Ni-base alloy, high-temperature member for steam turbine and welded rotor for turbine using the same, and method for manufacturing the same
View Patent ↗The present invention provides, in a γ′ phase precipitation strengthening type Ni-base alloy, an alloy excellent in heat treatment capability and weldability and suitable for joint with a ferritic steel. Further, the present invention provides a welded turbine rotor having the strength, ductility, and toughness simultaneously over the whole welded structure when a precipitation strengthening type Ni-base alloy having a heatproof temperature of 675° C. or higher is joined to a ferritic steel. A Ni-base alloy according to the present invention contains cobalt, chromium, aluminum, carbon, boron, and at least either tungsten or molybdenum with the remainder being nickel and inevitable impurities, having an alloy composition including 12 to 25 percent by mass of Co, 10 to 18 percent by mass of Cr, 2.0 to 3.6 percent by mass of Al, 0.01 to 0.15 percent by mass of C, 0.001 to 0.03 percent by mass of B, the total amount of tungsten and molybdenum being 5.0 to 10 percent by mass. A welded turbine rotor is structured by joining or building up by welding a second Ni-base alloy to a first Ni-base alloy that a γ′ phase solid solution temperature thereof is 900° C. or higher and a creep fracture strength at 675° C. is 100 MPa or more, and further welding a ferritic steel to the second Ni-base alloy. The second Ni-base alloy is a γ′ phase (Ni 3 Al) precipitation strengthening type Ni-base alloy, a γ′ phase solid solution temperature thereof is 850° C. or lower.
1. A welded turbine rotor configured by integrating a nickel member comprising a first Ni-base alloy and a steel member comprising a ferritic steel through a second Ni-base alloy,
wherein the second Ni-base alloy is interposed between the ferritic steel and the first Ni-based alloy,
wherein the first Ni-base alloy is a Ni-base alloy having a γ′ phase solid solution temperature of 900° C. or higher and a creep fracture strength at 675° C. of 100 MPa or more,
wherein the second Ni-base alloy is a γ′ phase precipitation strengthening type Ni-base alloy having a γ′ phase solid solution temperature of 850° C. or lower, and a γ′ phase precipitate of 10% to 25% by volume, and the second Ni-base alloy contains essentially no Ti, Nb, and Ta, and
wherein the second Ni-base alloy includes 5 to 12 percent by mass of W and Mo in total, and 3 to 12 percent by mass of Mo.
2. The welded turbine rotor according to claim 1 , wherein
the second Ni-base alloy is joined by welding to the nickel member, and
the second Ni-base alloy is joined by welding to the steel member.
3. The welded turbine rotor according to claim 1 , wherein the nickel member and the steel member are welded to each other by using the second Ni-base alloy as a weld metal.
4. A steam turbine including the welded turbine rotor according to claim 1 , and the steam turbine configured for operation in a main steam temperature of 675° C. or higher.
5. The welded turbine rotor according to claim 1 , wherein the second Ni-base alloy is a Ni-base alloy consisting of 0.001 to 0.1 percent by mass of C, 10 to 20 percent by mass of Cr, 2.0 to 3.0 percent by mass of Al, 0 to 23 percent by mass of Co, 5 to 12 percent by mass of W and Mo in total, and 3 to 12 percent by mass of Mo, with the remainder being Ni and inevitable impurities.
6. A welded turbine rotor configured by integrating a nickel member comprising a first Ni-base alloy and a steel member comprising a ferritic steel through a second Ni-base alloy,
wherein the second Ni-base alloy is interposed between the ferritic steel and the first Ni-based alloy,
wherein the first Ni-base alloy has a γ′ phase solid solution temperature of 900° C. or higher, and a creep fracture strength at 675° C. of 100 MPa or more,
wherein the second Ni-base alloy is a γ′ phase precipitation strengthening type Ni-base alloy consisting essentially of 0.001 to 0.1 percent by mass of C, 10 to 20 percent by mass of Cr, 2.0 to 3.0 percent by mass of Al, 5 to 12 percent by mass of W and Mo in total, 3 to 12 percent by mass of Mo, and the balance being Ni, and
wherein the second Ni-base alloy has a γ′ phase solid solution temperature of 850° C. or lower, and a γ′ phase precipitate of 10% to 25% by volume, and the second Ni-base alloy contains essentially no Ti, Nb, and Ta.
7. The welded turbine rotor according to claim 6 , wherein
the second Ni-base alloy is joined by welding to the nickel member, and
the second Ni-base alloy is joined by welding to the steel member.
8. The welded turbine rotor according to claim 6 , wherein the nickel member and the steel member are welded to each other by using the second Ni-base alloy as a weld metal.
9. A steam turbine including the welded turbine rotor according to claim 6 , and the steam turbine configured for operation in a main steam temperature of 675° C. or higher.
10. The welded turbine rotor according to claim 1 , wherein a 0.2% proof stress of the second Ni-base alloy at 650° C. is 405 to 450 MPa.
11. The welded turbine rotor according to claim 6 , wherein a 0.2% proof stress of the second Ni-base alloy at 650° C. is 405 to 450 MPa.
12. The welded turbine rotor according to claim 1 , wherein a 0.2% proof stress of the second Ni-base alloy at 650° C. is 450 MPa.
13. The welded turbine rotor according to claim 6 , wherein a 0.2% proof stress of the second Ni-base alloy at 650° C. is 450 MPa.