IP Library Granted Patent US 9,546,311
Granted Patent B2
US 9,546,311 · App. 12/542,185 · Granted Jan 17, 2017

Azeotrope-like compositions of 1,1,1,2-tetrafluoropropene and 1,1,1,2-tetrafluoroethane

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Quick Facts
Patent No.
US 9,546,311
App. No.
12/542,185
Granted
Jan 17, 2017
Kind
B2
Abstract

Provided are azeotrope-like compositions consisting essentially of 1,1,1,2-tetrafluoropropene and 1,1,1,2-tetrafluoroethane and uses thereof, including use in refrigerant compositions, refrigeration systems, blowing agent compositions, and aerosol propellants.

Claims (19)

1. A non-flammable composition consisting essentially of from about 56 weight percent to about 65 weight percent of 1,1,1,2-tetrafluoropropene and from about 35 weight percent to about to about 44 weight percent of 1,1,1,2-tetrafluoroethane to form a non-flammable composition, said composition being azeotropic at at least one concentration of the components within said range of component concentrations, said non-flammable composition having a boiling point that is below the boiling point of said 1,1,1,2-tetrafluoropropene and said 1,1,1,2-tetrafluoroethane and that is from about −29.81° C. to about −29.92° C. at a pressure of about 14.3 psia.

2. The composition of claim 1 which consists essentially of about 40 weight percent 1,1,1,2-tetrafluoroethane and about 60 weight percent of 1,1,1,2-tetrafluoropropene.

3. The composition of claim 1 which consists of about 40 weight percent 1,1,1,2-tetrafluoroethane and about 60 weight percent of 1,1,1,2-tetrafluoropropene.

4. A solvent consisting essentially of the composition of claim 1 .

5. A blowing agent consisting essentially of a composition of claim 1 .

6. A foam premix composition comprising a polyol and blowing agent of claim 5 .

7. A foam comprising a plurality of polymeric cells and a composition contained in at least one of said cells, said composition comprising a blowing agent of claim 5 .

8. A foamable composition comprising and at least one thermoset foam component and a blowing agent consisting essentially of a composition of claim 1 .

9. The foamable composition of claim 8 , wherein said at least one thermoset component comprises a composition capable of forming a polyurethane foam, a phenolic foam, or a polyisocyanurate foam.

10. A foamable composition comprising at least one thermoplastic foam component and a blowing agent consisting essentially of a composition of claim 1 .

11. The foamable composition of claim 10 wherein said thermoplastic foam component comprises a polystyrene, polyethylene, polypropylene, polyethyleneterephthalate, and combinations of these.

12. A sprayable composition comprising a material to be sprayed and a propellant consisting essentially of a composition of claim 1 .

13. A sprayable composition according to claim 12 wherein the material to be sprayed comprises a drug, a biologically active material, a deodorant, a perfume, a hair spray, a cleanser, a wax, a defluxing agent, a polishing agent, a room freshener, an insecticide, a cooking oil, or combinations thereof.

14. A refrigerant composition comprising the composition of claim 1 .

15. A method for cooling an article which comprises condensing a refrigerant composition of claim 14 and thereafter evaporating said refrigerant composition in the vicinity of the article to be cooled.

16. A method for heating an article which comprises condensing a refrigerant composition of claim 14 in the vicinity of the article to be heated and thereafter evaporating said refrigerant composition.

17. A method of recharging a refrigerant system that contains a refrigerant to be replaced and a lubricant comprising the steps of: (a) removing the refrigerant to be replaced from the refrigeration system while retaining a substantial portion of the lubricant in said system; and (b) introducing to the system a refrigerant composition of claim 14 .

18. A method for modifying a refrigeration apparatus which refrigeration apparatus comprises a refrigerant and a lubricant, which refrigerant comprises a chlorofluorocarbon, a hydrofluorocarbon, a hydrochlorofluorocarbon, a chlorofluorcarbon, or combinations thereof, and the lubricant comprises a mineral oil, alkybenezene, polyalphaolefin, polyol ester, polyakylene glycol, polyvinyl ether, synthetic naphthalene, fluorolubricant or combinations thereof, the method comprising removing or leaking at least a portion of the refrigerant from the refrigeration apparatus and leaving a residue comprising the lubricant, and adding to said residue a composition consisting essentially of the composition of claim 1 .

19. A refrigeration system comprising a refrigerant consisting essentially of the composition of claim 1 .

Assignments (2)
SECURITY INTEREST Recorded Jan 12, 2026
From: SOLSTICE ADVANCED MATERIALS US, INC.
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 074569/0260 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 17, 2009
From: SEETON, CHRISTOPHER J.; PHAM, HANG T.; SINGH, RAJIV R.; HULSE, RYAN; SPATZ, MARK W.; WILSON, DAVID P.; YANA MOTTA, SAMUEL F.
To: HONEYWELL INTERNATIONAL INC.
Reel/Frame 023106/0009 →