Temperature compensated valve for gas chromatography

1. A multiport gas chromatograph diaphragm-sealed valve comprising:

a valve cap comprising a plurality of process conduits extending therethrough, each of the process conduits ending in a process port;

a valve body facing the valve cap, the valve body comprising plunger passages extending therein and in alignment with the respective process conduits;

a diaphragm positioned between the valve cap and the valve body, the diaphragm having temperature characteristics; and

a plunger assembly comprising:

a plunger-actuating mechanism located within the valve body; and

a plurality of normally-closed and normally-opened plungers slidably fitting in the respective passages of the valve body, said plungers being simultaneously actuated by the plunger-actuating mechanism, each plunger comprising:

a base member operatively connected to the actuating mechanism;

an upper member projecting towards the diaphragm, for pressing the diaphragm in a closed position, or extending away from the diaphragm in an opened position, the upper member having a longitudinal play within a corresponding one of the passages with respect to the base member; and

a resilient middle element provided between the base member and the upper member, said resilient middle element being made of a material which is based on the temperature characteristics of the diaphragm, the resilient middle element decreasing a sealing force on the diaphragm when the operating temperature of the valve increases, the force profile of the resilient element matching a varying pressure profile required to maintain proper sealing of the plunger on the diaphragm over an operating temperature range varying from 0 to 350° C.

each of said plungers thereby providing an active temperature mechanical feedback loop when in use within the multiport gas chromatograph diaphragm-sealed valve.

2. The multiport gas chromatograph diaphragm-sealed valve according to claim 1 , wherein for each plunger, the resilient middle element is selected from the group consisting of rings made of a compressible material, a sleeve made of polymer or silicone, helicoidal springs and Belleville-type springs.

3. The multiport gas chromatograph diaphragm-sealed valve according to claim 1 , wherein the upper member of each plunger comprises a head portion for contacting the diaphragm, and a base portion larger than the head portion, the base portion extending from and being integrally formed with the head portion, further comprises a spring element surrounding said head portion to bias the upper member away from said diaphragm.

4. The multiport gas chromatograph diaphragm-sealed valve according to claim 1 , wherein the base member of each of said plungers has a threaded bottom portion, and said plunger-actuating mechanism comprises at least one support element movable within said valve body with respect to said diaphragm, the at least one support element being provided with a corresponding threaded opening for receiving the threaded bottom portion of each plunger.

5. The multiport gas chromatograph diaphragm-sealed valve according to claim 1 , wherein for each plunger:

the upper member comprises a head portion for projecting towards said diaphragm, a neck portion holding the resilient middle element and an anchor portion interlocked and in contact with the base member, the head, neck and anchor portions being integrally part of the upper member;

the base member has an abutment surface; and

the resilient middle element has opposite ends in abutment with the head portion of the upper member and the abutment surface of the base member, respectively.

6. The multiport gas chromatograph diaphragm-sealed valve according to claim 5 , wherein for each plunger, the base member comprises a recess extending internally and longitudinally therein and opening upwardly, the resilient middle element being at least partially received within said recess, a bottom surface of said recess defining the abutment surface.

7. The multiport gas chromatograph diaphragm-sealed valve according to claim 5 , wherein for each plunger:

the anchor portion of the upper member has a width greater than said neck portion; and

the base member comprises:

a cavity for receiving said anchor portion, said cavity being sized to provide a longitudinal clearance for the anchor portion therein to define said longitudinal play;

a bore extending longitudinally therein and having opposite extremities opening on the abutment surface of said base member and said cavity, respectively, the bore being sized to receive a section of the neck portion of the upper member therein, a transition between the bore and cavity defining a shoulder for holding the anchor portion within said cavity, and

a transversal slot opening on a side of the base member for providing access to the cavity for removably assembling the base member and the upper member,

the bore and cavity being sized to provide a transversal clearance for the neck portion and anchor portion respectively therein, thereby defining a transversal play between the upper member and base member.

8. The multiport gas chromatograph diaphragm-sealed valve according to claim 5 , wherein each plunger comprises a retention pin for connecting the upper member to the base member,

the base member and anchor portion of the upper member respectively have a pin channel and a pin hole transversally extending therethrough, the retention pin being inserted in said pin channel and pin hole, the retention pin having a length not exceeding a diameter of the base member, so as to allow sliding of the base member within the corresponding passage,

said pin channel and pin hole being sized to provide a longitudinal clearance for the retention pin therein, thereby defining said longitudinal play between the upper member and base member,

said pin channel and pin hole are sized to provide a transversal clearance for the retention pin therein, thereby defining a transversal play between the upper member and base member.

9. The multiport gas chromatograph diaphragm-sealed valve according to claim 1 according to claim 1 , wherein the at least one support element comprises:

a push plate extending within the valve body parallel to the diaphragm and movable transversally thereto, the normally closed plungers being mounted on said push plate, a plurality of cavities extending across said push plate for allowing the normally open plungers to slide therethrough; and

an upper piston extending under the push plate contiguously thereto, the normally opened plungers being placed thereon.

10. The multiport gas chromatograph diaphragm-sealed valve according to claim 9 , wherein the plunger actuating mechanism further comprises:

a lower piston extending under the upper piston contiguously thereto, the lower piston being rigidly connected to the push plate;

biasing means for upwardly biasing the lower piston and downwardly biasing the upper piston; and

actuating means for actuating the plungers between opened and closed positions thereof, the actuating mechanism controlling a distance between the upper and lower pistons.

11. The multiport gas chromatograph diaphragm-sealed valve according to claim 10 , wherein the valve body comprises a shoulder near the interface of the lower and the upper pistons, for limiting a vertical displacement of the lower piston.

12. A method for adjusting a sealing force in a multiport gas chromatography diaphragm-sealed valve, the method comprising the steps of:

a) selecting the material of the diaphragm;

b) based on the material of the diaphragm selected in step a), determining a varying pressure profile required to maintain proper sealing of the plunger on the diaphragm over an operating temperature range varying from 0 to 350° C.

c) selecting the resilient middle element so that the force profile of the resilient element matches the varying pressure profile determined in step b), and

d) providing the multiport gas chromatography diaphragm-sealed valve, the multiport gas chromatography diaphragm-sealed valve comprising

a valve cap with process conduits extending therethrough, each of the process conduits ending in a process port;

a valve body facing the valve cap, the valve body comprising plunger passages extending therein and in alignment with the respective process conduits;

the diaphragm selected in step a), positioned between the valve cap and the valve body, and

a plunger assembly comprising:

a plunger-actuating mechanism located within the valve body; and

a plurality of normally-closed and normally-opened plungers slidably fitting in the respective passages of the valve body, each plunger comprising:

a base member operatively connected to the actuating mechanism;

an upper member projecting towards the diaphragm, for pressing the diaphragm in a closed position, or extending away from the diaphragm in an opened position, the upper member having a longitudinal play within a corresponding one of the passages with respect to the base member; and

the resilient middle element selected in step c), provided between the base member and the upper member,

each of said plungers thereby providing an active temperature mechanical feedback loop when in use within the multiport gas chromatography diaphragm-sealed valve.