Multi-ply self-adhesive tape
View Patent ↗Self-adhesive tape comprising a laminate composed of at least two pressure-sensitive adhesive (PSA) layers A and B laminated directly to one another, one or both of the surfaces to be laminated to one another of the PSA layers A and B having been chemically and/or physically pretreated prior to lamination, and the shear strength t S A/B of the self-adhesive tape at 25° C., 40° C. and 70° C. under a weight load of 1000 g being at least 80% of the shear strength t S o of the PSA layer A and/or of the PSA layer B, where t S o represents the shear strength of the PSA layer having the lower shear strength.
1. A self-adhesive tape comprising
a laminate including at least a first pressure-sensitive adhesive (PSA) layers A and
a second pressure-sensitive adhesive (PSA) layer B,
each layer having a lamination surface and wherein layer A and layer B are directly laminated to one another at their respective lamination surfaces, and wherein at least one of the lamination surfaces has been chemically and/or physically pretreated prior to lamination,
wherein the shear strength t s A/B of the self-adhesive tape at 25° C., 40° C. and 70° C. under a weight load of 1000 g being at least 80% of the shear strength t s o of the PSA layer A and/or of the PSA layer B, where t s o represents the shear strength of the PSA layer having the lower shear strength, and
wherein the at least first and second pressure-sensitive adhesives are composed of a copolymer of at least
a first monomer having 70% to 100% by weight of acrylic esters and/or methacrylic esters and/or their free acids, with the following formula CH 2 ═CH (R 1 )(COOR 2 ), where R 1 ═H and/or CH 3 and R 2 ═H and/or alkyl chains having 1 to 30 C atoms and being linear, branched and/or containing cyclic structural elements,
and
a second monomer having 0% to 30% by weight of olefinically unsaturated monomers.
2. The self-adhesive tape according to claim 1 , wherein the shear strength of the elf-adhesive tape at 25° C., 40° C. and 70° C. under a weight load of 1000 g is greater than 10 000 min.
3. The self-adhesive tape according to claim 1 , wherein the laminate contains a layer of a carrier material.
4. The self-adhesive tape according to claim 1 , wherein at least one of the lamination surfaces is subjected to corona treatment immediately prior to the laminating operation.
5. The self-adhesive tape according to claim 1 , wherein the at least two adhesive layers have an identical composition.
6. The self-adhesive tape according to claim 1 , wherein the at least first and second pressure-sensitive adhesive layers have a different composition.
7. The self-adhesive tape according to claim 1 , wherein the at least first and second pressure-sensitive adhesive layers are void of tackifier resins or plasticizers.
8. The self-adhesive tape according to claim 1 , wherein the at least first and second pressure-sensitive adhesive layers are composed of one or more copolymers in which acrylate monomers form the principal constituent.
9. The self-adhesive tape according to claim 1 , wherein the olefinically unsaturated monomers are containing specific functional groups or serve to set the glass transition temperature or other physical and/or chemical properties of the polymers.
10. The self-adhesive tape according to claim 9 , wherein the second monomer is a acrylic monomer which comprises acrylic and methacrylic esters with alkyl groups comprising 4 to 9 C atoms.
11. The self-adhesive tape according to claim 1 , wherein the total thickness of the self-adhesive tape is at least 100 μm.
12. The self-adhesive tape according to claim 11 , wherein the thickness of the individual PSA layers is 40 to 100 μm.
13. The self-adhesive tape according to claim 1 , wherein the pretreatment is a flame or plasma pretreatment.
14. The self-adhesive tape according to claim 13 , wherein the pretreatment takes place by corona pretreatment.
15. The self-adhesive tape according to claim 13 , wherein the pretreatment takes place by polar or reactive coating.
16. The self-adhesive tape according to claim 1 , wherein the at least first and second pressure-sensitive adhesive layers are composed of one or more copolymers in which acrylate monomers form the principal constituent.
17. The self-adhesive tape according to claim 16 , wherein the one or more copolymers are crosslinked.
18. The self-adhesive tape according to claim 1 , wherein the first monomer uses acrylic monomers which comprise acrylic and methacrylic esters with alkyl groups comprising of 4 to 14 C atoms.
19. The self-adhesive tape according to claim 18 , wherein the second monomer uses vinyl esters, vinyl ethers, vinyl halides, vinylidene halides, vinyl compounds with aromatic ring systems and heterocycles in α-position.
20. The self-adhesive tape according to claim 18 , wherein the first monomer is made of acrylic monomers which comprise acrylic and methacrylic esters with alkyl groups comprising 4 to 9 atoms.