceramics, stone, and metal.
19. The method of claim 1 , wherein the substrate comprises a flexible film or a rigid structure.
20. The method of claim 1 , wherein the step of applying comprises rolling, painting, spraying or any combination thereof.
21. The method of claim 1 , further comprising a step of permitting the composition to cure.
22. The method of claim 1 , further comprising a step of writing with the marking material on the write-erasable surface.
23. The method of claim 22 , further comprising a step of erasing the marking material.
24. The method of claim 1 , wherein the step of applying comprises forming a coating having a thickness of at least 20 mil.