Static dissipative polyacetal compositions
View Patent ↗Polyacetal compositions comprising polyacetal, electroconductive carbon black, and substituted urea provide a combination of good static dissipation properties, good thermal stability during processing, and good stability to contact with fuel.
1. A polyacetal composition comprising:
(a) from about 60 to about 98.9 weight percent (wt %) of polyacetal;
(b) from about 1 to about 30 wt % of electroconductive carbon black;
(c) from about 0.1 to about 5 wt % of at least one substituted urea having the structure:
(R 1 )(R 2 )N—(CO)—N(R 3 )(R 4 ),
wherein R 1 is a C3-C4 linear or branched hydrocarbon group and R 2 , R 3 , and R 4 are H; and
(d) up to about 5 wt % of at least one hindered amine light stabilizer, wherein the weight percentages are based on the total weight of (a)+(b)+(c)+(d).
2. The polyacetal composition of claim 1 , wherein polyacetal (a) comprises at least one polyvoxymethylene copolymer.
3. The composition of claim 1 , comprising about 79 to about 96.8 wt % (a); about 3 to about 15 wt % (b); about 0.2 to about 3 wt % (c); and 0 to about 3 wt % (d).
4. The composition of claim 1 , comprising about 87.5 to about 95.8 wt % (a); about 4 to about 9 wt % (b); about 0.2 to about 1.5 wt % (c); and 0 to about 2 wt % (d).
5. The composition of claim 1 , wherein the composition has a surface resistivity of no greater than about 1×10 6 Ωsq as measured using ATSM D257.
6. The composition of claim 1 , wherein the composition has a surface resistivity of about 1×10 2 to about 1×10 6 Ωsq as measured using ATSM D257.
7. The composition of claim 1 , wherein substituted urea (c) is n-butyl urea.
8. The composition of claim 1 , wherein (c) is at least one substituted urea selected from the group consisting of sec-butyl urea; tent-butyl urea; ethyl urea; methyl urea; iso-butyl urea; n-butyl urea; propyl urea; cyclohexyl urea; phenyl urea; benzyl urea; tolyl urea; and allyl urea.
9. The composition of claim 1 , wherein (d) comprises at least one triazine moiety having at least one secondary amine component.
10. The composition of claim 1 , wherein (d) is poly[[6-[(1,1,3,33-tetramethylbutyl) amino]-1,3,5-triazine-2,4-diyl][(2,2,6,6-tetramethyl-4-peperidinyl)-imino]-1,6-hexanediyl [(2,2,6,6-tetramethyl-4-piperidinyl)imino]].
11. The composition of claim 1 further comprising at least one additive that performs at least one of the following functions: impact modifier, lubricant, plasticizer, antioxidant, filler, reinforcing agent, light stabilizer, or nucleating agent.
12. The composition of claim 1 further comprising nanoparticles.
13. An article made from the composition of claim 1 .
14. The article of claim 13 wherein the article is used in a system to convey fuel.
15. The article of claim 13 wherein the article is useful as an automotive fuel system component.
16. The article of claim 15 wherein the fuel system component is a module, a fuel pump, or a fuel filler neck.
17. A film or sheet made from the composition of claim 1 .
18. The polyacetal of claim 1 wherein the polyacetal composition does not contain a tent-butyl urea and wherein the polyacetal composition has a formaldehyde index that is at least 30% less than the same polyacetal composition without a substituted urea.