Alkenyl aromatic foam with low solubility hydrofluorocarbon
View Patent ↗Prepare a closed-cell alkenyl aromatic polymer foam by an extrusion process using a blowing agent composition that contains at least 30 weight-percent of the chlorine-free hydrofluorocarbon blowing agent such that the foam has a density of 48 kilograms per cubic meter or less, contains more than 50 weight-percent styrene-acrylonitrile copolymer based on total polymer weight and at least eight weight-percent of a chlorine-free hydrofluorocarbon blowing agent that has a lower solubility in polystyrene than 1,1,2,2-tetrafluoroethane (HFC-134).
1. A process for preparing extruded polymer foam comprising the steps:
(a) preparing a foamable mixture of a thermoplastic polymer composition and blowing agent composition at a mixing temperature and mixing pressure in a range of 13.2 to 19.0 megaPascals;
(b) cooling the foamable mixture to a foaming temperature; and
(c) exposing the foamable mixture to an environment at a lower pressure than the mixing pressure and allowing the foamable mixture to expand into a polymer foam;
wherein, more than 95 wt % of the thermoplastic polymer composition is one or more styrene-acrylonitrile copolymer and wherein 1,1,1,2-tetrafluoroethane is present at a concentration of more than 30 weight-percent based on total blowing agent composition weight and at least eight weight-percent and 12 weight-percent or less based on thermoplastic polymer composition weight and wherein the polymer foam of step (c) is an extruded polymer foam comprising a thermoplastic polymer composition defining a plurality of cells therein, characterized by: (i) more than 95 weght-percent of the thermoplastic polymer composition is a styrene-acrylonitrile copolymer; (ii) having less than 30% open cell content according to ASTM method D6226-05; (iii) having a density of 48 kilograms per cubic meter or less according to ISO method 845-85; and (iv) containing at least eight weight-percent and 12 weight-percent or less, based on total foam weight, of 1,1,1,2-tetrafluoroethane.
2. The process of claim 1 , wherein the thermoplastic polymer composition is one or more styrene-acrylonitrile copolymer.
3. The process of claim 1 , wherein the thermoplastic polymer composition contains one weight-percent or more and 35 weight-percent or less of copolymerized acrylonitrile based on thermoplastic polymer composition weight.
4. The process of claim 1 , wherein the blowing agent composition consist of 50 weight-percent or more of 1,1,1,2-tetrafluoroethane and up to 50 weight-percent of a co-blowing agent selected from a group consisting of carbon dioxide, water, hydrocarbons having from one to seven carbons, alcohols having from two to five carbons, ether and ketones having from two to four carbons.
5. The process of claim 1 , wherein the blowing agent composition consists of 1,1,1,2-tetrafluoroethane.
6. The process of claim 1 , wherein the polymer foam has an open-cell content of less than 30 percent according to ASTM method D6226-05 and has a density of 32 kilograms per cubic meter or less according to ISO method 845-85.
7. The process of claim 6 , wherein the polymer foam has an average cell size of 0.1 millimeters or more according to ASTM method D-3756.
8. The process of claim 1 , wherein the concentration of 1,1,1,2-tetrafluoroethane is nine weight-percent or more and 12 weight-percent or less based on thermoplastic polymer composition weight.