Polycrystalline compacts having material disposed in interstitial spaces therein, and cutting elements including such compacts
View Patent ↗Polycrystalline compacts include smaller and larger hard grains that are interbonded to form a polycrystalline hard material. The larger grains may be at least about 150 times larger than the smaller grains. An interstitial material comprising one or more of a boride, a carbide, a nitride, a metal carbonate, a metal bicarbonate, and a non-catalytic metal may be disposed between the grains. The compacts may be used as cutting elements for earth-boring tools such as drill bits, and may be disposed on a substrate.
1. A polycrystalline compact, comprising:
a first plurality of grains of hard material having an average grain size of about five hundred nanometers (500 nm) or less;
a second plurality of grains of hard material having an average grain size of about five microns (5 μm) or greater; and
an interstitial material concentrated around at least some of the first plurality of grains of hard material, the interstitial material comprising at least one of a boride, a carbide, a nitride, a metal carbonate, a metal bicarbonate, and a non-catalytic metal.
2. The polycrystalline compact of claim 1 , wherein the first plurality of grains of hard material comprises grains of diamond.
3. The polycrystalline compact of claim 2 , wherein the interstitial material comprises at least one of a carbon nitride material, a carbon boride material, a metal carbonate, a metal bicarbonate, and a metal carbide.
4. The polycrystalline compact of claim 3 , further comprising a catalyst material disposed in at least some interstitial spaces between the first plurality of grains of hard material and the second plurality of grains of hard material.
5. A polycrystalline compact, comprising:
a first plurality of grains of hard material having a first average grain size;
at least a second plurality of grains of hard material having a second average grain size that is at least about one hundred fifty (150) times larger than the first average grain size, the first plurality of grains and the at least a second plurality of grains being interspersed and interbonded to form a polycrystalline hard material; and
an interstitial material concentrated around at least some grains of the first plurality of grains, the interstitial material comprising at least one of a boride, a carbide, a nitride, a metal carbonate, a metal bicarbonate, and a non-catalytic metal.
6. The polycrystalline compact of claim 5 , wherein the second average grain size is between two hundred fifty (250) times and seven hundred fifty (750) times larger than the first average grain size.
7. The polycrystalline compact of claim 5 , wherein the first average grain size is between about one nanometer (1 nm) and about one hundred fifty nanometers (150 nm), and the second average grain size is between about five microns (5 μm) and about forty microns (40 μm).
8. The polycrystalline compact of claim 5 , wherein the first plurality of grains comprises between about one-half of one percent (0.5%) and about thirty percent (30%) by volume of the polycrystalline hard material.
9. The polycrystalline compact of claim 5 , wherein each of the first plurality of grains and the at least a second plurality of grains comprises grains of diamond.
10. The polycrystalline compact of claim 5 , wherein each of the first plurality of grains and the at least a second plurality of grains comprises grains of cubic boron nitride.
11. The polycrystalline compact of claim 5 , wherein the interstitial material comprises at least one of a carbon nitride material, a carbon boride material, a metal carbonate, a metal bicarbonate, and a metal carbide.
12. The polycrystalline compact of claim 5 , further comprising a catalyst material disposed in at least some interstitial spaces between the first plurality of grains and the at least a second plurality of grains.
13. A cutting element, comprising:
a substrate; and
a polycrystalline compact on the substrate, the polycrystalline compact comprising:
a first plurality of grains of hard material having a first average grain size;
at least a second plurality of grains of hard material having a second average grain size that is at least one hundred fifty (150) times larger than the first average grain size; and
an interstitial material concentrated around at least some grains of the first plurality of grains, the interstitial material comprising at least one of a boride, a carbide, a nitride, a metal carbonate, a metal bicarbonate, and a non-catalytic metal.
14. The cutting element of claim 13 , wherein the second average grain size is between two hundred fifty (250) times and seven hundred fifty (750) times larger than the first average grain size.
15. The cutting element of claim 13 , wherein each of the first plurality of grains and the at least a second plurality of grains comprises grains of diamond.
16. The cutting element of claim 13 , wherein each of the first plurality of grains and the at least a second plurality of grains comprises grains of cubic boron nitride.
17. The cutting element of claim 13 , wherein the interstitial material comprises at least one of a carbon nitride material, a carbon boride material, a metal carbonate, a metal bicarbonate, and a metal carbide.