ALIGNMENT SUBSTRATE, METHOD OF MANUFACTURING THE ALIGNMENT SUBSTRATE AND LIQUID CRYSTAL DISPLAY DEVICE HAVING THE ALIGNMENT SUBSTRATE

1 . An alignment substrate comprising:

a substrate including a plurality of unit pixel areas, each of the unit pixel areas including a plurality of sub-pixel areas arranged in a matrix configuration; and

an alignment layer on the substrate having polymer chains protruding from a surface of the alignment layer, the alignment layer having a plurality of alignment vectors in which the polymer chains are pretilted according to the sub-pixel areas, the alignment vectors corresponding to adjacent sub-pixel areas pointing in different directions from each other.

2 . The alignment substrate of claim 1 , wherein the polymer chains are photoaligned by first ultraviolet light inclined toward a column direction and second ultraviolet light inclined toward a row direction that is substantially perpendicular to the column direction, each of the alignment vectors has an x-component corresponding to the column direction, a y-component corresponding to the row direction and a z-component corresponding to a direction substantially perpendicular to the column direction and the row direction, and projected alignment vectors of adjacent sub-pixels to a surface defined by the column direction and the row direction are substantially perpendicular to each other.

3 . The alignment substrate of claim 2 , wherein the alignment vectors of adjacent sub-pixel areas which are arranged in the column direction have x-components pointing in a same direction as each other and y-components pointing in opposite directions from each other and the alignment vectors of adjacent sub-pixel areas which are arranged in the row direction have x-components pointing in opposite directions from each other and y-components pointing in a same direction as each other.

4 . The alignment substrate of claim 3 , wherein each unit pixel comprises a first sub-pixel area and a second sub-pixel area which are arranged in a first line substantially parallel with the column direction and a third sub-pixel area and a fourth sub-pixel area which are arranged in a second line substantially parallel with the column direction, and the projected alignment vectors of the first, second, third, and fourth sub-pixel areas are different from one another and point in one of directions about ±45° and about ±135° with respect to a positive column direction.

5 . The alignment substrate of claim 4 , wherein the projected alignment vectors of the first, second, third, and fourth sub-pixel areas rotate in a clockwise rotation or a reverse direction of the clockwise rotation.

6 . The alignment substrate of claim 4 , wherein the projected alignment vectors of the first, second, third, and fourth sub-pixel areas respectively point in directions about 135°, about 45°, about −135°, and about −45° with respect to the positive column direction.

7 . The alignment substrate of claim 2 , wherein the substrate comprises:

a base layer;

a gate line formed on the base layer;

a data line insulated from the gate line, the data line crossing the gate line;

a switching element electrically connected to the gate line and the data line; and

a pixel electrode electrically connected to the switching element, and

wherein the alignment layer is disposed on the pixel electrode.

8 . The alignment substrate of claim 7 , wherein the pixel electrode is formed as a single body corresponding to the sub-pixel areas.

9 . The alignment substrate of claim 2 , wherein the substrate comprises:

a base layer;

color filters disposed in the unit pixel areas; and

a common electrode disposed on the color filters, and

wherein the alignment layer is disposed on the common electrode.

10 . The alignment substrate of claim 1 , wherein the substrate includes first and second pixel electrodes disposed in each unit pixel area, a plurality of the sub-pixel areas corresponding to the first pixel electrode and a plurality of the sub-pixel areas corresponding to the second pixel electrode, the alignment layer disposed on the first and second pixel electrodes.

11 . A method of manufacturing an alignment substrate, the method comprising:

providing a substrate including a plurality of unit pixel areas, each of the unit pixel areas including a plurality of sub-pixel areas arranged in a matrix configuration;

forming a photoreactive polymer layer on the substrate; and

irradiating inclined polarized light to the photoreactive polymer layer to form an alignment layer, the alignment layer having a plurality of alignment vectors in which polymer chains protruding from the photoreactive polymer layer are pretilted according to the sub-pixel areas.

12 . The method of claim 11 , wherein the photoreactive polymer layer is photoaligned by first ultraviolet light inclined toward a column direction and second ultraviolet light inclined toward a row direction that is substantially perpendicular to the column direction, each of the alignment vectors has an x-component corresponding to the column direction, a y-component corresponding to the row direction and a z-component corresponding to a direction substantially perpendicular to the column direction and the row direction, and projected alignment vectors of adjacent sub-pixels to a surface defined by the column direction and the row direction are substantially perpendicular to each other.

13 . The method of claim 12 , wherein the alignment vectors of adjacent sub-pixel areas which are arranged in the column direction have x-components pointing in a same direction as each other and y-components pointing in opposite directions from each other and the alignment vectors of adjacent sub-pixel areas which are arranged in the row direction have x-components pointing in opposite directions from each other and y-components pointing in a same direction as each other.

14 . The method of claim 13 , wherein irradiating the inclined polarized light to the photoreactive polymer layer comprises irradiating the inclined polarized light to the photoreactive polymer layer through a mask including a light-blocking area covering a portion of the unit pixel area and a light-transmitting area exposing a remaining portion of the unit pixel area.

15 . The method of claim 14 , wherein irradiating the inclined polarized light to the photoreactive polymer layer comprises:

irradiating a first polarized light inclined toward a positive row direction or a negative row direction to the photoreactive polymer layer through a first mask covering a second sub-pixel area and a fourth sub-pixel area, which are arranged in a second row, of four sub-pixel areas arranged in a 2×2 matrix configuration and exposing a first sub-pixel area and a third sub-pixel area which are arranged in a first row;

irradiating a second polarized light inclined toward the negative row direction or the positive row direction to the photoreactive polymer layer through a second mask covering the first and third sub-pixel areas and exposing the second and fourth sub-pixel areas;

irradiating a third polarized light inclined toward a positive column direction or a negative column direction to the photoreactive polymer layer through a third mask covering the third and fourth sub-pixel areas which are arranged in a second line and exposing the first and second sub-pixel areas which are arranged in a first line; and

irradiating a fourth polarized light inclined toward the negative column direction or the positive column direction to the photoreactive polymer layer through a fourth mask exposing the third and fourth sub-pixel areas and covering the first and second sub-pixel areas.

16 . The method of claim 15 , wherein angles between the projected alignment vectors of the sub-pixels and one of the column direction and the row direction are in a range of about 40° to about 50°.

17 . The method of claim 16 , wherein the first and second polarized light have a first energy level, the third and fourth polarized light have a second energy level, and a ratio of the second energy level to the first energy level is in a range of about 0.4 to about 2.0.

18 . The method of claim 17 , wherein a ratio of the second energy level to the first energy level is in a range of about 0.4 to about 0.5.

19 . The method of claim 16 , wherein the first and second polarized light are inclined at a first angle with respect to the substrate and the third and fourth polarized light are inclined at a second angle that is identical to or larger than the first angle with respect to the substrate.

20 . The method of claim 12 , wherein the photoreactive polymer layer is formed by disposing a blend comprising a cinnamate series photoreactive polymer and a polyimide.