Nanocomposites
View Patent ↗This invention provides composite materials comprising nanostructures (e.g., nanowires, branched nanowires, nanotetrapods, nanocrystals, and nanoparticles). Methods and compositions for making such nanocomposites are also provided, as are articles comprising such composites. Waveguides and light concentrators comprising nanostructures (not necessarily as part of a nanocomposite) are additional features of the invention.
1. A waveguide, comprising:
a cladding; and
a first core, the core having a first surface and a second surface that are substantially parallel to each other, the core having a higher index of refraction than the cladding;
and a first layer distributed within the first core comprising one or more nanowires or one or more branched nanowires and a matrix, and the core being in contact with the cladding over at least a majority of the first and second surfaces of the core.
2. A waveguide as in claim 1 , wherein the one or more branched nanowires comprise one or more nanotetrapods.
3. A waveguide as in claim 1 , wherein the cladding is air.
4. A waveguide as in claim 1 , wherein the waveguide is a flat sheet.
5. A waveguide as in claim 1 , wherein the core has an index of refraction between about 1.35 and about 4.
6. A waveguide as in claim 1 , wherein the matrix is substantially nonabsorbing and nonscattering with respect to light at wavelengths greater than about 300 nm.
7. A waveguide as in claim 1 , wherein the matrix comprises a glass, a polymer, a small molecule or molecular matrix, a liquid, a crystal, or a polycrystal.
8. A waveguide as in claim 1 , wherein the one or more nanowires have an average diameter between about 2 nm and about 100 nm or between about 2 nm and about 20 nm.
9. A waveguide as in claim 1 , wherein the one or more nanowires have an aspect ratio between about 1.5 and about 100, or between about 5 and about 30.
10. A waveguide as in claim 1 , wherein the waveguide comprises a plurality of nanowires.
11. A waveguide as in claim 10 , wherein the orientation of the nanowires is substantially nonrandom, with a vector average of the nanowires' orientations having a nonzero component perpendicular to the first surface of the core.
12. A waveguide as in claim 11 , wherein at least 1%, at least 10%, or at least 50% of the total nanowires within the core are substantially nonrandomly oriented.
13. A waveguide as in claim 11 , wherein a majority of the nanowires each has a long axis oriented more nearly perpendicular than parallel to the first surface of the core.
14. A waveguide as in claim 11 , wherein the plurality of nanowires form a liquid crystal phase in which each nanowire has a long axis oriented substantially normal to the first surface of the core.
15. A waveguide as in claim 10 , wherein the nanowires absorb light impinging on the first or second surface of the core and emit light, and wherein the nanowires are oriented within the core such that a majority of the light emitted from the nanowires is emitted at an angle greater than the critical angle crit, where crit=sin−1(nr/ni), nr is the index of refraction of the cladding, and ni is the index of refraction of the core, thereby directing a majority of the emitted light toward at least one edge of the core, providing a light concentrator.
16. A waveguide as in claim 1 , wherein the one or more nanowires or one or more branched nanowires comprise one or more of: a fluorescent material, a semiconducting material, a material comprising a first element selected from group 2 of the periodic table and a second element selected from group 16, a material comprising a first element selected from group 12 and a second element selected from group 16, a material comprising a first element selected from group 13 and a second element selected from group 15, a material comprising a group 14 element, or an alloy or a mixture thereof.
17. A waveguide as in claim 16 , wherein the one or more nanowires or one or more branched nanowires comprise one or more of: ZnS, ZnSe, ZnTe, CdS, CdSe, CdTe, HgS, HgSe, HgTe, MgS, MgSe, MgTe, CaS, CaSe, CaTe, SrS, SrSe, SrTe, BaS, BaSe, BaTe, GaN, GaP, GaAs, GaSb, InN, InP, InAs, InSb, Ge, Si, PbS, PbSe, PbTe, AlS, AlP, AlSb, or an alloy or a mixture thereof.
18. A waveguide as in claim 1 , wherein the one or more nanowires or one or more branched nanowires comprise one or more materials, each material having a band-gap energy between about 0.4 eV and about 4.1 eV.
19. A waveguide as in claim 1 , wherein the one or more nanowires or one or more branched nanowires are heterostructures comprising at least two different materials.
20. A waveguide as in claim 19 , wherein the at least two materials are distributed radially about a long axis of the one or more nanowires or about a long axis of an arm of the one or more branched nanowires.
21. A waveguide as in claim 1 , wherein at least one collector which collects waveguided light is operably connected to at least one edge of the core.
22. A multilayer light concentrator comprising: a stack comprising two or more waveguides as described in claim 1 .
23. A multilayer light concentrator as described in claim 22 , wherein the two or more waveguides comprise one or more nanowires or one or more branched nanowires that absorb light of different wavelengths, and wherein the waveguide comprising the one or more nanowires or one or more branched nanowires that absorb the shortest wavelength light is located closest to a light source and the waveguide comprising the one or more nanowires or one or more branched nanowires that absorb the longest wavelength light is located farthest from the light source.