Composite material based on polyamide and on poly(lactic acid), manufacturing process and use thereof
View Patent ↗The invention relates to a composite obtained from a composition comprising: 50 (excluded) to 90% by weight of at least one polyamide; 10 to 50% by weight of polylactic acid (PLA); and 0 to 30% by weight of at least one compatibilizing agent. The invention also relates to a process for manufacturing this composite and its use.
1. A composite composition comprising:
greater than 50% to 85% by weight, with respect to the total weight of the composition, of at least one polyamide, wherein the polyamide comprises a semi-crystalline polyamide selected from the group consisting of PA-10, PA-11, PA-6,10 and PA-10,10;
10 to 45% by weight, with respect to the total weight of the composition, of polylactic acid (PLA);
5 to 30% by weight, with respect to the total weight of the composition, of at least one functionalized polyolefin comprising α-olefin units and units selected from the group consisting of epoxide, carboxylic acid, and carboxylic acid anhydride; and
5 to 30% by weight of natural or synthetic fibers, with respect to the total weight of the composition.
2. The composite composition as claimed in claim 1 , wherein the functionalized polyolefin is selected from the group consisting of
an ethyleneacrylic estermaleic anhydride terpolymer; and
an ethylenemethyl acrylateglycidyl methacrylate terpolymer.
3. The composite composition as claimed in claim 1 , wherein the fibers are glass fibers.
4. The composite composition as claimed in claim 1 , wherein the composition further comprises at least one additive selected from the group consisting of plasticizers, impact modifiers, unfunctionalized polyolefins, dyes, pigments, brighteners, antioxidants and UV stabilizers.
5. An article comprising the composite composition of claim 1 .
6. The composite composition of claim 1 , comprising greater than 50% to 65% by weight of at least one polyamide, 30 to 45% by weight of polylactic acid (PLA); and 5 to 15% by weight of at least one functionalized polyolefin comprising α-olefin units and units selected from the group consisting of epoxide, carboxylic acid, and carboxylic acid anhydride.
7. The article of claim 5 , wherein said article is a compression-molded article, an injection-molded article, an extruded article or a thermoformed article.