IP Library Granted Patent US 8,333,947
Granted Patent B2
US 8,333,947 · App. 12/534,252 · Granted Dec 18, 2012

Method of manufacturing carbon nanotubes

Assignee: Shinshu University
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Quick Facts
Patent No.
US 8,333,947
App. No.
12/534,252
Granted
Dec 18, 2012
Kind
B2
Abstract

A method for manufacturing carbon nanotubes includes the steps of: preparing metal-containing-nanofibers which include nanofibers made of organic polymer and metal which possesses a catalytic function in forming carbon nanotubes; and forming carbon nanotubes which contain metal therein by using the nanofibers as a carbon source, wherein the carbon nanotubes are formed by putting the metal-containing-nanofibers into a heating vessel which has a substance capable of converting electromagnetic energy into heat, and by heating the metal-containing-nanofibers using heat which is generated by the heating vessel when electromagnetic energy is applied to the heating vessel.

Claims (30)

1. A method for manufacturing carbon nanotubes comprising the steps of:

preparing metal-containing-nanofibers which include nanofibers made of organic polymer and metal which possesses a catalytic function in forming carbon nanotubes; and

forming carbon nanotubes which contain metal therein by using the nanofibers as a carbon source, wherein the carbon nanotubes are formed by putting the metal-containing-nanofibers into a heating vessel which has a substance capable of converting electromagnetic energy into heat, and by heating the metal-containing-nanofibers using heat which is generated by the heating vessel when electromagnetic energy is applied to the heating vessel;

wherein the metal-containing-nanofibers are formed such that surfaces of nanofibers are coated with the metal using a vapor deposition method.

2. A method for manufacturing carbon nanotubes according to claim 1 , wherein the method further comprises a step of placing the metal-containing-nanofibers in the heating vessel between the step of preparing metal-containing-nanofibers and the step of forming carbon nanotubes.

3. A method for manufacturing carbon nanotubes according to claim 2 , wherein in the step of placing the metal-containing-nanofibers in the heating vessel, the metal-containing-nanofibers are placed in the heating vessel by putting the metal-containing-nanofibers into a reaction vessel and then placing the reaction vessel in the heating vessel.

4. A method for manufacturing carbon nanotubes according to claim 2 , wherein the step of forming carbon nanotubes includes a step of maintaining the inside of the heating vessel at a temperature of 600° C. to 900° C. for 5 to 20 minutes.

5. A method for manufacturing carbon nanotubes according to claim 1 , wherein in the step of forming carbon nanotubes, while the heating vessel generates heat by applying the electromagnetic energy to the heating vessel, the metal-containing-nanofibers gradually pass through the heating vessel so that the metal-containing-nanofibers are heated.

6. A method for manufacturing carbon nanotubes according to claim 5 , wherein in the carbon nanotubes forming step, a heat-resistant tube is arranged so that a predetermined longitudinal portion of the heat-resistant tube is positioned in the heating vessel and the reaction vessel which contains the metal-containing-nanofibers is gradually moved in the heat-resistant tube in the longitudinal direction so that the metal-containing-nanofibers gradually pass through the heating vessel.

7. A method for manufacturing carbon nanotubes according to claim 5 , wherein the step of forming carbon nanotubes, the inside of the heating vessel is heated at a temperature of 600° C. to 900° C., and the metal-containing-nanofibers gradually pass thorough the heating vessel for 5 to 20 minutes.

8. A method for manufacturing carbon nanotubes according to claim 1 , wherein the metal is at least one metal selected from a group consisting of iron, cobalt and nickel.

9. A method for manufacturing carbon nanotubes according to claim 8 , wherein the metal is nickel.

10. A method for manufacturing carbon nanotubes according to claim 1 , wherein the step of forming carbon nanotubes is carried out in an inert-gas atmosphere.

11. A method for manufacturing carbon nanotubes according to claim 1 , wherein the nanofibers are formed by an electro-spinning method which uses a solution containing a resin of the nanofibers therein.

12. A method for manufacturing carbon nanotubes comprising:

applying electromagnetic energy to a heating vessel which has a substance that converts the electromagnetic energy into heat; and

heating, with heat formed from the conversion of electromagnetic energy into heat, a reaction vessel containing metal-containing-nanofibers which include nanofibers made of organic polymer and metal which possesses a catalytic function in forming carbon nanotubes;

wherein the heating forms carbon nanotubes which contain metal therein by using the nanofibers as a carbon source;

wherein the metal-containing-nanofibers are formed such that surfaces of nanofibers are coated with the metal; and

wherein the coating on the metal-containing-nanofibers has a thickness ranging from 10 nm to 300 nm.

13. A method for manufacturing carbon nanotubes of claim 12 , wherein the formed carbon nanotubes are made in a yield greater than or equal to approximately 4% based on a carbon content of the nanofibers.

14. A method for manufacturing carbon nanotubes of claim 13 , wherein the electromagnetic energy is in the form of microwave radiation.

15. A method for manufacturing carbon nanotubes comprising:

applying electromagnetic energy to a heating vessel which has a substance that converts the electromagnetic energy into heat; and

heating, with heat formed from the conversion of electromagnetic energy into heat, a reaction vessel containing metal-containing-nanofibers which include nanofibers made of organic polymer and metal which possesses a catalytic function in forming carbon nanotubes;

wherein the heating forms carbon nanotubes which contain metal therein by using the nanofibers as a carbon source;

wherein the substance that converts the electromagnetic energy into heat is chosen from alumina, mullite, ferrite, silicon nitride, and silicon carbide: and

wherein the heating is maintained the inside of the heating vessel at a temperature of 600° C. to 900° C. for 5 to 20 minutes.

16. A method of claim 15 , wherein the heating vessel is formed using the substance that converts the electromagnetic energy into heat.

17. A method of claim 15 , wherein the heating vessel contains the substance that converts the electromagnetic energy into heat dispersed or impregnated into a wall of the heating vessel.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 29, 2016
From: SHINSHU UNIVERSITY
To: SHINSHU UNIVERSITY; ZAOZHUANG YOUYUE NANOFIBER SCIENCE AND TECHNOLOGY CO., LTD.
Reel/Frame 039034/0920 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 6, 2011
From: FINETEX ENE, INC.
To: SHINSHU UNIVERSITY
Reel/Frame 026395/0038 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 15, 2009
From: OHTA, KAZUCHIKA; KIM, ICK-SOO; KIM, BYOUNG-SUHK; PARK, JONGCHUL
To: SHINSHU UNIVERSITY; FINETEX ENE, INC.
Reel/Frame 023518/0449 →
Continuity (2)
Continuation In Part PCTJP2009059389 · May 21, 2009
Related Publication 20100296996A1 · Nov 25, 2010