Low hysteresis rubber elastomer
View Patent ↗Curable elastomer compositions and cured and/or curable articles made therefrom, the curable elastomer composition comprising an essentially unsaturated rubber elastomer, between 0.5 and 25 phr of a metal salt of a carboxylic acid, an effective amount of a peroxide curing agent for curing the elastomer composition and between 0.1 and 10. phr of a hysteresis-decreasing multifunctional curing coagent that decreases the hysteresis of the cured elastomer composition, wherein the hysteresis is measured using a rotorless shear rheometer as a loss tangent at 150° C., 41.85% strain and 10 Hz. The hysteresis of such a cured composition may decrease by at least 15% or alternatively, by at least 25%. The elastomer is useful in tires including, for example, the sidewall supports, the carcass reinforcement and the tread.
1. A curable elastomer composition for curing into a cured elastomer composition, the curable elastomer composition comprising:
an essentially unsaturated rubber elastomer;
between 0.5 and 25 parts by weight per hundred parts by weight of the rubber elastomer (phr) of a metal salt of a carboxylic acid;
an effective amount of a peroxide curing agent for curing the elastomer composition; and
between 0.1 and 10 phr of an anhydride multifunctional curing coagent that decreases the hysteresis of the cured elastomer composition as compared to the cured elastomer composition lacking the multifunctional curing coagent, wherein the hysteresis is measured using a rotorless shear rheometer as a loss tangent at 150° C., 41.85% strain and 10 Hz.
2. The composition of claim 1 , wherein the hysteresis decreases by at least 15%.
3. The composition of claim 1 , comprising:
between 0.5 and 10 phr of the metal salt of the carboxylic acid.
4. The composition of claim 1 , wherein the carboxylic acid is selected from methacrylic acid, ethacrylic acid, acrylic acid, cinnamic acid, crotonic acid, maleic acid, fumaric acid, itaconic acid, or mixtures thereof.
5. The composition of claim 1 , wherein the metal used to form the metal salt with the carboxylic acid is selected from sodium, potassium, iron, magnesium, calcium, zinc, barium, aluminum, tin, zirconium, lithium, cadmium, and cobalt or combinations thereof.
6. The composition of claim 1 , wherein the metal salt is zinc dimethacrylate, zinc diacrylate or combinations thereof.
7. The composition of claim 1 , wherein the metal salt is magnesium dimethacrylate, magnesium diacrylate or combinations thereof.
8. The composition of claim 1 , wherein the rubber elastomer is selected from polybutadienes, polyisoprenes, natural rubber, butadiene copolyniers, isoprene copolymers or mixtures thereof.
9. The composition of claim 1 , wherein the rubber elastomer is selected from butadiene-styrene copolymers, butadiene-isoprene copolymers, isoprene-styrene copolymers and isoprene-butadiene-styrene copolymers.
10. The composition of claim 1 , wherein the anhydride multifunctional curing coagent is selected from maleic anhydride, succinic anhydride or combinations thereof.
11. An article, comprising:
a cured elastomer composition, the cured elastomer composition produced by curing the curable elastomer composition of claim 1 .
12. The article of claim 11 , comprising:
the cured elastomer composition produced by curing the curable elastomer composition of claim 2 .
13. The article of claim 11 , wherein the curable rubber composition comprises a rubber elastomer selected from polybutadienes, polyisoprenes, natural rubber, butadiene copolymers, isoprene copolymers or mixtures thereof.
14. The article of claim 11 , wherein the curable rubber composition comprises a rubber elastomer selected from butadiene-styrene copolymers, butadiene-isoprene copolymers, isoprene-styrene copolymers and isoprene-butadiene-styrene copolymers.
15. The article of claim 11 , wherein the curable rubber composition comprises the anhydride multifunctional curing coagent selected from maleic anhydride, succinic anhydride or combinations thereof.
16. The article of claim 11 , wherein the article is a tire component.
17. The article of claim 11 , wherein the tire component is a sidewall