ELASTOMERIC COMPOUND
The invention relates to an elastomeric compound comprising at least one olefinic elastomer comprising ethylene, an α-olefin, from 1 to 7 wt % vinyl norbornene and from 0 to 15 wt % of a second non-conjugated polyene, wherein the wt % are related to the total weight of ethylene, α-olefin, vinyl norbornene and the second non-conjugated polyene, and which elastomer has long chain branching corresponding with Δδ<20, wherein Δδ, expressed in degrees, is calculated from the difference between the phase angle δ between stress and strain in a dynamic shear measurement at 125° C. at a frequency of 0.1 rads and the phase angle δ at a frequency of 100 rad/s and the compound further comprising a solid tiller and an oil, such that the compound has a compound loading between 120 and 300 phr, wherein said olefinic elastomer satisfies the following relation S b >30, wherein S b is the slope in graph of ln(a c ) versus Φ, in which a c is the factor along which the low frequency part (ω<1 rad/s) of the phase angle δ versus ω plots, measured at at least one volume fraction Φ between 0.2 and 1 of the olefinic elastomer in squalane, must be shifted to coincide with a δ versus ω plot of an undiluted polymer (Φ=1), and wherein the δ versus ω plots results from a frequency sweep performed on a stress controlled rheometer carried out at 125° C. under nitrogen atmosphere, using a parallel plate geometry in shear. The invention further relates to a method for the preparation of the compound of the invention.
1 . An elastomeric compound comprising at least one olefinic elastomer comprising ethylene, an a-olefin, from 1 to 7 wt % vinyl norbornene and from 0 to 15 wt % of a second non-conjugated polyene, wherein the wt % are related to the total weight of ethylene, a-olefin, vinyl norbornene and the second non-conjugated polyene, and which elastomer has long chain branching corresponding with Δδ<20, wherein Δδ, expressed in degrees, is calculated from the difference between the phase angle δ between stress and strain in a dynamic shear measurement at 125° C. at a frequency of 0.1 rad/s and the phase angle δ at a frequency of 100 rad/s, the compound further comprising a solid filler and an oil, such that the compound has a compound loading between 120 and 300 phr, characterized in that the said olefinic elastomer satisfies the following relation S b >30, wherein S b is the slope in a graph of Ln(a c ) versus Φ, in which a c is the factor along which the low frequency part (ω<1 rad/s) of the phase angle δ versus ω plots, measured at at least one volume fraction Φ between 0.2 and 1 of the olefinic elastomer in squalane, must be shifted to coincide with a δ versus ω plot of an undiluted polymer (Φ=1), and wherein the δ versus ω plots results from a frequency sweep performed on a stress controlled rheometer carried out at 125° C. under nitrogen atmosphere, using a parallel plate geometry in shear.
2 . Compound according to claim 1 wherein the olefinic elastomer has a ML(1+4)125° C. according to ASTM D-1646 in the range of from 30 to 130 MU.
3 . Method for the preparation of a compound according to claim 1 , by mixing 100 phr elastomeric polymer with between 20 and 200 phr of a solid filler, an oil and other compounding ingredients, characterized in that the elastomeric polymer is prepared by polymerising at least ethylene, an alpha-olefin and vinyl norbornene in the presence of a catalyst system comprising:
a metal-organic compound of the following formula:
where:
M is a metal of group 3-13 or the lanthanide series, and p is the valency of the metal M;
A represents a neutral or anionic spectator ligand whose valency v is 0, 1 or 2, and q is an integer denoting the number of spectator ligands A;
Z is an optional bridging moiety, and n is the integer number of parallel bridging moieties Z;
Y is an amidine-containing spectator ligand represented by formula 2:
wherein the amidine-containing ligand is covalently bonded to the metal M via the imine nitrogen atom, Sub 1 is a substituent, which comprises a group 14 atom through which Sub 1 is bonded to the imine carbon atom. Sub 2 is a substituent, which comprises a heteroatom of group 15-16, through which Sub 2 is bonded to the imine carbon atom;
r is an integer>0;
L is an optional neutral Lewis basic ligand, and j is an integer denoting the number of neutral ligands L, and
X is an anionic ligand that may be independently selected from the group consisting of hydride, halide, alkyl, silyl, germyl, aryl, amide, aryloxy, alkoxy, phosphide, sulfide, acyl, pseudo halides such as cyanide, azide, and acetylacetonate, or a combination thereof. and a cocatalyst comprising an aluminoxane.
4 . Extruded part comprising a cured compound according to claim 1 .