Process for enhanced total organic carbon removal while maintaining optimum membrane filter performance
View Patent ↗A system and process for enhancing total organic carbon (“TOC”) removal from raw, untreated water while maintaining optimum membrane filter performance. The present invention overcomes many of the disadvantages of prior art water filtration systems by controlling the pH level of the water, prior to the water being directed through said membrane filter, so that the particulate charge of the water aligns with the electromagnetic surface charge of membrane filter. Maintaining the particulate charge of the water within an optimum charge window for the particular membrane filter enhances the membrane filter's performance by decreasing the fouling rate of the membrane filter.
1. A process for optimizing the removal of total organic carbon (TOC) from water while enhancing the performance of a membrane filter, comprising:
monitoring a TOC level of said water;
dispersing an effective amount of a coagulant into said water based on the TOC level;
monitoring a pH level of said water; and
adjusting the pH level of said water, prior to said water being directed through said membrane filter, to align the particulate charge of said water with an electromagnetic surface charge of said membrane filter by measuring the particulate charge of said water using a micro amp streaming current monitor and dosing said water with acid or base to maintain the particulate charge of said water within an optimum charge window of between −9.8 and −9.4 micro amps for said membrane filter.
2. The process of claim 1 , wherein said effective amount of coagulant is further based upon at least one of a volume and temperature of said water.
3. The process of claim 1 , further comprising suppressing the pH of said water prior to said coagulant dispersing step.
4. The process of claim 3 , wherein said suppressing the pH of said water includes dosing said water with acid or base to maintain a pH of 4.0 to 6.0 standard units.
5. The process of claim 1 , further comprising directing said water through a mechanical clarifier device prior to said adjusting step, but after said coagulant dispersing step.
6. The process of claim 2 , wherein said effective amount of coagulant is further based upon the optimum charge window for said membrane filter.
7. The process of claim 1 , further comprising monitoring a trans-membrane pressure of said membrane filter and preventing said water from being directed through said membrane filter when said trans-membrane pressure exceeds a predetermined value.
8. The method of claim 1 , wherein the coagulant is dispersed in a first stage and the particulate charge is aligned with the electromagnetic surface charge of said membrane filter in a second stage.
9. The method of claim 8 , wherein a first pH level is maintained in the first stage to maximize TOC removal during liquids-solids filtration, and wherein a second pH level is maintained in the second stage to optimize performance of said membrane filter.
10. The method of claim 9 , wherein the first pH level is 4.0 to 6.0 and the second pH level is 7.0 to 8.0.
11. The method of claim 9 , wherein the first pH level is maintained upstream of a clarifier, and wherein the second pH level is maintained downstream of the clarifier and upstream of said membrane filter.
12. The method of claim 1 , wherein coagulant is dispersed and the pH level is adjusted in a single stage upstream of said membrane filter to achieve as much TOC removal as possible while optimizing membrane performance.
13. The method of claim 12 , wherein said water bypasses a clarification operation.
14. The method of claim 1 , further comprising dosing chlorine to treated water downstream of said membrane filter.