Scavenging oxygen
View Patent ↗A container ( 22 ) includes a shell ( 24 ) made from a polymer, for example PET, and incorporating a catalyst, for example a palladium catalyst. A closure ( 40 ) incorporates a plug which includes a source of hydrogen, for example a hydride. In use, with container ( 22 ) including a beverage and closure ( 40 ) in position, the headspace in the container will be saturated with water vapor. This vapor contacts the hydride associated with plug ( 42 ) and as a result the hydride produces molecular hydrogen which migrates into the polymer matrix of shell ( 24 ) and combines with oxygen which may have entered the container through its permeable walls. A reaction between the hydrogen and oxygen takes place, catalyzed by the catalyst, and water is produced. Thus, oxygen which may ingress the container is scavenged and the contents of the container are protected from oxidation.
1. A container comprising:
a shell; and
a closure;
wherein the shell and the closure are complementary;
wherein the closure includes an active substance which releases molecular hydrogen by reaction with moisture;
wherein the active substance is dispersed in a matrix for restricting the rate at which moisture can reach the active substance, thereby reducing and controlling the rate of generation of molecular hydrogen; and
wherein the shell includes a catalyst for catalyzing a reaction between the molecular hydrogen and molecular oxygen;
wherein the active substance dispersed in the matrix is capable of generating molecular hydrogen for a period of time of at least one week.
2. A container according to claim 1 , wherein the shell further comprises a polymer resin component.
3. A container according to claim 1 wherein said shell includes at least one of a threaded neck, a capping flange, a tapered section, a base, and a body section containing said catalyst.
4. A container according to claim 1 wherein the catalyst is selected from the group consisting of Group VIII metals, Group VIII metal salts, transition metals, transition metal carbides, transition metal nitrides, transition metal borides, and combinations thereof.
5. A container according to claim 1 wherein the active substance is capable of generating molecular hydrogen for a period of time greater than a month.
6. A container according to claim 1 , wherein the active substance is capable of generating molecular hydrogen for a period of time greater than six months.
7. A container according to claim 1 , wherein the shell comprises a sidewall constructed from a composition including a polymer comprising a resin component and the catalyst; and wherein said container is a beverage container.
8. A container according to claim 1 , wherein the matrix is a polymeric matrix.
9. A container according to claim 1 wherein the active substance is selected from the group consisting of Group I, II, and Ill metals, Group I, II, and Ill metal hydrides, rare earth metals, rare earth hydrides, alkali metal borohydrides, alkaline earth metal borohydrides, alkali metal aluminum hydrides, silicon hydrides, tin hydrides, and combinations thereof.
10. A container according to claim 1 wherein the active substance is selected from the group consisting of sodium hydride, lithium hydride, sodium borohydride, sodium metal, lithium metal, potassium metal, calcium hydride, magnesium hydride, lithium aluminum hydride, and combinations thereof.
11. A container according to claim 1 wherein the matrix comprises a polyolefin.
12. A container according to claim 8 wherein the polymeric matrix is in the form of a film, sheet, disk, fiber, mat, fabric, powder, or pellet.
13. A container according to claim 8 wherein the polymeric matrix comprises polyethylene.
14. A container according to claim 8 wherein the polymeric matrix comprises ethylene vinyl acetate copolymer.
15. A container according to claim 1 wherein the container surrounds a food or beverage.
16. A container according to claim 1 wherein the container is rigid or semi-rigid.
17. A container according to claim 1 wherein the container is flexible.
18. A container according to claim 1 wherein the shell comprises a first polymeric material; and wherein the closure comprises a second polymeric material.
19. A container according to claim 1 wherein said shell comprises a polyester.
20. A container according to claim 1 wherein at least one wall of the container comprises more than one polymeric material.
21. A container according to claim 1 wherein at least one wall of the container comprises more than one layer.
22. A container according to claim 1 wherein the active substance is located behind or inside a permeable polymeric material.
23. A packaged beverage comprising a container of claim 1 in which said beverage is arranged.
24. A container according to claim 1 , wherein the ratio of the weight of active substance to matrix material is at least 0.01.
25. A container according to claim 8 , wherein the polymeric matrix includes from 1 to 16 wt % of active substance relative to the weight of polymer in the polymeric matrix.
26. A container according to claim 1 , wherein the closure comprises a selectively removable film sealed to the shell.
27. A container according to claim 1 , which includes from 0.01 ppm to 1,000 ppm of catalyst relative to the weight of said container, excluding any contents thereof.
28. A container according to claim 1 , wherein said container includes 5 ppm or less of catalyst relative to the weight of said container, excluding any contents thereof.
29. A container according to claim 1 , which has a volume in the range from 20 mL to 100 L.
30. A container according to claim 1 , said container including a permeable wall comprising one or more polymers that have in the absence of any oxygen scavenging a permeability between about 6.5×10 −7 cm 3 -cm/(m 2 -atm-day) and about 1×10 4 cm 3 -cm/(m 2 -atm-day).
31. A container according to claim 1 , wherein the matrix comprises a polymeric matrix material selected from the group consisting of low density polyethylene, high density polyethylene, polypropylene, and ethylene vinyl acetate.
32. A container according to claim 1 , wherein complementary portions of the shell and closure are screw-threaded.
33. A container according to claim 1 , wherein the closure includes a functional barrier.
34. A container according to claim 33 , wherein the functional barrier is a lidding material.
35. A container according to claim 1 , wherein the closure does not include the catalyst.
36. A container according to claim 3 , wherein the catalyst is distributed substantially throughout an entirety of the shell.
37. A container according to claim 8 , wherein the polymeric matrix includes from 4 to 8 wt % of active substance relative to the weight of polymer in the polymeric matrix.
38. A container according to claim 1 wherein the active substance is capable of generating molecular hydrogen for a period of time of at least one month.
39. A container according to claim 1 wherein the active substance is capable of generating molecular hydrogen for a period of time of at least three months.
40. A container according to claim 1 wherein the active substance is capable of generating molecular hydrogen for a period of time of at least six months.