Flame retardant thermoplastic polycarbonate compositions and films made therefrom
View Patent ↗Described herein is a thermoplastic composition comprising a polycarbonate, a mineral filler, inorganic acid or acid salt, an anti-drip agent, and a flame retardant comprising a perfluoroalkyl sulfonate salt or a combination of an aromatic phosphate ester and a polycarbonate-siloxane block copolymer.
1. A thermoplastic composition comprising
80 to 95 weight percent of a polycarbonate;
3 to 7 weight percent of a talc having an average particle size less than or equal to 5.0 micrometers;
an inorganic acid or acid salt comprising a phosphorous containing oxy-acid, a mono zinc phosphate, a mono calcium phosphate, a mono natrium phosphate, or a combination comprising one or more of the foregoing;
0.10 to 0.50 weight percent of an encapsulated fluoropolymer; and
greater than 0.40 to 1.00 weight percent of a perfluoroalkyl sulfonate salt,
wherein weight percent is based on the total weight of the composition and the weight ratio of inorganic acid or acid salt to talc is 0.01 to 0.04;
wherein the thermoplastic composition has a flame retardancy rating of V0 when in the form of a sheet having a thickness of 0.43 mm according to UL94; and
wherein the thermoplastic composition is free of an aromatic phosphate ester and a polycarbonate-siloxane block copolymer.
2. The thermoplastic composition of claim 1 , wherein the average particle size less than or equal to 3.0 micrometers.
3. The thermoplastic composition of claim 1 , comprising 4 to 7 weight percent of the talc.
4. The thermoplastic composition of claim 1 , comprising 0.20 to 0.45 weight percent of the encapsulated fluoropolymer.
5. The thermoplastic composition of claim 1 , wherein the perfluoroalkyl sulfonate salt is a perfluorobutane sulfonate salt.
6. The thermoplastic composition of claim 1 , comprising 0.45 to 0.80 weight percent of the perfluoroalkyl sulfonate salt.
7. The thermoplastic composition of claim 1 , wherein the inorganic acid or acid salt comprises the phosphorous containing oxy-acid; wherein the phosphorous containing oxy-acid has a formula of H m P t O n , wherein m and n are each 2 or greater and t is 1 or greater.
8. The thermoplastic composition of claim 1 , wherein the inorganic acid or acid salt comprises the phosphorous containing oxy-acid; and wherein the phosphorous containing oxy-acid comprises phosphoric acid, phosphorous acid, hypophosphorous acid, hypophosphoric acid, phosphinic acid, phosphonic acid, metaphosphoric acid, hexametaphosphoric acid, thiophosphoric acid, fluorophosphoric acid, difluorophosphoric acid, fluorophosphorous acid, difluorophosphorous acid, fluorohypophosphorous acid, fluorohypophosphoric acid, or a combination comprising at least one of the foregoing.
9. The thermoplastic composition of claim 1 , comprising 4 to 7 weight percent of the talc; 0.20 to 0.45 weight percent of the encapsulated fluoropolymer; and 0.45 to 0.80 weight percent of the perfluoroalkyl sulfonate salt.
10. The thermoplastic composition of claim 1 , having a flame retardancy rating of V0 when in the form of a sheet having a thickness of 0.38 mm according to UL94.
11. The thermoplastic composition of claim 1 , wherein the thermoplastic composition has an HDT greater than or equal to 130 degrees Celsius according to ASTM D648.
12. The thermoplastic composition of claim 1 , wherein the thermoplastic composition has a notched Izod impact strength greater than or equal to 1000 Joules/meter according to ASTM D256 at 23 degrees Celsius.
13. A film comprising the thermoplastic composition of claim 1 .
14. The film of claim 13 , wherein the film is a multi-layer film.
15. The film of claim 13 having a thickness of 0.1 to 0.5 millimeters.
16. The thermoplastic composition of claim 1 , further comprising a colorant.