Method for producing methacrylic alkyl esters by way of azeotropic distillation
View Patent ↗The present invention relates in general terms to a process for preparing alkyl methacrylates, comprising as steps: providing an acetone cyanohydrin by a process according to one of the preceding claims; contacting the acetone cyanohydrin with an inorganic acid to obtain a methacrylamide; contacting the methacrylamide with an alcohol in the presence of an inorganic acid in a reactor to obtain an alkyl methacrylate; continuously discharging at least a portion of the alkyl methacrylate from the reactor into a distillation column as a vapor stream; the discharge being effected by feeding a discharge stream comprising steam into the reactor, to an apparatus for preparing alkyl methacrylates, to a process for preparing polymers based at least partly on alkyl methacrylates, to the use of the alkyl methacrylates obtainable by the process according to the invention in chemical products, and to chemical products based on alkyl methacrylates obtainable by the process according to the invention.
1. A process for preparing an alkyl methacrylate, comprising:
esterifying a methacrylamide with an alcohol in the presence of an inorganic acid in a reactor comprising a battery of three or more tanks in series to obtain an alkyl methacrylate;
continuously passing steam into each of the three or more tanks;
continuously discharging at least a portion of the alkyl methacrylate from the reactor into a distillation column as a vapor stream comprising an azeotrope of at least the alkyl methacrylate and water; and
separating the azeotrope from higher boiling components of the vapor stream in the distillation column;
wherein in the battery of reaction tanks,
the first tank in the series does not have a direct vapor connection to the distillation column,
gaseous products of the first tank in the series are fed directly to the second tank, overflow of each tank is successively passed to the next tank, each tank is steam heated, a temperature of the first and second tank is 100 to about 180° C. and a temperature of the third tank and an optional fourth tank is about 120 to 140° C.
2. The process according to claim 1 , wherein the inorganic acid is sulphuric acid.
3. The process according to claim 1 , wherein the alcohol is fed into a lower region of each of the three or more tanks of the reactor.
4. The process according to claim 3 , wherein the alcohol is fed in through a porous body.
5. The process according to claim 1 , wherein the alcohol is fed in an upper region of the reactor.
6. The process according to claim 1 , wherein a distillation temperature is 50 to 120° C. in the distillation column.
7. The process according to claim 1 , wherein the separated higher boiling components are recycled into the reactor.
8. The process according to claim 1 , wherein the vapor stream is fed into the distillation column in a circular motion.
9. The process according to claim 1 , further comprising a phase separation upstream of the distillation column.