Cationic dyeable polyurethane elastic yarn and method of production
View Patent ↗Disclosed is a polyurethane elastic yarn which is excellent in elongation, resilience, heat resistance, alkali resistance, chemical resistance, and capability of being dyed with a cationic dye and which is suitable for use in a stretch cloth, a wearing apparel or the like. The polyurethane elastic yarn comprises: an elastic yarn comprising a polyurethane mainly composed of a polymer diol and a diisocyanate; and a polymer of a compound having a sulfonate group contained in the elastic yarn.
1. Polyurethane elastic yarn comprising primary structural components of polymer diol and diisocyanate, and further comprising as an additive component thereto prior to spinning a polymer which contains a sulfonate group, wherein the polymer which contains a sulfonate group comprises a monomer which has a sulfonate group that is present at a molar concentration of the monomer of at least 5 mol %, wherein said polymer which contains a sulfonate group is a formaldehyde condensation polymer.
2. The polyurethane elastic yarn according to claim 1 wherein the content of said polymer which contains a sulfonate group is from 0.5 wt % to 50 wt %.
3. The polyurethane elastic yarn according to claim 1 or 2 wherein the number-averaged molecular weight of said polymer which contains a sulfonate group is from 2000 to 500000.
4. The polyurethane elastic yarn according to claim 1 wherein said polymer which contains a sulfonate group is a copolymer of a monomer which has a sulfonate group and a monomer which has a sulfonyl group (excluding sulfonic acid).
5. The polyurethane elastic yarn according to claim 4 wherein said monomer which has a sulfonyl group (excluding sulfonic acid) is an aromatic sulfone.
6. The polyurethane elastic yarn according to claim 5 wherein said monomer which has a sulfonyl group (excluding sulfonic acid) is a dihydroxy diphenyl sulfone.
7. The polyurethane elastic yarn according to claim 4 wherein the copolymer of said monomer which has a sulfonate group and said monomer which has a sulfonyl group (excluding sulfonic acid) is a formaldehyde condensation polymer of benzene sulfonate or phenol sulfonate and 4,4′-dihydroxy diphenyl sulfone.
8. The polyurethane elastic yarn according to claim 1 wherein the b-value as determined by a Hunter type colorimeter is less than 15.
9. The polyurethane elastic yarn according to claim 1 which exhibits dyeing properties of L*≦20 when dyed with a black cationic dye.
10. The polyurethane elastic yarn according to claim 1 wherein the content of said sulfonate groups is greater than or equal to 10 millimoles/kilogram and less than or equal to 500 millimoles/kilogram.
11. Stretchable fabric wherein the polyurethane elastic yarn according to claim 1 and other fibers are blended.
12. A method of production of polyurethane elastic yarn containing a polymer which contains a sulfonate group, comprising the step of producing an elastic yarn comprising polyurethane having primary structural components of polymer diol and diisocyanate, wherein said polymer which contains a sulfonate group is a formaldehyde condensation polymer and wherein said polymer which contains a sulfonate group is added to a solution of polyurethane having primary structural components of polymer diol and diisocyanate, and spinning is performed.
13. The method of production of polyurethane elastic yarn according to claim 12 wherein said polymer which contains a sulfonate group uses a monomer which has a sulfonic acid salt.