Polymer electrolyte fuel cell, electrolyte material therefore and method for its production
View Patent ↗An electrolyte material for a polymer electrolyte fuel cell, which is made of a copolymer comprising repeating units based on CF 2 ═CFCF 2 OCF 2 CF 2 SO 3 H and repeating units based on tetrafluoroethylene and which has an ion exchange capacity of from 0.9 to 1.5 (meq/g dry resin). This electrolyte material has ion conductivity and durability equal to conventional electrolyte material, is easy to synthesize, has a softening point higher than electrolyte material heretofore widely used for application to fuel cells and is suitable for operation of a polymer electrolyte fuel cell at a temperature higher than the conventional material.
1. A method for producing an electrolyte material for a polymer electrolyte fuel cell, which is made of a copolymer comprising repeating units obtained from a monomer of the formula (1) and repeating units obtained from tetrafluoroethylene and which has an ion exchange capacity of from 0.9 to 1.5 (meq/g dry resin), the method comprising subjecting tetrafluoroethylene and a monomer of the formula (2) in the presence of an initiator of a perfluoro compound to radical copolymerization at from 80 to 200° C. and then converting —SO 2 F groups to —SO 3 H groups:
CF 2 ═CFCF 2 OCF 2 CF 2 SO 3 H (1)
CF 2 ═CFCF 2 OCF 2 CF 2 SO 2 F (2).
2. The method for producing an electrolyte material for a polymer electrolyte fuel cell according to claim 1 , wherein the initiator of a perfluoro compound is a perfluorobenzyl peroxide.
3. The method for producing an electrolyte material for a polymer electrolyte fuel cell according to claim 1 , wherein the polymer obtained by the copolymerization of the monomer of the formula (2) and tetrafluoroethylene, has T Q of from 200 to 400° C. while T Q indicates a temperature at which, when melt-extrusion of the resin is carried out using a nozzle having a length of 1 mm and an inner diameter of 1 mm under an extrusion pressure condition of 30 kg/cm 2 , the extrusion rate would be 100 mm 3 /sec., and is obtained by hydrolysis of said polymer followed by conversion to an acid-form.
4. The method for producing an electrolyte material for a polymer electrolyte fuel cell according to claim 1 , wherein the ion exchange capacity is from 1.0 to 1.5 (meq/g dry resin).
5. The method for producing an electrolyte material for a polymer electrolyte fuel cell according to claim 1 , wherein the ion exchange capacity of from 1.1 to 1.5 (meq/g dry resin).
6. The method for producing an electrolyte material for a polymer electrolyte fuel cell according to claim 3 , wherein T Q is at most 350° C.
7. The method for producing an electrolyte material for a polymer electrolyte fuel cell according to claim 3 , wherein T Q is at most 300° C.
8. The method for producing an electrolyte material for a polymer electrolyte fuel cell according to claim 1 , wherein the copolymer additionally comprises a minor amount of repeating units obtained from another fluorinated monomer.
9. The method for producing an electrolyte material for a polymer electrolyte fuel cell according to claim 8 , wherein copolymer has a perfluoro structure.
10. The method for producing an electrolyte material for a polymer electrolyte fuel cell according to claim 1 , additionally comprising subjecting the copolymer to fluorination with fluorine gas alone or diluted with an inert gas prior to said converting.
11. The method for producing an electrolyte material for a polymer electrolyte fuel cell according to claim 10 , wherein said subjecting is at a temperature of from 150 to 200° C.
12. The method for producing an electrolyte material for a polymer electrolyte fuel cell according to claim 11 , wherein the temperature is from 170 to 190° C.
13. The method for producing an electrolyte material for a polymer electrolyte fuel cell according to claim 1 , wherein the copolymerization temperature is from 80 to 100° C.