Siloxane-polymer dielectric compositions and related organic field-effect transistors
View Patent ↗Dielectric compositions comprising siloxane and polymeric components, as can be used in a range of transistor and related device configurations.
1. A composite comprising a crosslinked dielectric film in contact with a semiconductor component, wherein the crosslinked dielectric film comprises a crosslinked product of a composition comprising a polymeric component and a bis(silylated) component, wherein the polymeric component is selected from poly(vinylphenol), polystyrene, poly(styrene-co-vinylphenol), and poly(ethylene-co-vinylalcohol), and wherein the bis(silylated) component has the formula Cl 3 Si—O—SiCl 3 or (X) 3-m (Y) m Si(Z)Si(Y′) m′ (X′) 3-m′ , wherein Z is a moiety selected from (CH 2 ) n , a divalent branched alkyl group, and a divalent substituted alkyl group; n ranges from 1 to 20; X and X′ are independently selected from halide, amino, alkoxy and carboxylate groups, and combinations thereof; Y and Y′ are independently selected from H and alkyl; and m and m′ independently range from 0 to 2.
2. The composite of claim 1 , wherein the semiconductor component comprises a semiconducting molecule or polymer.
3. The composite of claim 2 on a substrate component.
4. The composite of claim 3 , wherein the substrate component comprises a gate component of a transistor device.
5. A field-effect transistor device comprising source and drain electrodes and the composite of claim 4 .
6. The field-effect transistor device of claim 5 , wherein the transistor device is an organic thin-film transistor.
7. The field-effect transistor device of claim 5 , wherein the field-effect transistor device is a complementary logic device.
8. The field-effect transistor device of claim 7 , wherein the complementary logic device is an inverter.
9. The composite of claim 1 , wherein the bis(silylated) component has the formula (X) 3-m (Y) m Si(Z)Si(Y′) m′ (X′) 3-m′ , wherein (X) 3-m (Y) m Si and Si(Y′) m′ (X′) 3-m′ are selected from a trihalosilyl group, a trialkoxysilyl group, a triacetoxysilyl group, a dialkoxyhalosilyl group, a dihydrohalosilyl group, a dialkylhalosilyl group, a dihaloalkylsilyl group, a dihalohydrosilyl group, and a dihaloalkoxysilyl group, and Z is a moiety selected from (CH 2 ) n , a divalent branched alkyl group, and a divalent substituted alkyl group, wherein n ranges from 1 to 20.
10. The composite of claim 1 , wherein Z is (CH) n , wherein n is an integer ranging from 3 to 14.
11. The composite of claim 1 , wherein the bis(silylated) component is selected from hexachlorosiloxane, 1,6-bis(trichlorosilyl)hexane, 1,12-bis(trichlorosilyl)dodecane, and 1,6-bis(triacetoxysilyl)hexane.
12. The composite of claim 1 , wherein the crosslinked dielectric material comprises metal oxide particles, wherein the metal oxide particles comprise a metal component selected from a Group III metal, a Group IV metal, a transition metal, and combinations thereof.
13. The composite of claim 1 , wherein the crosslinked dielectric film has a thickness dimension ranging from about 10 nm to about 1 μm.
14. The composite of claim 2 , wherein the semiconducting molecule or polymer is selected from pentacene, a polythiophene, and a phthalocyanine.
15. The field-effect transistor device of claim 5 configured as a top-contact thin film transistor, wherein the source and drain electrodes are defined on top of the semiconductor component.
16. The field-effect transistor device of claim 5 configured as a bottom-contact thin film transistor, wherein the source and drain electrodes are defined on the crosslinked dielectric film.