IP Library Granted Patent US 8,669,032
Granted Patent B2
US 8,669,032 · App. 12/556,306 · Granted Mar 11, 2014

Electrostatic-image-developing toner, production method thereof, electrostatic image developer, and image forming apparatus

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Quick Facts
Patent No.
US 8,669,032
App. No.
12/556,306
Granted
Mar 11, 2014
Kind
B2
Abstract

An electrostatic-image-developing toner includes a binder resin that contains a crystalline polyester resin and an amorphous polyester resin; and a coloring agent, wherein the crystalline polyester resin has a melting temperature Tmc of about 25° C. or greater but not greater than about 50° C., and a content of the crystalline polyester resin in the electrostatic-image-developing toner is about 3 wt % or greater but not greater than about 15 wt. %.

Claims (21)

1. An electrostatic-image-developing toner comprising:

a binder resin that contains a crystalline polyester resin and an amorphous polyester resin; and

a coloring agent, wherein

the crystalline polyester resin has a melting temperature Tmc of from 25° C. to 32° C., and

a content of the crystalline polyester resin in the electrostatic-image-developing toner is about 3 wt. % or greater but not greater than about 15 wt. %.

2. The electrostatic-image-developing toner according to claim 1 , wherein the binder resin further contains a urea-modified polyester resin.

3. The electrostatic-image-developing toner according to claim 2 , wherein the urea-modified polyester resin is obtained by a reaction between a polyester resin containing an isocyanate group and an amine.

4. The electrostatic-image-developing toner according to claim 1 , wherein the crystalline polyester resin has an acid value AVc of about 5 mgKOH/g or greater but not greater than about 20 mgKOH/g.

5. The electrostatic-image-developing toner according to claim 1 , wherein the crystalline polyester resin has a weight average molecular weight (Mw) of about 10,000 or greater but not greater than about 30,000.

6. The electrostatic-image-developing toner according to claim 1 , wherein the amorphous polyester resin has an acid value AVa of about 10 mgKOH/g or greater but not greater than about 20 mgKOH/g.

7. The electrostatic-image-developing toner according to claim 1 , wherein the amorphous polyester resin has a weight average molecular weight (Mw) of about 10,000 or greater but not greater than about 50,000.

8. The electrostatic-image-developing toner according to claim 1 , wherein the amorphous polyester resin has a glass transition temperature (Tg) of about 40° C. or greater but not greater than about 60° C.

9. The electrostatic-image-developing toner according to claim 3 , wherein an [NCO]/[OH] equivalent ratio is about 1/1 or greater but not greater than about 5/1 wherein [NCO] represents the isocyanate group and [OH] represents a hydroxyl group of the polyester resin.

10. The electrostatic-image-developing toner according to claim 1 , further comprising a releasing agent that has a melting temperature Tmw of about 50° C. or greater but not greater than about 120° C.

11. The electrostatic developing toner according to claim 1 , which has a volume average particle size of about 4 μm or greater but not greater than about 8 μm.

12. The electrostatic-image-developing toner according to claim 1 , which has a volume average particle size distribution index GSDv of about 1.27 or less.

13. The electrostatic-image-developing toner according to claim 1 , which has a shape factor SF 1 of about 110 or greater but not greater than about 140.

14. The electrostatic-image-developing toner according to claim 1 , which has a water content of about 0.01 wt. % or greater but not greater than about 10 wt. %.

15. An electrostatic image developer comprising:

the electrostatic-image-developing toner as claimed in claim 1 ; and

a carrier.

Assignments (2)
CHANGE OF NAME Recorded Aug 12, 2021
From: FUJI XEROX CO., LTD.
To: FUJIFILM BUSINESS INNOVATION CORP.
Reel/Frame 058287/0056 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 9, 2009
From: IWANAGA, TAKESHI; FUJII, TAKAHISA; IIJIMA, MASAKAZU
To: FUJI XEROX CO., LTD.
Reel/Frame 023217/0207 →