IP Library Granted Patent US 8,460,409
Granted Patent B2
US 8,460,409 · App. 12/537,953 · Granted Jun 11, 2013

Plasma-catalyzed fuel reformer

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Quick Facts
Patent No.
US 8,460,409
App. No.
12/537,953
Granted
Jun 11, 2013
Kind
B2
Abstract

A reformer is disclosed that includes a plasma zone to receive a pre-heated mixture of reactants and ionize the reactants by applying an electrical potential thereto. A first thermally conductive surface surrounds the plasma zone and is configured to transfer heat from an external heat source into the plasma zone. The reformer further includes a reaction zone to chemically transform the ionized reactants into synthesis gas comprising hydrogen and carbon monoxide. A second thermally conductive surface surrounds the reaction zone and is configured to transfer heat from the external heat source into the reaction zone. The first thermally conductive surface and second thermally conductive surface are both directly exposed to the external heat source. A corresponding method and system are also disclosed and claimed herein.

Claims (22)

1. A reformer comprising:

a plasma zone to receive a pre-heated mixture of reactants and ionize the reactants by applying an electrical potential thereto;

a first thermally conductive surface surrounding the plasma zone and configured to transfer heat from an external heat source into the plasma zone;

a reaction zone to chemically transform the ionized reactants into synthesis gas comprising a mixture of hydrogen and carbon monoxide; a second thermally conductive surface surrounding the reaction zone and configured to transfer heat from the external heat source into the reaction zone, wherein the second thermally conductive surface and the first thermally conductive surface are both directly exposed to the external heat source; and

a housing containing the plasma zone and reaction zone and physically configured such that the plasma zone and reaction zone are not co-axial, thereby imparting an elongated aspect ratio to the reformer, wherein the housing further comprises unobstructed open space between the plasma zone and reaction zone to facilitate heat transfer into and around the plasma and reaction zones.

2. The reformer of claim 1 , wherein the reactants comprise a feedstock fuel and an oxidant.

3. The reformer of claim 2 , wherein the first thermally conductive surface and the second thermally conductive surface have a surface area sufficient to transfer between about two and thirty percent of the heating value of the feedstock fuel present in the reformer into the plasma and reaction zones to provide the heat of reformation.

4. The reformer of claim 1 , wherein the reformer is characterized by a length and width, and wherein the aspect ratio of the length to width is greater than 1:1.

5. The reformer of claim 4 , wherein the aspect ratio of the length to width is greater than 1.5:1.

6. The reformer of claim 1 , wherein the housing is one of a U-shaped, M-shaped, and serpentine-shaped housing.

7. The reformer of claim 2 , wherein the feedstock fuel comprises at least one of a hydrocarbon and carbon.

8. The reformer of claim 2 , wherein the oxidant comprises at least one of steam, oxygen, and an oxygen-containing compound.

9. The reformer of claim 2 , wherein the oxidant is provided in substoichiometric amounts to partially oxidize the feedstock fuel.

10. The reformer of claim 1 , wherein the pre-heated mixture of reactants is provided as a vapor.

11. The reformer of claim 1 , wherein the plasma zone uses a gliding electric arc to ionize the reactants.

12. The reformer of claim 1 , wherein the reaction zone comprises a reaction bed to at least one of homogenize the reactants by mixing, and homogenize the reactants by chemical buffering.

13. The reformer of claim 1 , wherein the reaction zone comprises a reaction bed containing catalysts to promote equilibration of reactive species at temperatures lower than the temperature of reformation.

14. The reformer of claim 1 , wherein the external heat source is one of a solid-oxide fuel cell, a molten-carbonate fuel cell, a phosphoric acid fuel cell, and a Fischer-Tropsch process.

15. The reformer of claim 14 , wherein at least one reactant comprises CO 2 obtained as a product of the fuel cell reaction.

16. The reformer of claim 14 , wherein at least one reactant comprises steam obtained as a product of the fuel cell reaction.

17. The reformer of claim 1 , wherein the reformer and external heat source are disposed within an insulated enclosure.

18. The reformer of claim 1 , further comprising a heating zone to heat the preheated mixture.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 27, 2023
From: CERAMATEC, INC
To: COORSTEK, INC.
Reel/Frame 062876/0001 →
CONFIRMATORY LICENSE Recorded Apr 17, 2017
From: CERAMTEC, INC.
To: US GOVERNMENT AS REPRESENTED BY THE SECRETARY OF THE ARMY
Reel/Frame 042270/0325 →
CONFIRMATORY LICENSE Recorded Apr 24, 2014
From: CERAMATEC, INC.
To: ENERGY, UNITED STATES DEPARTMENT OF
Reel/Frame 032797/0823 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 30, 2011
From: HARTVIGSEN, JOSEPH; ELANGOVAN, S; CZERNICHOWSKI, PIOTR; HOLLIST, MICHELE
To: CERAMATEC, INC.
Reel/Frame 026533/0791 →