Composition suitable for thin-wall injection molded articles
View Patent ↗Compositions suitable for manufacturing injection molded articles having a minimum wall thickness of from 500 μm to 2.0 mm comprise from: (A) 2 to 15% by weight of a propylene-ethylene copolymer having substantially isotactic propylene sequences; (B) 85 to 98% by weight of a random polypropylene copolymer having from 2.5 to 5.0% by weight units derived from ethylene and a melt flow rate of from 25 to 130 grams/10 minutes (g/10 min); and (C) 500 to 2500 ppm by weight of a nucleator/clarifier additive (based on the weight of the random polypropylene copolymer). Typically, the melt flow rate of the compositions is from 20 to 125 g/10 min, and the propylene-ethylene copolymer comprises at least 75% by weight propylene and has a melt flow rate from 4 to 30 g/10 min.
1. A composition for manufacturing injection molded articles having a wall thickness of between 500 μm and 2.0 mm, the composition comprising a blend of:
(A) from 2 to 15% by weight of a propylene-ethylene copolymer having substantially isotactic propylene sequences, the propylene-ethylene copolymer comprising:
(1) at least 75% by weight units derived from propylene and from about 11 to 18% by weight units derived from ethylene;
(2) the propylene-ethylene copolymer having a melt flow rate from 4 to 30 grams/10 minutes;
(B) from 85 to about 98% by weight of a random polypropylene copolymer having an ethylene content of from 2.0-5.0 percent by weight, a melt flow rate of from 25 to 130 grams/10 minutes, wherein, the melt flow rate of the blend is from 20 to 125 grams/10 minutes; and
(C) from 500 to 2500 ppm by weight of a nucleator/clarifier additive based on the weight of the random polypropylene copolymer (B), wherein, the melt flow rate of the composition is from 20 to 125 grams/10 minutes and wherein a 1.6 mm thick section of the injection molded article exhibits:
(1) room temperature (23° C.) Dart Impact strength by ISO 6603 of at least 7.5 J/mm;
(2) tensile-yield strength by ISO 527 of between 20 and 30 MPa;
(3) 0° Dart Impact Strength by ISO 6603 of at least 0.43 to 0.75 J/mm; and
(4) a value for haze of less than 50% by ASTM 1003.
2. The composition of claim 1 , wherein the 1.6 mm thick section exhibits low stress whitening.
3. The composition of claim 1 , wherein the propylene-ethylene copolymer has a molecular weight distribution (Mw/Mn) of less than 3.5.
4. The composition of claim 1 , wherein the propylene-ethylene copolymer has a melt flow rate of from 5 to 26 g/10 min.
5. The composition of claim 1 , wherein the random polypropylene copolymer contains 3 to 4 percent by weight units derived from ethylene.
6. The composition of claim 1 , wherein the random polypropylene copolymer has a melt flow rate of from 30 to 60 grams/10 minutes.
7. The composition of claim 5 , wherein the random polypropylene copolymer has a melt flow rate of from 40 to 50 grams/10 minutes.
8. The composition of claim 1 , wherein composition contains from 4 to 10 percent by weight of the propylene-ethylene copolymer.
9. The composition of claim 1 , wherein the 1.5 mm thick section of the injection molded sample exhibits:
(1) Room temperature (23° C.) Dart impact from 7.5 to 15 J/mm;
(2) 0° C. Dart Impact from 0.45 to 0.75 J/mm; and
(3) a value for haze of less than 48% by ASTM 1003.
10. The composition of claim 1 , wherein the nucleator/clarifier additive is a sorbitol-type nucleator/clarifier.
11. The composition of claim 10 , wherein the nucleator/clarifier is selected from the group consisting of, Geniset MD-LM-30 (1,3,2,4-Di(methylbenzylidene)Sorbitol) and Millad 3988 (1,2,3,4-di-meta, para-methylbenzylidene sorbitol).
12. The composition of claim 10 , wherein the nucleator/clarifier is present at a level of between 800 and 2500 ppm based on the weight of the random polypropylene copolymer in the composition.
13. The composition of claim 10 , wherein the nucleator/clarifier is present at a level of between 1700 and 2200 ppm based on the weight of the random polypropylene copolymer in the composition.
14. The composition of claim 1 , the composition further including a homogeneous ethylene-alpha olefin interpolymer.
15. The composition of claim 14 , wherein the homogeneous ethylene-alpha olefin interpolymer is present at between 3 and 25 percent by weight based on the weight of the propylene-ethylene copolymer and the homogeneous ethylene-alpha olefin interpolymer.
16. A thin wall injection molded article having a minimum wall thickness of between 500 μm and 2.0 mm incorporating the composition of claim 1 .
17. An injection molded article of claim 16 , wherein the articles comprise crates, boxes, pails, houseware articles, furniture, drinking cups, caps and closures.