Multicolor phosphorescent organic electroluminescent element and lighting system
View Patent ↗This invention provides a multicolor phosphorescent organic electroluminescent element having an excellent electric power efficiency, a prolonged service life, an excellent storage stability, and an excellent stability of chromaticity against drive current, and a lighting system using the multicolor phosphorescent organic electroluminescent element. The multicolor phosphorescent organic electroluminescent element contains a plurality of phosphorescent dopants different from each other in luminescence wavelength and particularly exhibits white luminescence. Specifically, the multicolor phosphorescent organic electroluminescent element contains two or more phosphorescent dopants different from each other in luminescence wavelength and comprises two or more luminescent layers, the luminescent dopant being a phosphorescent dopant. The multicolor phosphorescent organic electroluminescent element is characterized in that at least one layer formed of luminescent layer A containing two or more phosphorescent dopants different from each other in luminescence wavelength in the same layer is provided, the content of the luminescent dopant having the highest concentration used in the luminescent layer A is not less than 4% by mass and not more than 20% by mass, and luminescent layer B having a maximum luminescence wavelength of not more than 480 nm is provided at a position near the cathode side as compared with the luminescent layer A.
1. A multicolor phosphorescence light emitting organic electroluminescent element comprising two or more phosphorescence light emitting dopants which emit emission lights each having a different emission wavelength from each other, and at least two light emitting layers, provided that all of the light emitting dopants are phosphorescence light emitting dopants,
wherein one of the light emitting layers, designated as a light emitting layer A, contains the two or more phosphorescence light emitting dopants which emit the emission lights each having a different wavelength from each other in the same layer, provided that a content of the phosphorescence emitting dopant which is contained in a largest density among the phosphorescence light emitting dopants in the light emitting layer A is in the range of 4 weight % to 20 weight %; and
another one of the light emitting layers, designated as a light emitting layer B, is provided at a nearer position to a cathode than the light emitting layer A; and the light emitting layer B emits an emission light having a maximum emission wavelength of 480 nm or less.
2. The multicolor phosphorescence light emitting organic electroluminescent element of claim 1 ,
wherein the light emitting layer A and the light emitting layer B each contain the same host compound in an amount of 30 weight % or more based on a total weight of host compounds contained in each layer,
provided that the light emitting layer A contains two or more phosphorescence light emitting dopants which emit two or more emission lights each having a different emission wavelength from each other in the same layer, and the light emitting layer B is provided at a nearer position to the cathode than the light emitting layer A and the light emitting layer B emits a light having a maximum emission wavelength of 480 nm or less.
3. The multicolor phosphorescence light emitting organic electroluminescent element of claim 1 ,
wherein a host compound contained in the light emitting layer A and a host compound contained in the light emitting layer B are the same host compound,
provided that the light emitting layer A contains two or more phosphorescence light emitting dopants which emit the emission lights each having a different emission wavelength from each other in the same layer, and the light emitting layer B is provided at a nearer position to the cathode than the light emitting layer A and the light emitting layer B emits a light having a maximum emission wavelength of 480 nm or less.
4. The multicolor phosphorescence light emitting organic electroluminescent element of claim 1 ,
wherein the light emitting dopant contained in the light emitting layer B which is provided at a nearer position to the cathode and emits a light having a maximum emission wavelength of 480 nm or less is a compound having a partial structure represented by any one of Formulas (A) to (C):
wherein Ra represents a hydrogen atom, an aliphatic group, an aromatic group or a heterocyclic group; Rb and Rc each represent a hydrogen atom or a substituent; A1 represents a group of atoms necessary to form an aromatic ring or an aromatic heterocyclic ring; and M represents Ir or Pt,
wherein Ra represents a hydrogen atom, an aliphatic group, an aromatic group or a heterocyclic group; Rb, Rc, Rb 1 and Rc 1 each represent a hydrogen atom or a substituent; A1 represents a group of atoms necessary to form an aromatic ring or an aromatic heterocyclic ring; and M represents Ir or Pt,
wherein Ra represents a hydrogen atom, an aliphatic group, an aromatic group or a heterocyclic group; Rb and Rc each represent a hydrogen atom or a substituent; A1 represents a group of atoms necessary to form an aromatic ring or an aromatic heterocyclic ring; and M represents Ir or Pt.
5. The multicolor phosphorescence light emitting organic electroluminescent element of claim 1 ,
wherein the light emitting layer B which emits a light having a maximum emission wavelength of 480 nm or less contains a host compound represented by Formula (a):
wherein X represents NR′, O, S, CR′R″ or SiR′R″, R′ and R″ each represent a hydrogen atom or a substituent; Ar represents an aromatic ring; and n is an integer of 0 to 8.
6. The multicolor phosphorescence light emitting organic electroluminescent element of claim 1 ,
wherein the light emitting layer B which emits a light having a maximum emission wavelength of 480 nm or less contains a host compound having a glass transition temperature of 90° C. or more, and having a lowest excited triplet energy of 2.7 eV or more.
7. The multicolor phosphorescence light emitting organic electroluminescent element of claim 1 ,
wherein a light emitting layer C is provided between the light emitting layer B and the cathode, the light emitting layer C being adjacent to the light emitting layer B,
provided that the light emitting layer B is provided at a nearer position to the cathode than the light emitting layer A and the light emitting layer B emits a light having a maximum emission wavelength of 480 nm or less,
wherein the light emitting layer C contains the light emitting dopant which emits a light having a maximum emission wavelength at a longest wavelength among the two or more light emitting dopants contained in the light emitting layer A.
8. The multicolor phosphorescence light emitting organic electroluminescent element of claim 7 ,
wherein a light emitting layer D is provided between the light emitting layer B and the cathode, the light emitting layer D being adjacent to the light emitting layer B,
provided that the light emitting layer B is provided at a nearer position to the cathode than the light emitting layer A and the light emitting layer B emits a light having a maximum emission wavelength of 480 nm or less,
wherein the light emitting layer D contains:
the light emitting dopant which emits a light having a maximum emission wavelength at a longest wavelength among the two or more light emitting dopants contained in the light emitting layer A; and
the light emitting dopant contained in the light emitting layer B.
9. The multicolor phosphorescence light emitting organic electroluminescent element of claim 1 ,
wherein an emitted light from the organic electroluminescent element is a white color or a light bulb color which exhibits an x value of 0.37±0.1 and a y value of 0.37±0.07 in chromaticity coordinates conformed to a CIE1931 color representation.
10. A lighting device comprising the multicolor phosphorescence light emitting organic electroluminescent element of claim 1 .