Membrane/electrode assembly with multilayered cathode catalyst for polymer electrolyte fuel cells
View Patent ↗To provide a membrane/electrode assembly for polymer electrolyte fuel cells, a polymer electrolyte fuel cell and processes for their production, which make it possible to stably exhibit a high power generation performance in various environments. A membrane/electrode assembly for polymer electrolyte fuel cells, which comprises a first electrode having a first catalyst layer and a first gas diffusion layer, a second electrode having a second catalyst layer and a second gas diffusion layer, and a polymer electrolyte membrane disposed between the first electrode and the second electrode, wherein the 90° peel strength at least one of the interface between the first electrode and the polymer electrolyte membrane and the interface between the second electrode and the polymer electrolyte membrane is at least 0.03 N/cm.
1. A membrane/electrode assembly for polymer electrolyte fuel cells, comprising:
a first electrode having a first cathode catalyst layer and a first gas diffusion layer,
a second electrode having a second catalyst layer and a second gas diffusion layer, and
a polymer electrolyte membrane disposed between the first electrode and the second electrode,
wherein the 90° peel strength of at least one of the interface between the first electrode and the polymer electrolyte membrane and the interface between the second electrode and the polymer electrolyte membrane is at least 0.03 N/cm,
wherein the cathode catalyst layer comprises
a layer A comprising a proton-conductive polymer with an ion exchange capacity of X meq/g dry resin, wherein the layer A is in contact with the polymer electrolyte membrane, and
a layer B comprising a proton-conductive polymer with an ion exchange capacity of Y meq/g dry resin, wherein the layer B is in contact with the cathode gas diffusion layer;
and wherein said X and Y satisfy the following formulae (a) to (c) simultaneously:
1.5 <X≦ 2.0( a ), 0.9 <Y≦ 1.5( b ), and 0.18≦( X−Y ) ( c ).
2. The membrane/electrode assembly for polymer electrolyte fuel cells according to claim 1 , wherein the first catalyst layer comprises an electrode catalyst and a proton-conductive polymer; the second catalyst layer comprises an electrode catalyst and a proton-conductive polymer; said polymer electrolyte membrane is disposed between the first catalyst layer and the second catalyst layer; the polymer electrolyte membrane has a proton conductivity of at least 0.05 S/cm in an atmosphere at a temperature of 80° C. under a relative humidity of 40%; the 90° peel strength between the polymer electrolyte membrane and the first gas diffusion layer is at least 0.03 N/cm; and the dimensional change when the first gas diffusion layer is immersed in warm water of 80° C. , is less than 10%.
3. The membrane/electrode assembly for polymer electrolyte fuel cells according to claim 2 , wherein the polymer electrolyte membrane is formed by casting a liquid composition having a proton-conductive polymer dispersed in a dispersing medium.
4. The membrane/electrode assembly for polymer electrolyte fuel cells according to claim 1 , wherein the first electrode having a first catalyst layer and a first gas diffusion layer, is a cathode having the cathode catalyst layer and a cathode gas diffusion layer, and the second electrode having a second catalyst layer and a second gas diffusion layer, is an anode having an anode catalyst layer and an anode gas diffusion layer.
5. The membrane/electrode assembly for polymer electrolyte fuel cells according to claim 4 , wherein the 90° C. peel strength of at least one of the interface between the anode and the polymer electrolyte membrane and the interface between the cathode and the polymer electrolyte membrane is at least 0.1 N/cm.