IP Library Granted Patent US 8,192,714
Granted Patent B2
US 8,192,714 · App. 12/534,262 · Granted Jun 5, 2012

Method for manufacturing carbon nanotubes

Assignee: Shinshu University
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Quick Facts
Patent No.
US 8,192,714
App. No.
12/534,262
Granted
Jun 5, 2012
Kind
B2
Abstract

A method for manufacturing carbon nanotubes of the present invention includes the steps of: preparing at least one metal selected from a group consisting of iron, cobalt and nickel and an organic compound: and forming carbon nanotubes by using the organic compound as a carbon source, wherein the metal and the organic compound are put into a heating vessel having a substance capable of converting electromagnetic energy into heat, and the organic compound is brought into contact with the metal in a state where the inside of the heating vessel is heated at a temperature of 600° C. to 900° C. by applying the electromagnetic energy to the heating vessel so as to form the carbon nanotubes.

Claims (33)

1. A method for manufacturing carbon nanotubes comprising the steps of:

preparing at least one metal selected from a group consisting of iron, cobalt and nickel and an organic compound; and

forming carbon nanotubes by using the organic compound as a carbon source, wherein the metal and the organic compound are put into a heating vessel having a substance capable of converting electromagnetic energy into heat, and the organic compound is brought into contact with the metal in a state where the inside of the heating vessel is heated at a temperature of 600° C. to 900° C. by applying the electromagnetic energy to the heating vessel so as to form the carbon nanotubes;

wherein the method further comprises a step of putting the metal and the organic compound into a reaction vessel in a state where the metal and the organic compound are separated from each other between the step of preparing the metal and the organic compound and the step of forming the carbon nanotubes;

in the step of forming the carbon nanotubes, the organic compound is brought into contact with the metal in the inside of the reaction vessel;

wherein in the step of forming the carbon nanotubes, the reaction vessel is placed in the inside of the heating vessel and, thereafter, the electromagnetic energy is applied to the heating vessel so as to heat the inside of the heating vessel at a temperature of 600° C. to 900° C.; and

wherein the substance capable of converting electromagnetic energy into heat is at least one selected from a group of substances consisting of a alumina, mullite, ferrite, silicon nitride and silicon carbide.

2. A method for manufacturing carbon nanotubes according to claim 1 , wherein the step of forming the carbon nanotubes includes a step of feeding an inert gas and the organic compound to the inside of the heating vessel.

3. A method for manufacturing carbon nanotubes according to claim 1 , wherein the metal is nickel.

4. A method for manufacturing carbon nanotubes according to claim 1 , wherein the organic compound is a stearic acid.

5. A method for manufacturing carbon nanotubes comprising the steps of:

preparing at least one metal selected from a group consisting of iron, cobalt and nickel and an organic compound; and

forming carbon nanotubes by using the organic compound as a carbon source, wherein the metal and the organic compound are put into a heating vessel having a substance capable of converting electromagnetic energy into heat, and the organic compound is brought into contact with the metal in a state where the inside of the heating vessel is heated at a temperature of 600° C. to 900° C. by applying the electromagnetic energy to the heating vessel so as to form the carbon nanotubes;

wherein the method further comprises a step of putting the metal and the organic compound into a reaction vessel in a state where the metal and the organic compound are separated from each other between the step of preparing the metal and the organic compound and the step of forming the carbon nanotubes;

in the step of forming the carbon nanotubes, the organic compound is brought into contact with the metal in the inside of the reaction vessel;

wherein in the step of forming the carbon nanotubes, the reaction vessel gradually passes through the heating vessel in a state where the inside of the heating vessel is heated at a temperature of 600° C. to 900° C. by applying the electromagnetic energy to the heating vessel; and

wherein the substance capable of converting electromagnetic energy into heat is at least one selected from a group of substances consisting of a alumina, mullite, ferrite, silicon nitride and silicon carbide.

6. A method for manufacturing carbon nanotubes according to claim 5 , wherein in the step of forming the carbon nanotubes, in a state where a predetermined longitudinal portion of a heat resistant tube is arranged in the inside of the heating vessel, the reaction vessel gradually passes through the heating vessel by gradually moving the reaction vessel in the heat resistant tube in the longitudinal direction.

7. A method for manufacturing carbon nanotubes according to claim 5 , wherein the step of forming the carbon nanotubes includes a step of feeding an inert gas and the organic compound to the inside of the heating vessel.

8. A method for manufacturing carbon nanotubes according to claim 5 , wherein the metal is nickel.

9. A method for manufacturing carbon nanotubes according to claim 5 , wherein the organic compound is a stearic acid.

10. A method for manufacturing carbon nanotubes comprising the steps of:

preparing at least one metal selected from a group consisting of iron, cobalt and nickel and an organic compound; and

forming carbon nanotubes by using the organic compound as a carbon source, wherein the metal and the organic compound are put into a heating vessel having a substance capable of converting electromagnetic energy into heat, and the organic compound is brought into contact with the metal in a state where the inside of the heating vessel is heated at a temperature of 600° C. to 900° C. by applying the electromagnetic energy to the heating vessel so as to form the carbon nanotubes;

wherein the method further comprises a step of putting the metal and the organic compound into a reaction vessel in a state where the metal and the organic compound are separated from each other between the step of preparing the metal and the organic compound and the step of forming the carbon nanotubes;

in the step of forming the carbon nanotubes, the organic compound is brought into contact with the metal in the inside of the reaction vessel; and

wherein in the step of putting the metal and the organic compound into the reaction vessel, the metal is put into the reaction vessel in a state where the metal is fixed to an upper portion of the reaction vessel, and the organic compound is put into a lower portion of the reaction vessel.

11. A method for manufacturing carbon nanotubes according to claim 10 , wherein the step of forming the carbon nanotubes includes a step of feeding an inert gas and the organic compound to the inside of the heating vessel.

12. A method for manufacturing carbon nanotubes according to claim 10 , wherein the metal is nickel.

13. A method for manufacturing carbon nanotubes according to claim 10 , wherein the organic compound is a stearic acid.

14. A method for manufacturing carbon nanotubes according to claim 10 , wherein the substance capable of converting electromagnetic energy into heat is at least one selected from a group of substances consisting of a alumina, mullite, ferrite, silicon nitride and silicon carbide.

15. A method for manufacturing carbon nanotubes according to claim 10 , wherein the reaction vessel is a crucible, and the metal is coated to the inner surface of the top plate of the crucible in the step of putting the metal and the organic compound into the reaction vessel.

16. A method for manufacturing carbon nanotubes according to claim 15 , wherein in the step of putting the metal and the organic compound into the reaction vessel, a periphery of the crucible is coated with clay after the metal and the organic compound are put into the crucible.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 29, 2016
From: SHINSHU UNIVERSITY
To: SHINSHU UNIVERSITY; XUZHOU YOUWEI NANO SCIENCE AND TECHNOLOGY CO., LTD.
Reel/Frame 039034/0940 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 6, 2011
From: FINETEX ENE, INC.
To: SHINSHU UNIVERSITY
Reel/Frame 026395/0038 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 19, 2009
From: OHTA, KAZUCHIKA; KIM, ICK-SOO; KIM, BYOUNG-SUHK; PARK, JONGCHUL
To: SHINSHU UNIVERSITY; FINETEX ENE, INC.
Reel/Frame 023387/0798 →
Continuity (2)
Continuation In Part PCTJP2009051861 · Feb 4, 2009
Related Publication 20100196247A1 · Aug 5, 2010