Method for producing homogeneously crystallized polycondensate pellets
View Patent ↗The invention relates to a method for the continuous production of semicrystalline polycondensate pellets. Said method comprises the following steps: producing a polycondensate material; shaping polycondensate pellets and solidifying the polycondensate melt in a liquid cooling medium, wherein the shaping of the pellets can be carried out prior to or after solidification; separating the pellets from the liquid cooling medium once the polycondensate pellets have cooled down to an average temperature that lies within the crystallization temperature range of the polycondensate; and crystallizing the pellets in a treatment chamber, the treatment gas being led in said treatment chamber in a countercurrent to the polycondensate pellets, the flow rate of the treatment gas being above the incipient fluidization point of the polycondensate pellets and the polycondensate pellets having a narrow dwell time spectrum in the treatment chamber.
1. In a process for continuous production of semicrystalline polycondensate pellets, comprising the following steps:
producing a polycondensate melt having a crystallization temperature range;
shaping polycondensate pellets;
solidifying the polycondensate melt in a liquid coolant prior to or after the pellet shaping step;
separating the pellets from the liquid coolant, as soon as the polycondensate pellets have cooled to an average temperature which is within the crystallization temperature range of the polycondensate; and
crystallizing the pellets in a treatment space in which the pellets are maintained in a fluidized condition by means of a treatment gas, the improvement wherein:
the treatment gas in the treatment space is conducted in countercurrent with respect to the polycondensate pellets,
the flow rate of the treatment gas is slightly above the fluidization point of the polycondensate pellets, and
at least 95% of the polycondensate pellets in the treatment space have a minimum residence time of more than 20% of the average residence time.
2. The process as claimed in claim 1 , wherein treatment gas is introduced at a temperature which is above the average temperature at which the polycondensate pellets enter the treatment space.
3. The process as claimed in claim 1 , wherein the liquid coolant is circulated and heated.
4. The process of claim 1 , wherein the polycondensate is polyamide, polycarbonate, polyhydroxyalkanoate, polylactide, or polyester, or a copolymer of these and/or a mixture of these.
5. The process as claimed in claim 4 , wherein the polyester is polyethylene terephthalate (PET), polybutylene terephthalate (PBT) or polyethylene naphthalate (PEN).
6. The process as claimed in claim 1 , wherein the settling rate of the polycondensate pellets in the treatment space is greater than 0.05 m/min.
7. The process as claimed in claim 1 , wherein the settling rate of the polycondensate pellets in the treatment space is greater than 0.15 m/min.