Cathode material for Li ion secondary battery and Li ion secondary battery using the same
View Patent ↗A cathode material with excellent capacity and output characteristics and safety, and a lithium ion secondary battery using the same is provided. The invention relates to a cathode material which includes a mixture of a cathode active material having a large primary particle size with excellent capacity characteristics and represented by the composition formula: Li x1 Ni a1 Mn b1 Co c1 O 2 , where 0.2≦x1≦1.2, 0.6≦a1, 0.05≦b1≦0.3, 0.05≦c1≦0.3, and another cathode active material having a small primary particle size with excellent output characteristics and represented by the composition formula: Li x2 Ni a2 Mn b2 Co c2 O 2 , where 0.2≦x2≦1.2, a2≦0.5, 0.05≦b2≦0.5, 0.05≦c2≦0.5. The invention also relates to a lithium ion secondary battery using the cathode material.
1. A lithium ion secondary battery including a cathode for absorbing and releasing lithium and an anode for absorbing and releasing lithium which are formed with an electrolyte positioned therebetween,
wherein the cathode comprises a cathode active material, a cathode mixture containing a carbon-based conductive agent and a binder, and a current collector, the cathode active material comprising:
a first cathode active material represented by the composition formula: Li x1 Ni a1 Mn b1 Co c1 O 2 , where 0.2≦x1≦1.2, 0.7≦a1≦0.9, 0.05≦b1≦0.3, 0.05≦c1≦0.3, and
a second cathode active material represented by the composition formula: Li x2 Ni a2 Mn b2 Co c2 O 2 , where 0.2≦x2≦1.2, 0.4≦a2≦0.5, 0.05≦b2≦0.5, 0.05≦c2≦0.5,
wherein a content of the first cathode active material in the cathode active material is not less than 15% nor more than 70% in terms of percentage by mass,
wherein a difference in Ni content between the first cathode active material and the second cathode active material is equal to or more than 20% and equal to or less than 90% in terms of atomic percentage, and
wherein the first cathode active material has an average primary particle size of not less than 1 μm nor more than 3 μm,
the second cathode active material has an average primary particle size of not less than 0.05 μm nor more than 0.5 μm,
an average secondary particle size of the first cathode active material is 1.5 times or more as large as an average secondary particle size of the second cathode active material, and
the average secondary particle size of the first cathode active material is equal to or more than 5 μm and equal to or less than 30 μm, and the average secondary particle size of the second cathode active material is equal to or more than 2 μm and equal to or less than 10 μm.
2. The lithium ion secondary battery according to claim 1 ,
wherein the first cathode active material is represented by the composition formula: Li x1 Ni a1 Mn b1 Co c1 O 2 , where 0.2≦x1≦1.0, a1 is 0.7, 0.05≦b1≦0.3, 0.05≦c1≦0.3,
the second cathode active material is represented by the composition formula: Li x2 Ni a2 Mn b2 Co c2 O 2 , where 0.2≦x2≦1.0, 0.4<a2≦0.5, 0.05≦b2≦0.5, 0.05≦c2≦0.5, and
the difference in Ni content between the first cathode active material and the second cathode active material is equal to or more than 20% and equal to or less than 30% in terms of atomic percentage.