IP Library Granted Patent US 8,470,483
Granted Patent B2
US 8,470,483 · App. 12/515,600 · Granted Jun 25, 2013

Wettable gas diffusion layer for a wet seal in a fuel cell

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Quick Facts
Patent No.
US 8,470,483
App. No.
12/515,600
Granted
Jun 25, 2013
Kind
B2
Abstract

An example fuel cell stack ( 10, 40 ) includes a cathode plate ( 60 ) having oxidant flow passages ( 62 ) and coolant flow passages ( 64 ), and a porous anode plate ( 42 ) adjacent the coolant flow passages ( 64 ). The porous anode plate ( 42 ) includes fuel flow passages ( 46 ) and a network of pores ( 44 ) that fluidly connect the fuel flow passages ( 46 ) and the coolant flow passages ( 64 ). A membrane electrode arrangement ( 50 ) adjacent the fuel flow passages ( 46 ) generates electricity in a fuel cell reaction. A hydrophilic gas diffusion layer ( 48 ) between the membrane electrode arrangement ( 50 ) and the porous anode plate ( 42 ) distributes water from the coolant flow passages ( 64 ) to maintain or establish a wet seal ( 70 ) within the network of pores ( 44 ) that limits fuel transport through the network of pores ( 44 ) from the fuel flow passages ( 46 ) to the coolant flow passages ( 64 ).

Claims (26)

1. A fuel cell stack comprising:

a solid cathode plate having oxidant flow passages on one side and coolant flow passages on an opposite side;

a porous anode plate adjacent the coolant flow passages, the porous anode plate having fuel flow passages and a network of pores that fluidly connect the fuel flow passages and the coolant flow passages, and configured to provide a wet seal comprising a liquid within the network of pores from the coolant flow passages that limits fuel transport through the network of pores from the fuel flow passages to the coolant flow passages;

a membrane electrode arrangement adjacent the fuel flow passages; and

a hydrophilic gas diffusion layer between the membrane electrode arrangement and the porous anode plate, configured to distribute the liquid through the hydrophilic gas diffusion layer to a dehydrated section of the porous anode plate.

2. The fuel cell stack as recited in claim 1 , wherein one of the coolant flow passages includes a first cross-sectional area and one of the fuel flow passages includes a second cross-sectional area that is greater than the first cross-sectional area.

3. The fuel cell stack as recited in claim 1 , wherein the hydrophilic gas diffusion layer includes a carbon substrate infused with a substance having a metal oxide.

4. The fuel cell stack as recited in claim 1 , wherein the hydrophilic gas diffusion layer includes a carbon substrate infused with a substance having tin oxide.

5. The fuel cell stack as recited in claim 1 , wherein the hydrophilic gas diffusion layer includes a carbon substrate infused with a substance having titanium oxide.

6. The fuel cell stack as recited in claim 1 , further comprising another gas diffusion layer located adjacent the membrane electrode arrangement such that the hydrophilic gas diffusion layer is located adjacent one side of the membrane electrode assembly and the other gas diffusion layer is located adjacent an opposite side of the membrane electrode assembly.

7. The fuel cell stack as recited in claim 6 , wherein the hydrophilic gas diffusion layer includes a first thickness and the other gas diffusion layer includes a second thickness that is less than the first thickness.

8. The fuel cell stack as recited in claim 1 , wherein at least some of the coolant flow passages includes an open end and a closed terminal end such that the liquid within each of the coolant flow passages enters through the respective open end and exits through the network of pores in the anode porous plate.

9. The fuel cell stack as recited in claim 1 , wherein at least some of the coolant flow passages include an open end and an open terminal end such that the liquid within each of the coolant flow passages enters through the respective open end and exits through the network of pores in the anode porous plate and through the respective open terminal end.

10. A method of operating a fuel cell stack, the method comprising:

providing a fuel cell stack having a porous anode plate that includes fuel flow passages, a cathode plate having oxidant flow passages and coolant flow passages, the plates on opposite sides of a membrane electrode arrangement with a first hydrophilic gas diffusion layer adjacent one side of the membrane electrode arrangement and the fuel flow passages and a second hydrophilic gas diffusion layer adjacent an opposite side of the membrane electrode arrangement and the oxidant flow passages, the membrane electrode arrangement including a polymer exchange membrane between an anode catalyst layer and a cathode catalyst layer, the anode catalyst layer and the cathode catalyst layer each including a respective porous carbon substrate that is separate and distinct from the first hydrophilic gas diffusion layer and the second hydrophilic gas diffusion layer; and

distributing water from the first hydrophilic gas diffusion layer to flood a network of pores within the porous anode plate with the water and thereby establish a wet seal.

11. The method as recited in claim 10 , including distributing the water from a hydrated section of the porous anode plate through the first hydrophilic gas diffusion layer to a dehydrated section of the porous anode plate.

12. The method as recited in claim 10 , including distributing the water through the first hydrophilic gas diffusion layer to a dehydrated section of the porous anode plate, wherein the transient obstruction is between the dehydrated section and one of the coolant flow passages and blocks water transport from the one of the coolant flow passages to the dehydrated section.

13. The method as recited in claim 10 , including distributing the water while operating the fuel cell stack to generate electricity.

14. The method as recited in claim 10 , including moving the water through the coolant flow passages using only capillary forces.

15. A method of operating a fuel cell stack, the method comprising:

providing a fuel cell stack having a porous anode plate that includes fuel flow passages, a cathode plate having oxidant flow passages and coolant flow passages, the plates on opposite sides of a membrane electrode arrangement with, a first hydrophilic gas diffusion layer adjacent one side of the membrane electrode arrangement and the fuel flow passages and a second hydrophilic gas diffusion layer adjacent an opposite side of the membrane electrode arrangement and the oxidant flow passages, the membrane electrode arrangement including a polymer exchange membrane between an anode catalyst layer and a cathode catalyst layer, the anode catalyst layer and the cathode catalyst layer each including a respective porous carbon substrate that is separate and distinct from the first hydrophilic gas diffusion layer and the second hydrophilic gas diffusion layer; and

distributing water from the first hydrophilic gas diffusion layer to a section of the porous anode plate to thereby circumvent a transient obstruction associated with the porous anode plate that blocks water transport from one of the coolant flow passages to the section.

16. The method as recited in claim 15 , wherein the transient obstruction is a gas bubble.

17. The method as recited in claim 10 , wherein the cathode plate is solid.

18. The method as recited in claim 15 , wherein the cathode plate is solid.

Assignments (5)
CORRECTIVE ASSIGNMENT TO CORRECT ASSIGNEE ADDRESS PREVIOUSLY RECORDED AT REEL 035716, FRAME 0253. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Aug 24, 2015
From: BALLARD POWER SYSTEMS INC.
To: AUDI AG
Reel/Frame 036448/0093 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 18, 2015
From: BALLARD POWER SYSTEMS INC.
To: AUDI AG
Reel/Frame 035716/0253 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 30, 2014
From: UNITED TECHNOLOGIES CORPORATION
To: BALLARD POWER SYSTEMS INC.
Reel/Frame 033070/0235 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 19, 2013
From: UTC POWER CORPORATION
To: UNITED TECHNOLOGIES CORPORATION
Reel/Frame 031033/0325 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 20, 2009
From: BADRINARAYANAN, PARAVASTU
To: UTC POWER CORPORATION
Reel/Frame 022710/0826 →