Cathode for an electrochemical cell
View Patent ↗The invention provides a cathode for an electrochemical cell comprising: a first particulate material having particles comprising a mixture of at least one alkali metal halide and at least one metal; and a second particulate material comprising at least one alkali metal halide, wherein the second particulate material has a particle size smaller than that of the first particulate material.
1. A cathode for an electrochemical cell comprising:
a first particulate material having particles comprising a mixture of at least one alkali metal halide and at least one metal selected from the group consisting of iron, nickel, cobalt, chromium, manganese and mixtures thereof, wherein the at least one alkali metal halide first particulate material comprises sodium chloride;
a second particulate material consisting of sodium chloride, and
an electrolyte dispersed about the first and second particulate materials, wherein the electrolyte is a salt electrolyte that is molten at an operating temperature of the electrochemical cell; and
wherein a mean particle size ratio of the first particulate material to the second particulate material varies from 500:1 to 10:1.
2. A cathode according to claim 1 , wherein the alkali metal halide of the first particulate materials further comprises at least one of sodium fluoride, sodium iodide, or mixtures thereof.
3. A cathode according to claim 1 , wherein the first particulate material further comprises aluminum.
4. A cathode according to claim 1 , wherein the mean particle size of the first particulate material is from 400 to 1100 and wherein the mean particle size of the second particulate material is from 0.8 to 110 μm.
5. A cathode according to claim 1 , wherein the electrolyte is an alkali metal haloaluminate salt.
6. A cathode according to claim 5 , wherein the alkali metal haloaluminate salt is sodium chloroaluminate.
7. A cathode according to claim 1 , wherein the weight ratios of the first particulate material to the second particulate material vary from 10:1 to 1:1.
8. A cathode according to claim 1 , wherein the mean particle size ratio of the first particulate material to the second particulate material varies from 100:1 to 10:1.
9. The cathode for an electrochemical cell of claim 1 , wherein the first particulate material is in the form of granules, pellets, beads, or flakes, and the second particulate material is in the form of a powder.
10. The cathode for an electrochemical cell of claim 9 , wherein the second particulate material is in the form of a free-flowing powder.