IP Library Granted Patent US 9,539,795
Granted Patent B2
US 9,539,795 · App. 12/534,950 · Granted Jan 10, 2017

Matte substrate

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Quick Facts
Patent No.
US 9,539,795
App. No.
12/534,950
Granted
Jan 10, 2017
Kind
B2
Abstract

Matte substrates comprising a water based coating composition and a base substrate. The water based coating composition comprises either no or only small amounts of mineral filler, refractory filler and/or organic filler and no other matting agents. The water based coating composition is typically applied to the base substrate at a coating weight of less than or equal to about 3 dry pounds of the water based coating composition per about 3,000 square feet of the base substrate. The matte substrate generally has a 60° gloss less than about 20.

Claims (23)

1. A matte substrate comprising

a) a dried film formed from a water based coating composition comprising

a water base consisting of the combination of (a) a polyurethane dispersion, wherein the polyurethane dispersion comprises a water based aliphatic urethane, carboxyl or sulfonate functionality and less than about 2% N methyl pyrrolidone and (b) a binder comprising an acrylic resin; and

one or more cross-linking agents; and

b) a base substrate having a thickness of about 0.02 mil to about 25 mil selected from the group consisting of polyamide, polyester, polypropylene, polyethylene, polyvinyl chloride, styrene, foil, paper, paperboard and combinations thereof, wherein the matte substrate has a 60° gloss less than about 20;

wherein part a) is absent the addition of a mineral filler, refractory filler, organic filler, or combinations thereof.

2. The matte substrate of claim 1 wherein the one or more cross-linking agents are selected from the group consisting of aziridine, carboiimides, isocyanates, silanes, multivalent cation solutions, organometallic compounds and combinations thereof.

3. The matte substrate of claim 1 wherein the water based coating composition further comprising flow promoters, adhesion promoters or gloss enhancers.

4. The matte substrate of claim 1 wherein the water based coating composition further comprising a material selected from the group consisting of thickeners, antifoaming agents, flocculents, slip additives, wax additives and optical brighteners.

5. The matte substrate of claim 1 wherein the base substrate has a surface energy greater than about 38 dynes/cm 2 .

6. The matte substrate of claim 1 comprising a first down adhesion promoter layer having a first down adhesion promoter.

7. The matte substrate of claim 1 made by applying the water based coating composition to the base substrate at a coating weight of less than or equal to about 3 dry pounds of the water based coating composition per about 3,000 square feet of the base substrate.

8. The matte substrate of claim 7 wherein the coating weight is less than or equal to about 2.4 dry pounds of the water based coating composition per about 3,000 square feet of the base substrate.

9. The matte substrate of claim 1 wherein the water based coating composition does not curl the base substrate.

10. The matte substrate of claim 1 wherein the water based coating composition has soft touch.

11. The matte substrate of claim 1 wherein the water based coating composition is self healing.

12. The matte substrate of claim 1 comprising printing on the dried film of the water base coating composition.

13. The matte substrate of claim 1 comprising a dried film of an overcoat wherein the overcoat comprises one selected from the group consisting of an overcoat water base, an energy curable material and combinations thereof.

14. A laminated material comprising the matte substrate of claim 1 and a second material.

15. The laminated material of claim 14 wherein the second material is thermal heat sealing layer or an adhesive.

16. An over laminate material comprising the laminated material of claim 14 and an over laminated substrate.

17. The over laminate material of claim 16 wherein the over laminated substrate is selected from the group consisting of metal, wood, paper, paperboard and plastic.

18. A cover material comprising the over laminate of claim 16 and a printed substrate.

Assignments (7)
CHANGE OF ADDRESS Recorded Jul 4, 2025
From: ARKEMA FRANCE
To: ARKEMA FRANCE
Reel/Frame 071814/0739 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 8, 2022
From: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC
To: ARKEMA FRANCE
Reel/Frame 060740/0862 →
RELEASE OF PATENT SECURITY AGREEMENT Recorded Mar 18, 2013
From: THE BANK OF NOVA SCOTIA
To: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; AQUALON COMPANY; ISP INVESTMENTS INC.; HERCULES INCORPORATED
Reel/Frame 030025/0320 →
SECURITY AGREEMENT Recorded Sep 16, 2011
From: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; HERCULES INCORPORATED; AQUALON COMPANY; ISP INVESTMENT INC.
To: THE BANK OF NOVA SCOTIA, AS ADMINISTRATIVE AGENT
Reel/Frame 026918/0052 →
RELEASE OF PATENT SECURITY AGREEMENT Recorded Sep 15, 2011
From: BANK OF AMERICA, N.A.
To: ASHLAND, INC.; ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; AQUALON COMPANY; HERCULES INCORPORATED
Reel/Frame 026927/0247 →
SECURITY AGREEMENT Recorded Apr 14, 2010
From: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; AQUALON COMPANY; HERCULES INCORPORATED
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 024225/0289 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 8, 2009
From: OSCAR, DENNIS J., MR.; WASSERMAN, CHARLES J., MR.
To: ASHLAND LICENSING AND INTELLECTUAL PROPERTY, LLC
Reel/Frame 023346/0226 →