Long-fibre-reinforced, thermoplastic moulding compound, method for production thereof and use thereof
View Patent ↗A long-fiber-reinforced, thermoplastic molding compound of plastics material has outstanding impact strength and notched impact strength if it contains 30 to 90% by weight of at least one thermoplastic polyolefin, 9 to 69% by weight of at least one glass-like reinforcing fiber and 1 to 30% by weight of at least one mineral filler of an average particle size in the range from 0.1 to 2 μm. The molding compound is produced by the pultrusion method and is used in the production of domestic appliances such as washing machines or washer-dryers or electrical appliances such as coffeemakers or toasters or refrigerators or in automobile construction.
1. Long-fiber-reinforced thermoplastic molding compound from plastic, characterized in that it contains 30 to 90 wt % of at least one thermoplastic polyolefin, 9 to 69 wt % of at least one reinforcement fiber, wherein the at least one reinforcement fiber is selected from the group consisting of glass fibers, carbon fibers, and metal fibers, and 1 to 30 wt % of at least one mineral filler, characterized in that the average particle size of the mineral filler expressed as a value of d 50 ranges from 0.1 to 2 μm, wherein the mineral filler is a material selected from the group consisting of calcite, glass spheres, ground glass, gypsum, barium sulfate, and silica, the mineral filler having an aspect ratio of from 1 to 5.
2. Molding compound according to claim 1 , characterized in that it contains an additional α-olefin polymer.
3. Molding compound according to claim 1 or 2 , characterized in that the compound contains a partially crystalline polypropylene based on propylene homopolymer as the thermoplastic polyolefin, which has an isotactic fraction of >90%, a degree of crystallization >50% and a melt flow index MFI (230/5), measured according to ISO 1133 at 230° C. and a contact load of 2.16 kg from 0.5 to 70 g/10 min.
4. Molding compound according to claim 1 , characterized in that the reinforcement fiber further comprises polyamide fibers.
5. Molding compound according to claim 1 , characterized in that the compound contains glass fiber rovings that are surface treated.
6. Molding compound according to claim 1 , characterized in that the compound contains mineral fillers with an aspect ratio ranging from 1 to 2.
7. Molding compound according to claim 1 , characterized in that the mineral filler comprises calcite (CaCO 3 ).
8. Method for the production of a molding compound according to claim 1 , wherein the reinforcement fibers are initially passed together with a melt of the thermoplastic polyolefin through a nozzle, the reinforcement fibers forming a reinforcement fiber roving, the reinforcement fiber roving together with the plastic is then passed over a shaping nozzle and shaped, whereupon the formed roving is cooled, shaped, and then cut across the running direction or wound as an endless structure.
9. Method according to claim 8 , further comprising producing a rod in which the rod has a length of from 3 to 100 mm.
10. An article comprising the molding compound according to claim 1 , the article comprising a household appliance, an electrical appliance, or an automaking part.
11. An article comprising the molding compound according to claim 1 , the article comprising a computer housing, a television housing, or a mobile telephone.
12. Molding compound according to claim 1 , further comprising a polymethylpentene.
13. Molding compound according to claim 2 , wherein the additional α-olefin polymer comprises a copolymer of ethylene or propylene.
14. Molding compound according to claim 1 , wherein the thermoplastic polyolefin is a material selected from the group consisting of a partially crystalline ethylene/propylene, a propylene/1-olefin block copolymer, and a propylene/ethylene/1-olefin block terpolymer with C 4 to C 8 1-olefins with an ethylene and/or 1-olefin fraction from 2% to 30% by weight.
15. Molding compound according to claim 1 , wherein the reinforcement fiber comprising glass fibers comprises bundles of glass fibers with a diameter of 8 to 25 microns and a weight of 500 to 4800 g per 1000 m.
16. Molding compound according to claim 7 , wherein the mineral fillers have an aspect ratio of from 1 to 2.
17. Molding compound according to claim 1 , wherein the thermoplastic polyolefin has a MFI (230/5), measured according to ISO 1133 at 230° C. and a contact load of 2.16 kg of from 0.5 to 70 g/10 minutes.
18. Molding compound according to claim 17 , wherein the thermoplastic polyolefin is a material selected from the group consisting of a partially crystalline ethylene/propylene, a propylene/1-olefin block copolymer, and a propylene/ethylene/1-olefin block terpolymer with C 4 to C 8 1-olefins with an ethylene and/or 1-olefin fraction from 2% to 30% by weight.