Hydrogen peroxide detector comprising light-blocking tip with air deflector

1. An apparatus for detecting vapor-phase hydrogen peroxide, said apparatus comprising:

a housing having a passageway therethrough, said passageway comprising a portion having a non-linear path;

an inlet for receiving a vapor-phase sample in fluid communication with said passageway;

an outlet in fluid communication with said passageway;

a pump in fluid communication with said passageway, said pump suitable for drawing the vapor-phase sample from the exterior of said housing into said passageway;

a sensing assembly arranged within the housing and in fluid communication with said passageway, said sensing assembly comprising a glass capillary comprising a chemiluminescent material, and an optical light detector, said chemiluminescent material having at least component reactive with hydrogen peroxide; and

a light-blocking tip arranged within the housing, wherein the light blocking tip comprises the inlet and an air deflector component which forms the non-linear path within the light-blocking tip such that the vapor-phase sample entering the inlet is forced through the non-linear path and ambient light is substantially precluded from contacting the sensing assembly.

2. The apparatus of claim 1 , wherein said apparatus further comprises a heater constructed and arranged to heat said tip.

3. The apparatus of claim 1 , wherein said sensing assembly further comprises a heater constructed and arranged to heat said chemiluminescent material.

4. The apparatus of claim 1 , wherein said sensing assembly further comprises a single heater constructed and arranged to heat said chemiluminescent material and said tip.

5. The apparatus of claim 1 , wherein said chemiluminescent material is formed on the interior walls of the glass capillary.

6. The apparatus of claim 5 , wherein said chemiluminescent material is formed as a layer having a thickness of about 2 μm to about 10 μm.

7. The apparatus of claim 1 , further comprising a plurality of glass beads positioned within the glass capillary, said chemiluminescent material formed on the surface of the glass beads.

8. The apparatus of claim 1 , wherein said chemiluminescent material comprises a light-emitting material, a peroxide-reactive material and a carrier.

9. The apparatus of claim 8 , wherein said light-emitting compound is selected from the group consisting of: iptycene compounds, anthracenes, diphenylanthracenes, 9,10-bis(phenylethynyl) anthracene, benzanthracenes, phenanthrenes, naphthacenes, pentacenes, poly(arylene)s, poly(phenylene vinylene)s, poly(phenylene ethynylene)s, 5-amino-2,3-dihydrophthalazine-1,4-dione, 3-aminophthalhydrazide, 2,4,5-triphenylimidazole, 10,10′-dialkyl-9,9′-biacridinium salts, and 9-chlorocarbonyl-10-methylacridinium chloride.

10. The apparatus of claim 8 , wherein said peroxide reactive compound is selected from the group consisting of bis(2,4,6-trichlorophenyl) oxalate, bis(2-carbopentyloxy-3,5,6-trichlorophenyl)oxalate, or oxalic acid bis [2,4,5-trichloro-6-(pentyloxycarbonyl)phenyl]ester, bis(2-nitrophenyl) oxalate, bis(2,4-dinitrophenyl) oxalate, bis(2,6-dichloro-4-nitrophenyl) oxalate, bis(2,4,6-trichlorophenyl) oxalate, bis(3-trifluoromethyl-4-nitrophenyl) oxalate, bis(2-methyl 4,6-dinitrophenyl) oxalate, bis(1,2-dimethyl-4,6-dinitrophenyl) oxalate, bis(2,4-dichlorophenyl) oxalate, bis(2,5-dinitrophenyl) oxalate, bis(2-formyl-4-nitrophenyl) oxalate, bis(pentachlorophenyl) oxalate, bis(pentalluorophenyl) oxalate, bis(1,2-dihydro-2-oxo-l-pyridyl) glyoxal, bis-N-phthalmidyl oxalate, bis(2,4,5 trichloro-6-carbopentoxyphenyl) oxalate, bis(2,4,5-trichloro-6-carbobutoxyphenyl) oxalate, bis(2,4,6-trichlorophenyl) oxalate, and phthalimido 3,6,6-trisulfo-2-naphthyl oxalate.

11. The apparatus of claim 8 , wherein said peroxide reactive compound is an oxamide having the following formula

wherein R′ is selected from the group consisting of trifluoromethane sulfonyl, 2,4,5-trichlorophenyl, 2,3,4,5,6-pentafluorophenyl, 2,4-dinitrophenyl and phenyl and wherein R″ is selected from the group consisting of 2,4,5-trichlorophenyl, 2,3,4,5,6-pentafluorophenyl, 2,4-dinitrophenyl, phenyl.

12. The apparatus of claim 8 , wherein said peroxide reactive compound is an oxamide having the following formula

wherein R′ is a group comprising an electron withdrawing group, selected from the group consisting of nitro, cyano, carbonyl, sulfonyl and trifluoromethyl and R″ is a group comprising an electron withdrawing group, selected from the group consisting of nitro, cyano, carbonyl, sulfonyl and trifluoromethyl.

13. The apparatus of claim 8 , wherein said carrier is selected from the group consisting of: ethylene glycol ethers, diethyl ether, diamyl ether, diphenyl ether, anisole, tetrahydrofuran, dioxane, ethyl acetate, propyl formate, amyl acetate, dimethyl phthalate, diethyl phthalate, dibutyl phthalate, dioctyl phthalate, methyl formate, triacetin, diethyl oxalate, dioctyl terphthalate, citric acid ester, methyl benzoate, ethyl benzoate, butyl benzoate, benzene, ethyl benzene, butyl benzene, toluene, xylene, chlorobenzene, o-dichlorobenzene, m-dichlorobenzene, chloroform, carbon tetrachloride, hexachloroethylene, tetrachlorotetrafluoropropane, or combinations thereof.

14. The apparatus of claim 8 , wherein said chemiluminescent material further comprises a catalyst is selected from the group consisting of: sodium salicylate, tetrabutylammonium salicylate, potassium salicylate, lithium salicylate, tetrahexylammonium benzoate, benzyltrimethylammonium m-chlorobenzoate, tetraethyl ammonium stearate, calcium stearate, magnesium stearate, lithium stearate, triethylamine, pyridine, piperidine, imidazole, potassium trichlorophenoxide.

15. The apparatus of claim 8 , wherein said light-emitting material and said peroxide-reactive material have the same chemical structure.

16. The apparatus of claim 1 , wherein the air deflector component includes a C-shaped channel which does not travel through the center of the air deflector component cross-section, the C-shaped channel providing the non-linear path within the light-blocking tip.