Anode active material with improved electrochemical properties and electrochemical device comprising the same
View Patent ↗Disclosed is an anode active material, comprising: (a) a carbonaceous material; and (b) a carbide coating layer partially or totally formed on a surface of the carbonaceous material, the carbide coating layer comprising at least one element selected from the group consisting of metals and metalloids. An anode obtained by using the anode active material and an electrochemical device comprising the anode are also disclosed. The carbonaceous material comprises a coating layer of metal-/metalloid-carbide obtained by treating it at high temperature under inert atmosphere, wherein the coating layer has increased interfacial boding force to the carbonaceous material and thus shows minimized reactivity to lithium. The carbonaceous material as anode active material can minimize the irreversible anode capacity needed for the formation of an SEI film during the first charge/discharge cycle, thereby providing high capacity, high efficiency and significantly improved anode qualities.
1. A method for manufacturing a carbonaceous material having a coating layer of a metal-carbide, a metalloid-carbide or a metal-metalloid-carbide, which comprises the steps of:
(a) coating a surface of carbonaceous material with a compound containing at least one element selected from the group consisting of metals and metalloids; and
(b) heat-treating the carbonaceous material coated in step (a) under inert atmosphere at a temperature equal to or higher than a temperature where the metal-carbide, the metalloid-carbide or the metal-metalloid-carbide is formed,
wherein the coating layer of the metal-carbide, the metalloid-carbide or the metal-metalloid-carbide is represented by the following Formula 1:
{—C—C—C} n {C a M b } m {M x X y } l [Formula 1]
wherein M is at least one metal or metalloid element selected from the group consisting of alkali metals, alkaline earth metals, transition metals and elements of Group 13 and Group 14;
X is an oxygen atom or a nitrogen atom;
each of n, m, x, a and b independently represent a natural number of 1 or more; and
each of l and y independently represent an integer of 0 or more.
2. The method according to claim 1 , wherein step (a) includes the steps of:
(i) dispersing or dissolving a metal compound comprising at least one element selected from the group consisting of cobalt (Co), manganese (Mn), nickel (Ni), iron (Fe), aluminum (Al), magnesium (Mg), boron (B), titanium (Ti), zirconium (Zr), zinc (Zn) and silicon (Si) and/or a metalloid compound comprising at least one element selected from the group consisting of cobalt (Co), manganese (Mn), nickel (Ni), iron (Fe), aluminum (Al), magnesium (Mg), boron (B), titanium (Ti), zirconium (Zr), zinc (Zn) and silicon (Si) into a solvent to provide a dispersion or solution containing the same compound; and
(ii) adding the dispersion or solution obtained from step (i) to the carbonaceous material, followed by stirring and drying.
3. The method according to claim 1 , wherein the solution or dispersion obtained from step (i) is added to the carbonaceous material in such an amount that the weight ratio of metal (M) or metalloid (S) to carbonaceous material (C) (M/C or S/C) ranges from 0.5 wt % to 20 wt %.
4. The method according to claim 1 , wherein the carbonaceous material is at least one selected from the group consisting of natural graphite, artificial graphite, fiber graphite, amorphous carbon and amorphous carbon-coated graphite.
5. The method according to claim 1 , wherein the heat treatment temperature ranges from 500° C. to 2000° C.
6. The method according to claim 1 , wherein the heat treatment is conducted in an inert atmosphere.
7. The method according to claim 6 , wherein the inert atmosphere includes at least one inert gas selected from the group consisting of nitrogen, argon, xenon and helium.
8. An anode active material comprising the carbonaceous material having a coating layer of a metal-carbide, a metalloid carbide or a metal-metalloid-carbide produced according to the method of claim 1 .
9. An electrochemical device comprising the anode active material according to claim 8 .
10. An electrochemical device comprising an anode active material comprising the carbonaceous material having a coating layer of a metal-carbide, a metalloid carbide or a metal-metalloid-carbide produced according to the method of claim 1 .